High-temperature oxidation of SiC in a glow-discharge oxygen plasma

The oxidation kinetics and structure of the oxide scales formed on high-density SiC were studied in molecular oxygen at 740 Torr and in a glow-discharge oxygen plasma at 0.1 Torr at temperatures of 1000, 1100, and 1200°C. The monatomic oxygen formed by the glow discharge markedly increased the reaction rate and the vaporization of some of the oxidation products. The marked differences in kinetics suggest that the rate-controlling step during oxidation in molecular oxygen is the dissociation of adsorbed diatomic oxygen to the monatomic species. Films formed in molecular oxygen were mostly amorphous SiO₂ with small inclusions of SiC and graphite, whereas films formed in dissociated oxygen were primarily amorphous SiO₂ containing SiO, S₂O₃, and the coesite form of SiO₂.     

Metal Single-Site Molecular Complex–MXene Heteroelectrocatalysts Interspersed Graphene Nanonetwork for Efficient Dual-Task of Water Splitting and Metal–Air Batteries

Development of multifunctional electrocatalysts with high efficiency and stability is of great interest in recent energy conversion technologies. Herein, a novel heteroelectrocatalyst of molecular iron complex (Fe_MC)-carbide MXene (Mo₂TiC₂T_x) uniformly embedded in a 3D graphene-based hierarchical network (GrH) is rationally designed. The coexistence of Fe_MC and MXene with their unique interactions triggers optimum electronic properties, rich multiple active sites, and favorite free adsorption energy for excellent trifunctional catalytic activities. Meanwhile, the highly porous GrH effectively promotes a multichannel architecture for charge transfer and gas/ion diffusion to improve stability. Therefore, the Fe_MC–MXene/GrH results in superb performances towards oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER) in alkaline medium. The practical tests indicate that Zn/Al–air batteries derived from Fe_MC–MXene/GrH cathodic electrodes produce high power densities of 165.6 and 172.7 mW cm⁻², respectively. Impressively, the liquid-state Zn–air battery delivers excellent cycling stability of over 1100 h. In addition, the alkaline water electrolyzer induces a low cell voltage of 1.55 V at 10 mA cm⁻² and 1.86 V at 0.4 A cm⁻² in 30 wt.% KOH at 80 °C, surpassing recent reports. The achievements suggest an exciting multifunctional electrocatalyst for electrochemical energy applications.     

Epitaxial growth and thermal-conductivity limit of single-crystalline Bi2Se3/In2Se3 superlattices on mica

Nano Research - Thermal transport in superlattices is governed by various phonon-scattering processes. For extracting the phonon-scattering contribution of hetero-interfaces in chalcogenide...     

Monitoring the Dynamic Process of Formation of Plasmonic Molecular Junctions during Single Nanoparticle Collisions

The capability to study the dynamic formation of plasmonic molecular junction is of fundamental importance, and it will provide new insights into molecular electronics/plasmonics, single‐entity electrochemistry, and nanooptoelectronics. Here, a facile method to form plasmonic molecular junctions is reported by utilizing single gold nanoparticle (NP) collision events at a highly curved gold nanoelectrode modified with a self‐assembled monolayer. By using time‐resolved electrochemical current measurement and surface‐enhanced Raman scattering spectroscopy, the current changes and the evolution of interfacial chemical bonding are successfully observed in the newly formed molecular tunnel junctions during and after the gold NP “hit‐n‐stay” and “hit‐n‐run” collision events. The results lead to an in‐depth understanding of the single NP motion and the associated molecular level changes during the formation of the plasmonic molecular junctions in a single NP collision event. This method also provides a new platform to study molecular changes at the single molecule level during electron transport in a dynamic molecular tunnel junction.     

悬锤式小巧光电测角仪

本文给出一种基于微型光电编码器和８９Ｃ２０５１ 单片机的数字显示的小巧测角仪。其创新点在以重锤杆做为转动角度的基准线; 并用磁吸合方式与被测体固定。该仪在一些场合应用特别方便     

我国超高分子质量聚乙烯纤维的检测手段及发展现状

根据国内主要超高分子质量聚乙烯纤维制造商产品的测试结果,论述了国产该纤维的主要性能及其与国外同类产品的质量差距,论述了目前我国各生产厂家及相关检测机构在强度、模量、断裂伸长、耐磨性、蠕变率、分子质量等纤维主要性能测试中存在的问题,提出了解决建议,同时指出了我国在超高分子质量聚乙烯纤维应用方面与国外的差距．     

基于遗传算法的关联议题并发谈判

基于遗传算法的并发谈判在电子商务应用中具有独特的优势,但已有的研究尚未考虑议题之间的相关性、动态权重的变化规则依赖于对手信息的获取,极大地限制了其使用价值.对此,提出议题分组的方法以解决议题的相关性问题,而议题权重的变化则采取从历史资源中发掘知识的方法进行动态调整.构建了基于遗传算法的关联性议题并发谈判模型,给出了模型的形式化描述、谈判算法设计和动态权重更新方案.通过对模型的实验和比较分析,证实了该方案能够更方便地满足用户谈判的多样性需求,解决谈判中议题关联性的问题,而且能够快速、有效地得出最优谈判结果.     

一种基于模糊评判的水平叠加方法

以信号的模式识别为基础,应用模糊评判的方法,通过道集叠加得到标准道,对道集内的各道进行模糊评判,剔除评判结果最差的道,再次进行叠加、评判、剔除,直到达到要求的评判结果或规定的最大剔除道数.模拟试验表明,通过模糊评判方法得到的叠加记录的效果明显优于直接叠加.     

Observation and computer simulation of multicomponent chemical short-range order （MCSRO） for the bulk metallic glasses

The atomic configuration of chemical short-range order (CSRO) for the Zr-base metallic glasses was investigated by using nano-diffraction and high resolution transmission electronic microscopy (HRTEM) technology with a beam size of 0.5 rim. It is illustrated that the pattern of atomic configuration of CSRO might have various compound counterparts because of the chemical interaction of bonding atoms. Some atomic configuration of MCSRO is similar to the icosahedral structure with 10-fold symmetry of very weak spots. In deed, the nano-beam technology could clearly detect the evolution of atomic configuration in nanometer scale during the transformation from the metallic melt to the primary crystallization. The local atomic configuration of CSRO is also investigated by molecular dynamics simulation (MD) for the Zr2Ni compound in a wider temperature range. The CSRO in the melt could be pictorially demonstrated as distorted coordination polyhedron of the compound structure and/or the structure similar to cubo-octahedron analogs. The MD simulation illustrates that the atomic packing of long-range order disappears just above the melting point, but the chemical interaction of bonding atoms still exists that leads to form the various CSRO with the atomic configuration similar to stable or metastable unit cell of Zr2Ni compound. The icosahedral polyhedron became more abundance as the overheating temperature was raised.     

60m~3/h变压吸附制氮设备改造

介绍了60m3/h变压吸附制氮设备改造前存在的主要问题、改造的主要措施及改造前后设备的性能比较,分析了改造中的一些体会和需注意的事项。