High pressure organic colloid method for the preparation of high performance carbon nanotube-supported Pt and PtRu catalysts for fuel cell applications

Highly dispersed,high performance Pt and PtRu catalysts,supported on multiwalled carbon nanotubes(CNTs),were prepared by a high pressure organic colloid method.The particle sizes of the active components were as small as 1.2 nm for Pt and 1.1 nm for PtRu,and the active Pt surface areas were 295 and 395 m2/g,respectively.The catalysts showed very high activities toward the anodic oxidation of methanol,evaluated by cyclic voltammetry,being up to 4 times higher than that of commercial Johnson Matthey Hispec 20...     

Stochastic stability of quasi-integrable Hamiltonian systems with time delay by using Lyapunov function method

The asymptotic Lyapunov stability of one quasi-integrable Hamiltonian system with time-delayed feedback control is studied by using Lyapunov functions and stochastic averaging method.First,a quasi-integrable Hamiltonian system with time-delayed feedback control subjected to Gaussian white noise excitation is approximated by a quasi-integrable Hamiltonian system without time delay.Then,stochastic averaging method for quasi-integrable Hamiltonian system is used to reduce the dimension of the original system,a...     

Estimation of temporal changes in oxidation rates of sulphides in copper mine tailings at Laver, Northern Sweden

Tailings containing pyrrhotite were deposited in an impoundment at a copper mine at Laver, Northern Sweden, which operated between 1936 and 1946. Since then the oxidation of sulphides has acidified recipient water courses and contaminated them with metals. Measurements from surface water sampled in 1993, 2001 and 2004-05 from a brook into which the tailing impoundment drains indicate that the amounts of sulphide-associated elements such as Cu, S and Zn released into the brook have decreased over time, while pH has increased. The mass transport of S in the brook during 1993 and 2001 corresponded well with the amount of S estimated to be released from the tailings by oxidation. Secondary precipitates such as covellite and gypsum, which can trap sulphur, were shown in earlier studies to be present in only low amounts. The annual release of elements from the tailings was estimated from the volume of tailings assumed to oxidise each year, which depends on movement of the oxidation front with time. The results indicate that the oxidation rate in the tailings has decreased over time, which may be due to the increased distance over which oxygen needs to diffuse to reach unoxidised sulphide grains, or their cores, in the tailings.     

添加剂LiBOB在LiCoO2体系中的性能研究

采用恒流充放电法研究了LiBOB对LiCoO2作正极体系高温循环性能的影响。使用DSC法分析了LiBOB对负极SEI膜热稳定性的影响。初步探讨了LiBOB对PC基电解质与MAG相容性的影响机理。交流阻抗法测试结果表明,LiBOB的添加使MAG电极表面形成一层稳定的固体电解液相界面膜(SEI),抑制了PC共嵌,并使循环性能得到改善。DSC结果分析表明,LiBOB使负极SEI膜的热稳定性得到了改善。     

An innovative technique to evaluate network equivalent for voltage stability assessment in a widespread sub-grid system

The equivalent two-bus network models currently available are obtained by lumping all the series impedances and shunt admittances of transmission lines within a series equivalent impedance, to assess voltage stability of multi-bus power system. This paper reports the development of an equivalent pi-network model using a new methodology considering series and shunt parts of line loss separately obtained from the operational parameters of optimal power flow solution of the original multi-bus power network, which can be applied to assess the overall voltage stability status of the system accurately by developing the concept of a generalized global voltage stability margin (GVSM). Simulation results for a typical longitudinal power supply (LPS) system and a robust practical (Indian Eastern Grid) system establish that the pi-equivalent model obtained by the proposed method is highly promising for assessing voltage stability of any power system at any operating point in global scenario in a better way as compared to available series equivalent model. Continuation power flow (CPF) method has also been adopted here to verify the potential of the proposed method for voltage stability assessment. In the proposed equivalent network the generators have been modeled more accurately considering optimal operating criteria.     

具有阶段结构和HollingⅢ型功能反应的捕食-食饵系统持久性和全局稳定性

研究一类具有HollingⅢ型功能反应函数的捕食-食饵系统模型,通过建立适当的Lyapunov泛函,对模型进行定性分析,给出了系统的持久性、全局渐近稳定性的充分条件.     

逆变器电压电流瞬时值控制策略在UPS中的应用

介绍了一种基于电压、电流双环瞬时值反馈控制方法的UPS逆变部分的设计方案。建立了系统模型并阐述了控制环的设计。最后给出实验结果。     

气流床气化炉煤粉浓相气力输送综述

高压浓相煤粉气力输送是干煤粉气流床气化炉关键技术之一,文章从输送物料特性、输送相图、阻力特性及流动稳定性等方面评述了浓相粉体气力输送在近些年取得的研究进展,结合东南大学近年来在高压浓相煤粉气力输送领域获得的研究成果,系统地探讨了浓相气力输送过程中的流动特性,对今后浓相气力输送研究应开展的工作提出了建议。     

大干扰概率电压稳定评估方法的研究

在调研国内外电压稳定可靠性评估研究的基础上,基于电压稳定的定义和分类,并结合电力系统可靠性评估方法,提出大干扰概率电压稳定性的概念,基于该概念构造能够综合考虑暂态和长期电压稳定性的大干扰电压稳定的可靠性指标,制定概率电压稳定的综合评价原则,在此基础上,提出基于电力系统可靠性评估的大干扰概率电压稳定的评估方法及相应的算法流程。实际电网算例结果表明,所提方法能以定量评估指标直观地表达系统电压稳定的安全特性,有助于提高电力系统运行的可靠性。