磷石膏提质降杂实验研究

磷石膏的综合利用对保护环境、促进企业可持续健康发展具有重要意义,但是磷石膏中的磷、氟、二氧化硅等杂质影响其利用。针对云南磷石膏中二氧化硅含量高的问题,采用正浮选工艺开展了磷石膏提质降杂的实验研究。通过单因素条件实验获得了合适的工艺参数：浮选温度为15 ℃、矿浆pH为2、十二胺用量为300 g/t。在此条件下,进行了“一粗二精”的正浮选开路流程实验,获得了二水石膏（CaSO₄·2H₂O）质量分数为97.5%、二氧化硅质量分数为1.17%的精矿,所得精矿达到了GB/T 23456—2018《磷石膏》一级品指标的要求;二水石膏回收率为98.58%、二氧化硅去除率为92.23%。通过正浮选不仅成功实现了二水石膏和二氧化硅的有效分离,而且磷石膏中的水溶磷和水溶氟也得到了有效去除,从而提高了磷石膏的品质。     

某含铜尾矿粗砂工艺矿物学特征及选矿试验研究

为查找铜损失在尾矿中的原因并制定选矿回收工艺,对某低品位含铜尾矿粗砂进行了工艺矿物学分析和选矿试验研究。结果表明：含铜矿物主要是黄铜矿（CuFeS2）,嵌布粒度微细且呈浸染状分布,未能充分单体解离而损失在尾矿中。经过选矿优化试验确定粗尾砂可采用立式搅拌磨,使微细粒级铜矿物充分单体解离;然后,采用优先浮选工艺回收铜,闭路试验可获得Cu品位18.02%、Cu回收率41.05%的铜精矿。     

Collector matching in origin potential flotation

Through thermodynamic calculation and electrochemistry analysis~ taking the galena as example,the ba-sis for collector matching in origin potential flotation (OPF) was studied. The results of thermodynamic calculation show that the upper limit value of pH and flotation potential of diethyldithiocarbamate (DDTC) is higher than that of xanthogenate (KBX), which indicates that the collecting ability of DDTC for galena is better than that of KBX.The results of the interface capacitance analysis show that lead diethyldithiocarbamate (PbD2) is more steady than lead xanthogenate (Pb(BX)2) on the galena surface under the oxidation condition; the resistance analysis shows thatD2 (DDTC oxidizes into its dimmer) and dixanthogen (BX)2 will occur non-faradic desorption on the pyrite electrodesurface when the potentials are above 0.13 V and 0.2 V respectively. A synthetical criterion ΔE of collecting ability and selectivity was proposed. The results predicted by this criterion are confirmed through flotation experiments of ore.     

高压粉末制样-X射线荧光光谱法测定海洋沉积物中28种组分

常规粉末压片制样是一种简单、高效的绿色环保制样技术,但是应用于某些沉积物样品制备存在样片表面粗糙和粉末容易脱落的问题。实验采用高于常规的压力进行样品制备,建立了X射线荧光光谱法(XRF)分析海洋沉积物样品中包括硫、氧化钠、氧化镁、三氧化二铝、二氧化硅、五氧化二磷、氧化钾、氧化钙、二氧化钛、氧化锰、三氧化二铁、钴、镍、铜、锌、钒、铬、镓、铌、锆、钇、锶、铷、铅、钡、镧、钕和铪在内的28种主、微量组分的方法。探讨了压力为300 kN和1 600 kN时的制样效果,并尝试引入BP神经网络模型利用其非线性拟合能力校正主量组分的基体效应。结果表明,采用1 600 kN压力制备的样片,表面致密、光滑、不龟裂和不掉粉,制样重复性和测试精密度也有较大提高。以55个有证标准物质中17种组分的数据集为训练样本,建立了海洋沉积物样品中主、微量组分的遗传算法-BP神经网络预测模型。按照实验方法对各组分含量相对较低的实际样品连续测试12次,计算得方法的检出限在 0.63～634 μg/g之间;精密度试验结果表明,各组分测定值的相对标准偏差(RSD, n=7)为0.16%～25.1%。方法用于海洋沉积物实际样品分析,其分析结果与国标法的测定结果吻合,能够满足海洋沉积物样品中多种组分准确分析的要求。     

Progress in flotation de-silica

1　INTRODUCTIONBayer sprocessisatypicalmethodtoproducea luminumoxidefrombauxite .Forthediasporic baux ite ,theBayer sprocesscaneconomicallyproducealu minumoxideonlywhenthemassratioofAl2 O3toSiO2 >10 .However ,inChina ,thealuminumoxidewasmainlyproducedbyusing“sinteringprocess”or“in parallelBayer sinteringcombination process”technologiesbecausethediasporic bauxiteischarac terizedbyhighcontentofaluminumoxideandsilicabutlowAl2 O3/SiO2 (average 5 6 ) .Thesetwotech nologieshavetheproble…     

Unique microstructure and property of a 2024 aluminum alloy subjected to upsetting extrusion multiple processing

The microstructure and hardness of a 2024 aluminum alloy subjected to multi-pass upsetting extrusion at ambient temperature were studied. Experimental results indicated that with the number of upsetting extrusion passes increasing, the grains of the alloy are gradually refined and the hardness increases correspondingly. After ten passes of upsetting extrusion processing, the grain size decreases to less than 200 nm in diameter and the sample maintains its original shape, while the hardness is double owing to equal-axial ultrafine grains and work hardening effect caused by large plastic deformation.     

ADSORPTION MECHANISMS OF HS-IONS ON SULPHIDE MINERAL SURFACES RELATED TO Na_2S-INDUCED FLOTATION

The adsorption mechanisms of HS~- ions existing in air-saturated alkaline solutions on sulphide minerals (including pyrite, arsenopyrite, chalcopyrite and galena) were investigated. The measurement of adsorption density, solvent extraction-chemical analysis of neutral sulphur at the surfaces, measurements of pulp potential and voltammogram, and flotation tests were done. Both the electrochemical and non-electrochemi cal adsorption models of HS~- ions were established. The former was observed and resulted in the formation of neutral sulphur (S°)when the pyrite and arsenopyrite were chosen, and hence renders the surfaces hy drophobic and induced the two minerals flotation. It is called Na_2S-induced flotation. On the other hand, the latter took place and did not produce S° when the chalcopyrite and galena were selected, and hence de presses the collectorless flotation of the two minerals. The adsorptions of HS~- ions were mainly influenced by potentials, pH and the electron structures of the mineral surfaces.     

PRESSURE DISTRIBUTION IN THE AIR-SPARGED HYDROCYCLONE

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Flow field in air-sparged hydrocyclone

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