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71.
葵花籽油模拟液中甲基丙烯酸甲酯迁移量的测定 总被引:1,自引:0,他引:1
目的 建立了葵花籽油模拟液中甲基丙烯酸甲酯迁移量的测定方法。方法 采用乙醇漩涡提取葵花籽油中甲基丙烯酸甲酯2 min, 用GC/MS检测, 外标法定量。结果 本法的定量限(LOQ)为0.75 mg/kg, 线性范围为0.75~30.00 mg/kg, 线性相关系数为0.9998。在1倍LOQ、2倍LOQ、0.5倍限量、1倍限量及2倍限量5个添加水平下平均回收率在86.71%~100.45%之间, 相对标准偏差(n=6)均小于5%。结论 方法的灵敏度、回收率高、选择性好, 能满足实际工作的要求。 相似文献
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用混浊法和沸腾法分别研究了二叔丁基氮氧自由基(DTBNO)对丙烯腈(AN)及丙烯酸甲酯(MA)、甲基丙烯酸甲酯(MMA)自由基聚合的阻聚作用。结果表明,DTBNO对AN有较强的阻聚作用;DTBNO与对苯二酚(HQ)、苯醌(BQ)、二乙基羟胺(DEHA)等分别组成二元混合物时,其阻聚效果非常明显。当DTBNO-DEHA和DtBNO-HQ的浓度(ppm,下同)比分别为500:1000和1000:500时,对AN的阻聚效果最好;在二元混合阻聚剂中加入适量吩噻嗪(PT),其阻聚效果更佳,如DTBNO-DEHA-PT(500:500:500)在100℃时可使MMA完全终止聚合反应。 相似文献
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Based upon computer analysis, the Gibbs-DiMarzio (G-DM) theory is evaluated for the case of (a) constant V0 and (b) constant r where V0 is the fractional free volume at Tg and r is the ratio of the hole (E0) to the flex (ε) energy. For each respective case, results are presented in a reduced variables format that indicate the extent to which r and V0 vary at the transition temperature as a function of the reciprocal degree of polymerization (P?1). To further account for chemical differences that exist among polymers, an index (n) is introduced that ultimately incorporates the effective number average of chain atom segments (x?) per P?. Using these reduced variables plots, the effects of V0, r, and n are compared with the Tg data for four well-documented polymers. Although the theory adequately describes the PMMA, PS, and PVC data, for PαMS the fit is doubtful. The analysis demonstrates that, in order to maintain V0 within the range of 0.015–0.045, r must remain within approximately 1.0–1.1. Moreover, under conditions of either constant V0 or r, other more flexible polymers require that . 相似文献
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Leaf damage by herbivores inNicotiana sylvestris Spegazzini and Comes (Solanaceae) produces a damage signal that dramatically increasesde novo nicotine synthesis in the roots. The increased synthesis leads to increases in whole-plant nicotine pools, which in turn make plants more resistant to further herbivore attack. Because signal production and the response to the signal occur in widely separated tissues, the speed with which different damage signals exit a damaged leaf can be studied. We propose that electrical damage signals should exit a leaf faster (less than 60 min) than chemical damage signals. Excision of a leaf induces a smaller increase in nicotine production than does puncture damage, so we examined our proposition by excising previously punctured leaves at 1, 60, and 960 min after leaf puncture and quantifying the induced whole-plant nicotine pools six days later when the induced nicotine production had reached a maximum. Significant induced nicotine production occurred only if punctured leaves were excised more than 1 hr after puncture, which is consistent with the characteristics of a slow-moving chemical signal rather than a fast-moving electrical signal. We explore the nature of the chemical signal and demonstrate that additions of 90µg or more of methyl jasmonate (MJ) in an aqueous solution to the roots of hydroponically grown plants inducede novo nicotine synthesis from15NO3 in a manner similar to that induced by leaf damage. We examine the hypothesis that jasmonic acid (JA) functions in the transfer of the damage signal from shoot to root. Using GC-MS techniques to quantify whole-plant JA pools, we demonstrate that leaf damage rapidly (<0.5 hr) increases shoot JA pools and, more slowly (<2 hr), root JA pools. JA levels subsequently decay to levels found in undamaged plants within 24 hr and 10 hr for shoots and roots, respectively. The addition of sufficient quantities (186µg) of MJ in a lanolin paste to leaves from hydroponically grown plants significantly increased endogenous root JA pools and increasedde novo nicotine synthesis in these plants. However, the addition of 93µg or less of MJ did not significantly increase endogenous root JA pools and did not significantly affectde novo nicotine synthesis. We propose that wounding increases shoot JA pools, which either directly through transport or indirectly through a systemin-like signal increase root JA pools, which, in turn, stimulate root nicotine synthesis and increase whole-plant nicotine pools. 相似文献
78.
Li^+掺杂纳米TiO2的制备及其光催化性能研究 总被引:3,自引:0,他引:3
采用溶胶-凝胶法和浸渍法制备了Li^+掺杂纳米TiO2光催化剂,并用XRD和TEM等技术进行了表征;用pH值漂移法测量了催化剂的零电位pH值(pHPZC).结果表明,500℃煅烧制得的催化剂均为锐钛矿相;Li^+的掺杂抑制了TiO2,粒子的生长,提高了催化剂的分散性;催化剂的零电位pH值为6.6—8.1,其值取决于Li^+的浓度和掺杂方式.分别以紫外光和太阳光为光源,孔雀石绿和甲基橙为降解物评价了催化剂的光催化活性;并用气相色谱测试了污染物降解产生的CO2的含量.结果显示,对孔雀石绿的降解,浸渍法和溶胶-凝胶法掺Li^+都能有效提高TiO2的光催化活性,但浸渍法比溶胶-凝胶法效果更好,催化活性最高的为浸渍法制备的5%(摩尔分数)Li^+掺杂TiO2,其在紫外光和太阳光下的光催化活性分别比纯TiO2提高了6—8倍和9-10倍;对甲基橙的降解,除溶胶-凝胶法制备的3%(摩尔分数)Li^+掺杂TiO2能稍提高光催化活性外,其它Li'的掺杂都不同程度降低了TiO2的光催化活性;随污染物降解率的增加,最终降解产物CO2的含量增加.实验结果表明,Li^+掺杂改变了催化剂表面的电荷状态从而改变了催化剂的零电位pH值是造成催化剂降解不同污染物具有不同催化活性的主要原因. 相似文献
79.
L. Thiraphattaraphun S. Kiatkamjornwong P. Prasassarakich S. Damronglerd 《应用聚合物科学杂志》2001,81(2):428-439
The grafting of the methyl methacrylate (MMA) monomer onto natural rubber using potassium persulfate as an initiator was carried out by emulsion polymerization. The rubber macroradicals reacted with MMA to form graft copolymers. The morphology of grafted natural rubber (GNR) was determined by transmission electron microscopy and it was confirmed that the graft copolymerization was a surface‐controlled process. The effects of the initiator concentration, reaction temperature, monomer concentration, and reaction time on the monomer conversion and grafting efficiency were investigated. The grafting efficiency of the GNR was determined by a solvent‐extraction technique. The natural rubber‐g‐methyl methacrylate/poly(methyl methacrylate) (NR‐g‐MMA/PMMA) blends were prepared by a melt‐mixing system. The mechanical properties and the fracture behavior of GNR/PMMA blends were evaluated as a function of the graft copolymer composition and the blend ratio. The tensile strength, tear strength, and hardness increased with an increase in PMMA content. The tensile fracture surface examined by scanning electron microscopy disclosed that the graft copolymer acted as an interfacial agent and gave a good adhesion between the two phases of the compatibilized blend. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 428–439, 2001 相似文献
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