有机硅丙烯酸乳液的研制

以丙烯酸酯和有机硅官能单体为原料,合成了有机硅丙烯酸乳液。介绍了乳液及由其制备的涂料的性能。讨论了影响乳液性能的因素。     

高含水率杨木单板室温胶合的脲醛树脂胶研究

在实验室条件下 ,以传统脲醛树脂胶的生产工艺为基础 ,加用氨基取代羧酸类化合物。新配方制得脲醛树脂胶 ,用DSC分析了树脂固化反应热过程 ,对含水率在 12 % -2 0 %杨木单板进行了室温胶合研究     

表面改性活性炭对饮用水中THMs吸附性能研究

通过对活性炭的表面改性，并对氯化消毒后的高色度水进行吸附处理，可使其三氯甲烷（THMs)的含量降低到44μg/dm^3，达到国家生活饮用水质标准。     

RPF-AA改性纤维的制备及耐硫酸侵蚀性研究

通过对普通腈纶进行特殊预处理和改性,制备出一种具有良好抗浓酸侵蚀性的反应性高分子纤维材料,对改性纤维材料的化学(酸)稳定性、力学性能、微结构等特征性能研究表明:该纤维材料在120℃和98%浓硫酸环境条件下,经过20 min的侵蚀性处理后,其材料仍能够保持一定的力学性能和微结构,显示了突出的抗浓硫酸侵蚀性.     

聚四氟乙烯改性剂的制备及性能

介绍了隔膜法氯碱所用的聚四氟乙烯改性剂，即聚四氟乙烯乳液、聚四氟乙烯纤维（SM-1）、聚四氟乙烯类纤维（SM-2）的制造原理、制造方法以及在隔膜法氯碱上的应用效果。     

Electro-oxidation of hydrazine on electrodes modified with vitamin B12

In this paper we report a kinetic study of the electro-oxidation of hydrazine catalyzed by vitamin B₁₂ pre-adsorbed on an ordinary pyrolytic graphite electrode. Kinetic parameters were determined by linear sweep voltammetry and rotating-disk electrode polarization curves. The order of the reaction is 1 in OH⁻ ions and Tafel plots give slopes of 80 mV/decade. A possible redox-catalysis mechanistic scheme is proposed.     

Mechanical properties and crosslink density of rare earth‐modified high‐abrasion furnace‐filled powdered natural rubber

High‐abrasion furnace‐filled powdered natural rubber [P(NR/HAF)] has more advantages than traditional HAF‐filled bale NR (NR/HAF) because of its better environmental performance and easier processing quality, but its lower mechanical properties are disadvantageous. To improve the mechanical properties, rare earth‐modified HAF‐filled powdered NR [P(NR/HAF‐Ln)] (Ln = Sm,La,Pr) was prepared by means of coacervation–coprecipitation, using rare earth‐modified HAF as separant and filler. The effect on mechanical properties of P(NR/HAF‐Ln) vulcanizate exerted by the emulsifier/HAF ratio, powdering temperature, Ln/HAF ratio and type of Ln, and HAF content were studied. The results indicated that when optimum formulation, the mechanical properties of P(NR/HAF‐Ln) vulcanizate were better than P(NR/HAF) vulcanizate. In addition, the relationship of the apparent crosslink density and HAF content of P(NR/HAF‐Ln), P(NR/HAF), NR/HAF vulcanizates was also investigated, along with their SEM microphotographs of tensile fracture surface, which indicated that the excellent mechanical properties of P(NR/HAF‐Ln) vulcanizate was attributed to correct amount of Ln that could increase crosslink density and reinforce the interface structure of NR matrix/HAF‐Ln particle. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 1755–1762, 2006     

有机硅改性丙烯酸乳液性能的研究

采用含乙烯基官能团的有机硅单体与甲基丙烯酸酯、丙烯酸酯和丙烯酸羟基酯等单体通过种子乳液聚合方法进行共聚,合成了有机硅改性丙烯酸酯共聚乳液,考察了有机硅单体用量对乳液机械稳定性、热稳定性、电解质稳定性和冻融稳定性的影响,同时还考察了乳液胶膜的机械性能和吸水率改进。     

空气气氛中烧成Si3N4-SiC复合材料的性能、相组成和显微结构

以氮化硅细粉(粒度＜0.088 mm,w(β-Si3N4)＞95%)、碳化硅(w(SiC)＞98%,粒度分别为2.8～0.9mm、0.9～0.15 mm、＜0.115 mm和＜0.063 mm四级)、硅粉(粒度＜0.045 mm,w(Si)＞98%)和硅灰(w(SiO2)=98.3%)为原料,以木质素磺酸钙水溶液作成型结合剂,采用150 MPa的压力成型为65 mm×114 mm×230mm的Si3N4-SiC、Si3N4-SiC-Si和Si3N4-SiC-SiO2三种试样.在空气气氛中,以50℃·h-1的升温速度升至800℃保温4 h,再升至1450℃保温2 h,自然冷却至室温后,测定烧成后试样的常温耐压强度、常温抗折强度、1400℃下的高温抗折强度、显气孔率、体积密度和残氮率,并采用XRD、SEM和EPMA等手段分析烧后试样的相组成和显微结构.结果表明3种试样在空气气氛中烧成后的高温(1400℃)和常温抗折强度都比较高,显气孔率都比较低,而耐压强度则以Si3N4-SiC试样的最高;烧成后试样中心区域的残氮率以Si3N4-SiC-Si试样的最高,Si3N4-SiC-SiO2试样的次之,Si3N4-SiC试样的最小;在空气气氛中烧成后,Si3N4-SiC试样中的Si3N4分解较多,SiC-Si3 N4-Si试样的表面和内部都明显含有单质Si,SiC-Si3N4-SiO2试样表面区域的Si2N2O晶体发育很好,而内部区域的晶体发育较小.     

燃煤和大气污染

介绍了煤炭作为中国主要能源在开发利用过程中对大气污染的计数据，论述了燃煤的洁净技术和污染控制技术，提出今后发展的目标