Synthesis and Properties of Rare Earth Complexes with 3-Ferrocenyl-5-Phenyl-Pyrazoline-1-Dithiocarbamate

Sodium 3-ferrocenyl-5-phenyl-pyrazoline-1-dithiocarbamate (FPPD) reacts with anhydrousrare earth chlorides in absolute ethanol to give 14 new complexes.The results of elemental analysis show thatthe compositions of the complexes are RE(FPPD)_3·nH_2O(RE=La,Pr～Lu and Y;n=3).The ligand andits complexes have been characterized by infrared spectroscopy,UV-visible absorptionspectroscopy,~1H-NMR spectra,thermal analysis and molar conductivity measurement.     

DHDECMP-TBP/煤油萃取 HNO_3-稀土过程中防止形成第二有机相的研究

研究了ＤＨＤＥＣＭＰ－ＴＢＰ／煤油萃取ＨＮＯ３后形成和防止形成第二有机相的各影响因素。以Ｇｄ代表稀土，探讨了ＤＨＤＥＣＭＰ－ＴＢＰ／煤油萃取稀土时ＤＨＤＥＣＭＰ浓度、ＴＢＰ浓度、水相ＨＮＯ３浓度和温度对有机相萃取负载量的影响。结果表明：０．６０ｍｏｌ／ＬＤＨＤＥＣＭＰ－１．４０ｍｏｌ／ＬＴＢＰ／煤油能有效避免第二有机相的形成，又能满足工艺负载量的要求。     

接种氧化亚氮(N2O)还原细菌YSQ030对复垦土壤N2O排放和氮循环关键功能基因的影响

复垦土地是重要的后备土地资源,但通常土壤结构差、有机质和养分含量低;增施有机肥是快速提升地力的关键途径,但会造成温室气体如氧化亚氮(N₂O)的大量排放.接种具有N₂O还原功能的植物根际促生菌(PGPR)不仅能够减少温室气体排放,还能促进作物生长.本研究以一株具有N₂O还原功能的PGPR反硝化无色杆菌(Achromobacter denitrificans) YSQ030为供试菌株,明确接种YSQ030对施用有机肥的复垦土壤N₂O排放和氮循环关键功能基因的影响.通过设置施用有机无机复混肥和羊粪有机肥的土壤微宇宙试验,利用气相色谱仪分析接种YSQ030后土壤N₂O排放通量,进一步计算累积排放量;在试验结束后分析土壤pH、EC(电导率)、硝态氮和铵态氮含量,并利用实时荧光定量PRC分析土壤硝化功能基因(AOA amoA和AOB amoA)和反硝化功能基因(nirS、nirK、nosZ Ⅰ 和nosZ Ⅱ)的丰度.结果显示,施用有机无机复混肥和羊粪有机肥的土壤中接种YSQ030明显减少复垦土壤N₂O排放,N₂O排放量最大减少分别达90.4％和30.6％.施用有机无机复混肥处理的N₂O排放量远高于施用羊粪有机肥处理,这可能是由于施用有机无机复混肥的土壤与施用羊粪有机肥的土壤相比,土壤中编码反硝化细菌N₂O还原酶基因nosZ Ⅰ 和非典型反硝化细菌N₂O还原酶基因nosZ Ⅱ 基因丰度较低.施用有机无机复混肥均显著降低土壤硝化和反硝化功能基因丰度,而施用羊粪有机肥对土壤硝化和反硝化功能基因丰度大多没有明显影响.本研究表明,接种YSQ030能够减少施用有机肥土壤的N₂O排放,将为复垦土壤地力提升和N₂O减排提供科学依据,也将为研发新型微生物肥料或生物有机肥提供核心菌种资源.     

对流方程的交替分组显示方法

提出了求解对流方程初边值问题绝对稳定的二阶精度交替分组显示方法.模型问题的数值结果表明,本方法忧于陈景良和陆金甫的分组显示方法.     

Yielding, authoritarianism, and authoritarian ideology regarding groups.

This investigation was prompted by Asch's (1952) discussion of the personal and social significance of yielding to group pressure. For the person, yielding requires the inhibition of overt and perhaps implicit responses to objective situational requirements. For the group, malignant processes may arise and develop, unchecked by those members in whom goals of personal security predominate over group goals. In the present study, the view was taken that both meanings of yielding are assigned positive value in two separate ideologies concerning the group-individual relation. One of these is termed "conformity" and the other is "rugged individualism." In the study, group pressure was simulated by announcing bogus group judgments to small groups of Ss whose apparent task was to match one of three lines of variable length with a standard line. Questionnaires were used to measure variables, which were: the ideology of conformity (IC), the ideology of rugged individualism (RI), ethnocentrism (E), and authoritarianism (F). The questionnaires were administered to 91 college students, both day school and evening. It was found that the correlation with the F scale was .48 (P     

国内外城镇化与生态环境协调关系动态研究

为探讨当今城镇化与生态环境的研究重点和方向,进一步丰富城镇化与生态环境协调发展的研究理论,促进城镇化、生态环境健康发展。本文通过系统梳理国内外城镇化与生态环境协调关系的理论与实证研究文献,分析目前研究现状与存在的主要问题。指出在城镇化和生态环境指标的构建上有待进一步完善、研究维度上有待进一步深化、研究尺度上有待进一步拓展,进一步明晰了城镇化与生态环境高质量发展路径,为未来该领域理论完善提供借鉴。     

非饱和粉土回弹模量的应力依赖性与水敏感性耦合分析

为了研究路基内部应力状态和含水率变化对回弹模量的影响,建立了路基土回弹模量的预估模型。根据室内三轴重复加载试验结果,研究了应力依赖性控制指标的选择,结果表明:体应力变化时,回弹模量不具有单调变化的规律,所以不宜作为应力依赖性的控制指标;而利用围压和偏应力作为控制指标时则能全面的反映回弹模量的变化规律。根据土水特征曲线,利用基质吸力表征含水率的影响,构建应力依赖性和水敏感性的耦合模型,并通过试验结果的拟合验证,发现该模型能够较好地反映回弹模量随应力水平和含水率变化的规律。     

辐射和热同时作用对膨润土物理化学性质和微观结构影响的初步研究北大核心CSCD

为了研究γ辐射和热同时作用对膨润土的影响,以高庙子改性钠基膨润土为研究对象,开展了90℃热作用下、不同剂量率和不同累积剂量的γ辐射老化试验。结果表明:γ辐射和90℃热同时作用引起了膨润土物理化学性质和微观结构的变化。在老化作用后,膨润土的吸水率、pH值、阳离子交换容量、层荷以及蒙脱石001晶面方向的微晶尺寸均减小,比参考样分别降低了(最大减幅)18.4%、7.8%、3.4%、2.9%和15.6%,且表现出剂量率效应;老化作用对膨润土的矿物成分及含量影响较小。在高放废物地质处置的工程屏障设计和安全评价中,应考虑膨润土性质变化的影响因素。     

Metal‐containing Polymers via Electropolymerization

Electropolymerization represents a suitable and well‐established approach for the assembly of polymer structures, in particular with regard to the formation of thin, insoluble films. Utilization of monomers that are functionalized with metal complex units allows the combination of structural and functional benefits of polymers and metal moieties. Since a broad range of both electropolymerizable monomers and metal complexes are available, various structures and, thus, applications are possible. Recent developments in the field of synthesis and potential applications of metal‐functionalized polymers obtained via electropolymerization are presented, highlighting the significant advances in this field of research.     

官能化噻咯合成研究进展Ⅱ.交联法、取代法、硼化法与硅烷化法

官能化噻咯(silole音译)是一种重要的噻咯衍生物,不仅在有机金属合成领域占重要地位,也是建构新型π共轭体系的重要组成部分。本文介绍了官能化噻咯的几种重要合成方法,并对各种方法的特点及适用范围作了分析和总结。