助剂对Pd/树脂醚化催化剂催化性能的影响 Ⅰ.铝助剂的影响

研究了不同助剂对Ｐｄ／树脂醚化催化剂在临氢条件下对催化裂化汽油Ｃ５馏份与甲醇和Ｈ２反应的催化性能的影响。结果表明，在Ｐｄ／树脂醚化催化剂中引入Ｚｒ、Ｔｉ、Ｂ、Ｓｎ和Ａｌ等助剂后，都能改善催化剂的醚化、双键异构和二烯烃选择性加氢活性，其中以Ａｌ、Ｓｎ为最好。Ａｌ助剂的体积质量和负载方式对Ｐｄ－Ａｌ／树脂醚化催化剂的活性有影响。ＢＥＴ方法和Ｘ－射线荧光光谱分析（ＸＦＳＡ）表明，Ａｌ助剂对Ｐｄ－Ａｌ／树脂醚化催化剂的表面积、孔结构和Ｐｄ离子交换量影响较小。     

浅谈程序设计中一题多解的教学方法

中等职业学校一般开设VB、VC及数据库等涉及程序设计的计算机课程。本文拟就程序设计中一题多解的教学方法进行探讨。     

一维弹道修正模块设计与仿真

简要介绍了一种用于维弹道修正引信的执行机构。通过数学模型，结合MDT三机械设计软件和Working Model动力学仿真软件，对机构的受力情况和工作过程进行了数字仿真和系统分析，并通过对飞行弹道的模拟，得出了一维时间控制射程修正规律。     

Formation of C4 species in the deactivation of a Pd/SiO2 catalyst during the selective hydrogenation of acetylene

The deactivation characteristics of Pd/SiO₂ in the selective hydrogenation of acetylene were correlated with changes in the amount of the C4 species produced. The amounts of butenes produced changed in parallel with the catalyst activity, indicating that the rate limiting step for butene production was the same as that for acetylene hydrogenation. On the other hand, the amount of 1,3-butadiene produced changed, showing a maximum with catalyst deactivation because 1,3-butadiene is an intermediate in the sequential reaction process which involves both the production and consumption of 1,3-butadiene. This was verified by a simultaneous TG/reaction experiment showing that 1,3-butadiene was a precursor of green oil. The catalyst showed a self-regenerative behavior in its activity and the amounts of C4 species produced during the early stage of deactivation because two opposite factors, which contributed to either the lowering or the promotion of activity, were involved in the process. A specific type of polymer species, produced during the initial period of deactivation, is proposed to be responsible for the promotion of catalyst activity.     

形式化语言在UMTS开发中的应用

由于3G协议规范的复杂性，3GPP方法论指导方针中鼓励使用标准的形式化语言来进行UMTS产品的设计、开发与测试。文中概要性地描述了UMTS的体系结构和在规范描述中用到的一些形式化语言的基本概念和特点，探讨了这些形式化语言在UMTS开发中的应用。使用形式化语言开发UMTS可以简化和改进测试程序，实现新产品与新标准的同步推出。     

乙炔在磁稳定床中的选择性加氢研究

 制备了一种磁性Pd/Al₂O₃催化剂，采用磁稳定床考察了活性组分负载量、反应条件及CO浓度对乙炔加氢反应性能的影响。结果表明，当反应温度80℃、反应压力1.5MPa、空速9000h－1、磁场强度（H）25kA/m时，乙炔转化率为100％，乙烯选择性可达81％，具有优良的乙炔加氢活性和乙烯选择性，优于相同反应条件下的进口催化剂；250h稳定性实验结果表明，磁性Pd/Al2O3催化剂具有良好的初活性和乙烯选择性，催化剂性能稳定。     

Thermodynamic Aspects of Aromatic Hydrogenation

Aromatic hydrogenation is one of the important classes of hydrotreating reactions and its thermodynamics play a significant role in achieving the product specifications. This article comprehensively reviews the available experimental thermodynamic data as well as the methods to estimate the data for aromatic hydrogenation. The data indicate that aromatic hydrogenation reactions are thermodynamically more favorable at about 200°C-250°C and moderate pressures (3-5 MPa). Industrially, however, these reactions are carried out at 300°C-375°C to have reasonable kinetics. Hence there is a need for highly active catalysts, which can facilitate significant kinetics of hydrotreating reactions at around 200°C-250°C.     

加氢联合装置压缩机组的防喘振控制

阐述了喘振的发生、危害及其控制。介绍了加氢联合装置Triconex的TS-3000控制系统防喘振控制器的特性和各种控制线、防喘振控制的算法和操作。采用该系统后可以有效地实现防喘振控制，提高机组的控制灵敏度、稳定性及工艺生产过程的安全性和可靠性。     

NUMERICAL ANALYSIS AND EXPERI- MENT OF UNSTEADY THERMAL FIELD OF ROTOR PLATE FOR EDDY CURRENT RETARDER

The physical model based on heat transfer theory and virtual boundary method for analyzing unsteady thermal field of rotor plate for eddy current retarder used in automobile is established and boundary conditions are also defined. The finite element governing equation is derived by Galerkin method. The time differential item is discrete based on Galerkin format that is stable at any condition. And a new style of varying time step method is used in iteration process. The thermal field on the rotor plate at the radial and axle directions is analyzed and varying temperature at appointed points on two side-surfaces is measured. The testing and analytical data are uniform approximately. Finite element method can be used for estimating thermal field of the rotor plate at initial design stage of eddy current retarder.     

单片机自控系统在NS0631型轨道起重机上的应用

单片机自控系统在大型工程机械中得到了越来越广泛的使用，从而使设备的安全性、可靠性大为提高。文章着重分析了NS0631型轨道起重机中自控系统的结构、使用中存在的问题，提出了解决的方法及今后的改进设想。