高可靠性烧结金属丝网防爆元件的应用研究

烧结金属多孔元件作为隔爆元件的应用，很好地满足了火焰过滤元件的性能要求，进一步拓宽了烧结金属多孔元件的应用领域，章在论述其性能特点、结构类型的同时，对其在微孔结构设计上的差异也进行了描述。     

环境友好水基润滑添加剂的研究

在脂肪酸分子中引入硼和氮，合成了一种环境友好水基润滑添加剂BNR，并利用红外光谱对其主要官能团进行了表征。通过四球试验机考察了BNR添加剂在水中的抗磨性能与极压性能，用X射线光电子能谱仪对磨痕表面元素进行了分析，探讨了该类添加剂的极压抗磨作用机理。结果表明：硼氮化水基润滑添加剂BNR在水中具有优良的抗磨和减摩性能；其润滑作用机理是由于长链脂肪酸分子的载体作用、硼的缺电子性、氮的高反应活性以及三者的协同作用与摩擦金属表面形成了一层高强度的吸附膜和／或摩擦化学反应膜。     

Off-axis fatigue cracking behaviour in notched fibre metal laminates

The off‐axis fatigue cracking behaviour of notched fibre metal laminates under constant amplitude loading conditions was investigated experimentally and numerically. It was found that the off‐axis fatigue crack initiation life decreased as the off‐axis angles increased. This indicated that the off‐axis laminates raised the applied stress level in the aluminium (Al) layer and subsequently resulted in earlier cracking in the Al layer. The off‐axis fatigue crack initiation lives of notched fibre metal laminates were predicted using lamination theory and an energy‐based critical plane fatigue damage analysis from the literature. After a crack initiated in the Al layer, it was observed that the crack path angles of the off‐axis specimens were neither perpendicular to the fibre nor to the loading direction. A finite‐element model was established for predicting the crack path angles.     

Crack closure in fibre metal laminates

GLARE is a fibre metal laminate (FML) built up of alternating layers of S2-glass/FM94 prepreg and aluminium 2024-T3. The excellent fatigue behaviour of GLARE can be described with a recently published analytical prediction model. This model is based on linear elastic fracture mechanics and the assumption that a similar stress state in the aluminium layers of GLARE and monolithic aluminium result in the same crack growth behaviour. It therefore describes the crack growth with an effective stress intensity factor (SIF) range at the crack tip in the aluminium layers, including the effect of internal residual stress as result of curing and the stiffness differences between the individual layers. In that model, an empirical relation is used to calculate the effective SIF range, which had been determined without sufficiently investigating the effect of crack closure. This paper presents the research performed on crack closure in GLARE. It is assumed that crack closure in FMLs is determined by the actual stress cycles in the metal layers and that it can be described with the available relations for monolithic aluminium published in the literature. Fatigue crack growth experiments have been performed on GLARE specimens in which crack growth rates and crack opening stresses have been recorded. The prediction model incorporating the crack closure relation for aluminium 2024-T3 obtained from the literature has been validated with the test results. It is concluded that crack growth in GLARE can be correlated with the effective SIF range at the crack tip in the aluminium layers, if it is determined with the crack closure relation for aluminium 2024-T3 based on actual stresses in the aluminium layers.     

Effect of Rare Earth Element Cerium on Mechanical Properties and Morphology of TiN Coating Prepared by Arc Ion Plating

TiN coatings were deposited on polished substrates of W18Cr4V high speed steel by means of vacuum arc ion plating. The effect of cerium on adhesion between TiN coating and substrate was studied. The microstructures and composition of TiN coatings were also investigated by means of scanning electron microscope (SEM), Auger electron spectroscopy (AES), and X-ray diffraction (XRD) technique. It was found that cerium is an effective modifying agent and the addition of suitable amount of cerium to TiN coatings can produce relatively excellent properties such as micro-hardness, wear resistance, oxidation resistance and porosity. The experimental results show that the added cerium in TiN coatings makesa contribution to form the preferred direction along with a (111 ) or (222) close packed face, which may be one of the reasons that improves some properties mentioned above.     

热处理对Ti-25V-15Cr-2Al-2Mo-0.2C合金组织稳定性的影响

研究了热处理对Ti-25V-15Cr-2A1-2Mo-0.2C阻燃β钛合金组织稳定性的影响。结果表明，高温固溶并直接时效处理导致合金β基体上析出较多的α相沉淀，尤其在随后的热暴露组织中形成了恶化合金塑性的连续晶界α膜。然而，若在时效前再进行一次低温固溶处理则可明显减少α相的析出数量，合金的热稳定性因此而得到显著改善。     

Water‐Stable,Magnetic Silica–Cobalt/Cobalt Oxide–Silica Multishell Submicrometer Spheres

A method to produce monodisperse magnetic composite spheres with diameters from less than 100 nm to more than 1 μm in water solution is reported. The spheres consist of a dielectric silica core and a cobalt/cobalt oxide shell which can be protected from further oxidation with an outer shell of silica or, alternatively, they can be covered with the polymer polyvinylpyrrolidone as a stabilizer. The formation of a uniform magnetic shell proceeds with the adsorption of metallic cobalt seeds, produced by the reduction of cobalt chloride with sodium borohydride, on a self‐assembled layer of polyelectrolytes on the silica core. In the second step, an outer silica shell can be formed by the hydrolysis and condensation of (3‐aminopropyl)trimethoxysilane and tetraethoxysilane. The double‐shell composite spheres show excellent sphericity, monodispersity, and a magnetic hysteresis loop at room temperature.     

Low Electrical Percolation Threshold of Silver and Copper Nanowires in Polystyrene Composites

Silver and copper nanowires have been synthesized using a scalable method of AC electrodeposition into porous aluminum oxide templates, which produces gram quantities of metal nanowires ca. 25 nm in diameter and up to 5 and 10 μm in length for Ag and Cu, respectively. The nanowires have been used to prepare polystyrene nanocomposites by solution processing. Electrical resistivity measurements performed on polymer nanocomposites containing different volume fractions of metal indicate that low percolation thresholds of nanowires are attained between compositions of 0.25 and 0.75 vol %.     

Catalytic oxidation of sulphide ions to elementary sulphur in aqueous solutions over transition metal oxides

The catalytic activity of a wide range of transition metal oxides in oxidation of sulphide ions by air in aqueous medium was studied. Some specific features of the reaction mechanism on some of the studied oxides were considered. The transition metal oxides are promising catalysts for practical application. Some of these oxides will allow the preparation of catalysts possessing activity comparable to that of the cobalt phthalocyanine based catalysts, popular in industrial practice.