β-Phellandrene: kairomone for pine engraver,Ips pini (Say) (Coleoptera: Scolytidae)

The responses ofIps pini (Scolytidae) to multiple-funnel traps baited with the pheromone, ipsdienol, and various monoterpenes were determined in stands of lodgepole pine in southern and central British Columbia.Ips pini was attracted to both ipsdienol and -phellandrene, demonstrating that -phellandrene is a kairomone for this species.Lasconotus complex (Colydiidae) and aCorticeus sp. (Tenebrionidae) were attracted to both ipsdienol and -phellandrene. TheCorticeus sp. exhibited a synergistic response to the combination of ipsdienol and -phellandrene; the responses of the other two species to the combination were additive. The predators,Thanasimus undatulus, Enoclerus sphegeus, andE. lecontei (Cleridae), were attracted to ipsdienol-baited traps, whileMonochamus clamator (Cerambycidae) andDendroctonus ponderosae (Scolytidae) were attracted to -phellandrene. Attraction of all eight species increased with increasing release rates of ipsdienol and/or -phellandrene.     

磁氧分析仪在焦化回收系统的应用

分析磁氧分析仪在实际生产中存在的问题,并提出改造措施,以提高电捕焦油器的安全性和稳定性。     

Fluorescence of poly(di-n-alkylsilane)s in room-temperature solution

A comprehensive study of the electronic absorption and emission spectra and the fluorescence quantum yield and lifetime of seven poly(di-n-alkylsilane)s and of three isotopically labelled poly(di-n-hexylsilane)s in hydrocarbon solution at room temperature is reported. Also reported are fluorescence polarization and carbon tetrachloride quenching of fluorescence of poly(di-n-hexylsilane). The observed fluorescence spectra, quantum yield, and polarization depend on the selected excitation energy in a very characteristic fashion, whereas the fluorescence lifetime does not; however, it depends on the selected emission energy. These characteristic dependencies are qualitatively accounted for by the previously proposed segment distribution model if one assumes that the photophysical behavior at higher excitation energies is strongly affected by the presence of a low-lying weakly allowed state in short-segment chromophores and the behavior at lower excitation energies is dictated by the selective excitation of emitting long-segment chromophores.     

An EXAFS study of the Mo/TiO2 hydrodesulphurization catalysis

In-situ EXAFS studies of sulphided Mo/TiO₂ catalysts have shown that at low Mo loadings (2–4 wt%), an active species with a short Mo-S distance of 2.25 Å is formed, while on Mo/TiO₂ with high Mo loadings as well as on Mo/-Al₂O₃, bulk MoS₂ (Mo-S, 2.42 Å) is formed. The species with the short Mo-S distance has Mo in an oxidation state close to 6 + and is likely to result from the sulphidation of the tetrahedral molybdate species present in the oxidic precursor at low Mo loadings. The calcination temperature of the oxidic precursor appears crucial, a high calcination temperature of 973 K favouring the formation of MoS₃ on sulphidation, and a low calcination temperature of 623 K favouring MoS₂.Contribution No. 790 from the Solid State and Structural Chemistry Unit.     

基于溶液图像时序特征的元素组分含量动态监测系统

针对稀土萃取过程中组分含量难以实时监测以及现有组分含量检测方法耗时、耗内存的现状,设计了一种基于溶液图像时序特征的元素组分含量动态监测系统。首先使用图像采集装置获取萃取槽体溶液的时序图像,考虑萃取液颜色特性和单一颜色空间的不全面性,采用主成分分析（PCA）方法在HSI和YUV融合的颜色空间提取图像的时序特征,并结合生产指标构造基于鲸鱼优化算法（WOA）的最小二乘支持向量机（LSSVM）分类器来对工况状态进行判断。然后当工况处于非最佳状态时,在HSV颜色空间对图像提取颜色直方图和颜色矩特征,并开发以溶液图像间的混合特征差值的线性加权值为相似度度量的图像检索系统,从而获取组分含量值。最后进行镨/钕萃取槽体混合溶液测试,结果表明该系统能够实现元素组分含量的动态监测。     

砾石土质条件下葡萄滴灌生育期土壤含水率变化规律研究

为探究酿酒葡萄在砾石土质条件下的土壤含水率变化规律及合理灌溉制度,选取贺兰山东麓砾石土典型试验区,以五年生赤霞珠品种为研究对象,设计2 550、2 850、3 225、3 600 m3/hm24个不同定额的灌水处理,应用TDR土壤水分剖面仪和土壤水势仪,监测生育期滴灌前后不同土层含水率与水势变化,针对监测数据从灌水处理整体与单个生育期不同角度进行分析,研究酿酒葡萄在砾石土条件下不同滴灌定额土壤含水率变化规律,最终提出生育期适宜灌溉制度。研究结果表明:随着灌溉定额的增加,土壤含水率在0~40cm土层范围内变化较明显;不同深度土层土壤水势变化规律与灌溉定额的大小有关;1m深土壤水分蓄存比并不是随着灌水量的增加而增大,而是当灌水量达到某一定额时,随着灌水量的增加,土壤水分蓄存比减小,砾石土单次灌水量高于300 m3/hm2时,土壤水分蓄存比较低,易产生深层渗漏。     

旅游法实施背景下网友对“导游员”工作的感知——基于新浪微博文本分析

以2013年国庆期间新浪微博网友关于“旅游法”和“导游”的原创微博为样本,采用数量分析方法,分析网友对旅游法实施后导游工作关注程度的变化以及对旅游法的支持程度,研究表明,国庆期间网友对旅游法实施后导游工作的关注日益增加,认为旅游法的实施对导游工作有正面影响的网友占大多数.使用词频统计法和共现分析法进行内容分析,网友对导游工作的感知主要包括：导游工作需要旅行社和游客的支持和理解;支持旅游法对无证导游的惩罚,但是惩罚力度不足;旅游法对强制消费的约束已初见成效,但部分网友表现出对部分导游工作态度消极的不满;旅游法实施后导游收入下降明显.     

企业网站设计内容第一的原则

企业网站设计内容第一的原则,其根本在于企业网站能否吸引和留住客户或潜在客户,它包含三层意思：网站内容的面向对象要准确清晰;针对目标访客的网站内容要紧扣其兴趣中心,从为其带来价值的角度出发,令其感到有收获;促使目标访客对网站内容建立起充分的信任感、解答其疑问。从网站内容方面保证了企业网站对目标访客的吸引力和访问粘度,从而为企业网站实现其既定目标打下了良好的基础。     

燃烧离子色谱法测定α-烯烃齐聚反应体系中催化剂BF3的含量

BF₃作为α-烯烃齐聚反应催化剂,其含量控制对催化反应的调控与产品质量的把控至关重要。通过建立样品前处理方法、优化仪器测试条件与标准溶液配制方法,建立利用燃烧离子色谱测定BF₃·醇催化的α-烯烃齐聚反应体系中F元素含量,进而计算出BF₃含量的方法,并考察了方法的重复性和准确性。结果表明：利用该方法可测定BF₃质量分数范围为2.68～53.50 g/kg的样品,前处理时适量的正丁醇和白油可有效稳定和稀释样品;测定稀释样品中F元素含量的标准曲线分为2段,线性范围分别为300～2000 mg/L和2000～3000 mg/L,线性相关系数R²分别为0.9992和0.9940;测定5次BF₃质量分数结果相对标准偏差均小于5%,方法加标回收率在95.0%～105.0%之间,方法检出限取决于前处理时的取样量,当取样量为5 g时,检出限为1 mg/kg。     

高温-超压-高CO2背景下致密砂岩储层成岩作用特征——以莺歌海盆地LD10区新近系梅山组-黄流组为例

利用薄片鉴定、扫描电镜、阴极发光及碳氧同位素分析等手段,对莺歌海盆地LD10区新近系梅山组-黄流组高温-超压-高CO₂背景下的储层成岩作用特征及其对孔隙的影响进行了系统研究。研究结果表明: ①莺歌海盆地LD10区新近系梅山组-黄流组储层发育重力流沉积,岩性以中-细粒长石岩屑石英砂岩为主,储层物性以特低-低孔、特低渗特征为主。②压实、胶结和溶蚀作用是研究区主要的成岩作用类型。超压对黏土矿物的转化及石英次生加大具有明显抑制作用,并在一定程度上保护了原生孔隙。富含CO₂的高温流体不仅造成了黏土矿物的异常转化,同时促进了溶蚀作用发生,增加了次生孔隙。③研究区黄二段储层的成岩演化序列为: 菱铁矿胶结→石英次生加大→绿泥石胶结→长石淋滤溶蚀→高岭石形成→早期方解石胶结→早期白云石胶结→长石溶蚀→方解石溶蚀→伊利石大量生成→晚期铁方解石、铁白云石形成。④总体上,压实作用使孔隙度减少了45.30%～62.93%,胶结作用使孔隙度减少了1.65%～35.01%,溶蚀作用使孔隙度增加了0.72%～8.00%。其中,黄流组中下部砂岩储层受到了超压保护和CO₂溶蚀作用的双重影响,物性较好,钻井过程中应考虑高CO₂风险。