基于1H NMR测定和基团贡献法预测石油馏分的热化学性质

测定了两种原油 2 0个石油馏分的¹H NMR谱和氢、碳元素含量等结构参数 ,以及馏分的燃烧焓、蒸发焓等热化学性质 .假设每个石油馏分仅由CH₃ 、CH₂ 、CH、ACH和C这 5种简单基团构成 ,基于¹H NMR测定和元素分析结果解出石油馏分平均分子结构中的基团数目 ,再用纯有机物的基团贡献法预测石油馏分的燃烧焓、蒸发焓 ,预测值与实验数据吻合良好     

铝塑复合管硅烷交联聚乙烯专用料的研究

研究了高密度聚乙烯（HDPE）／线性低密度聚乙烯（LLDPE）硅烷接枝交联体系。分析了过氧化二异丙苯（DCP），乙烯基三乙氧基硅烷（VTES），加工设备及工艺条件（温度，螺杆转速）对体系熔体流动速率（MFR）和凝胶含量的影响。并用Buss混炼设备制备出高流动性的铝塑复合管硅烷接枝交联PE专用料。     

大型下行式循环流化床反应器颗粒浓度分布研究

采用双光路光纤密度探头研究了内径418mm,高18米大型下行式循环流化床（其中下行床部分长度6．5m)反应器中的颗粒浓度分布，结果表明大直径下行床中颗粒浓度沿径向呈现中心均匀，近壁处存在高浓环形区的分布，这类似于小直径反应器中的结果，随着反应器直径的增加，颗粒浓度分布最大值的径向位置向边壁方向移动，即：当下行床放大时，中心颗粒浓度均匀分布区的面积占整个床层截面积的比例增大，在一种特殊设计的下行床边壁结构中测量了颗粒浓度沿径向的分布，实验结果说明边壁效应对下行床近壁区颗粒浓环的形成起到了重要作用，研究结果将有助于了解下行床反应的放大特性。     

THE EFFECT OF LIQUID PHYSICAL PROPERTIES ON DRIFT VELOCITY

Drift velocity is a very important paramcter for predictirg the pool volumetric void fraction. Two-phase system of gas and high viscous liquids pool is encountered in various engineering applications. A review of the literature shows no data for explaining the effect of highly viscous liquids on the drift velocity. This paper's analysis shows that there is a considerable influence. It is shown that the foaming behaviour of liquids is dependent on the surface properties. For some highly viscous liquids at a given superficial gas velocity, the viscosity changes with time. The effect of "foam" and "time" on drift velocity is clearly elucidated.     

液体粘度,表面张力与管径对池式两相流型的影响

在不同直径的垂直玻璃管中盛装着不同物性(粘度与表面张力)的液体,空气经分配器注入静止的液体中,对两相流型的变化进行了观察研究。流型的确定采用了高速录相机系统,也同时进行肉眼观察,并测量了不同流型的空隙度。实验表明:空气-高粘性液体和空气-起泡液体的气、液两相流型与通常的空气-水系统的流型极不相同。其空隙度也在较广泛范围内变化。     

过氧化物交联聚乙烯的力学性能研究

采用过氧化物交联方法研究了交联聚乙烯的工艺、配方和性能，探讨了过氧化物用量对材料力学性能及凝胶含量的影响，以及炭黑、氧化锌、抗氧剂对材料性能的影响。结果表明，过氧化物交联聚乙烯的力学性能有一定的提高，随着DCP含量的增加，交联PE的凝胶含量提高，而随着凝胶含量的提高，交联PE的拉伸强度提高，断裂伸长率下降；炭黑对材料有一定的补强作用，氧化锌的加入有助于交联反应和拉伸强度的提高。     

垂直同心环形管内上升气液两相环状流含气率与压降预测

对垂直同心环形管内上升气液环状流的截面含气率及压降预测进行了研究.根据Kelessidis有关团状流向环状流转换的思路以及Wallis有关圆管内环状流积分分析的方法,考虑环形管的结构特征及环状流的流型特征,通过两相动力学理论建立了新的预测截面含气率及总压降的模型.将新模型及现有模型与实验数据的分析比较表明新模型对于总压降的预测效果较好.     

应用电导探针测定鼓泡塔内气泡参数

介绍了一种性能稳定的双头电导探针的制作工艺、测量原理。并用此电导探针测量了一定静液层高的带单个泡罩的鼓泡塔内气液两相流参数,包括局部气含率、界面浓度、当量直径等,并首次回归了局部气含率随空间位置、气体流量变化的关联式。     

Prediction of minimum fluidization velocity for vibrated fluidized bed

The prediction of minimum fluidization velocity for vibrated fluidized bed was performed. The Geldart group A and C particles were used as the fluidizing particles. The method based on Ergun equation was used to predict the minimum fluidization velocity. The calculated results were compared with the experimental data.The calculated results of minimum fluidization velocity are in good agreement with experimental data for Geldart group A particles. For group C particles, the difference between the calculated results and experimental data is large because of the formation of agglomerates. In this case, the determination of agglomerate diameter is considered to be necessary to predict the minimum fluidization velocity.     

Bubble size effect on low liquid input drift-flux parameters

We investigated the effect of bubble size on the drift-flux parameters at low liquid flow conditions by measuring the radial profiles of void fraction and phase velocities in a vertical bubbly pipe flow of diameter and height . To study the effect of the bubble size we used two different types of bubble inlets. We measured the local bubble fraction and velocity U_g by using single and four-point-optical fibre probes, and we used Laser Doppler Anemometry to determine the liquid velocity U_l. The distribution parameter C₀ and the weighted mean drift velocity |U_drift| were directly computed from the local measurements at a height on our experimental set-up. Both parameters were influenced by the bubble size. Provided no liquid flow reversal occurred at the near wall region, the distribution parameter reached a below unity minimum plateau value of C₀=0.95 for wall peaking void fraction profiles. At low liquid input conditions both the liquid input and bubble size had an influence on the distribution parameter. Extreme values such as C₀>2 were measured. From these measurements we developed models for the drift-flux parameters to take into account the effect of bubble size and input-flow conditions for our intermediate pipe diameter value. These models were tested and validated with separately collected experimental data.