Miscibility and morphology of poly(vinylidene fluoride)/poly[(vinylidene fluoride)‐ran‐trifluorethylene] blends

This study presents an investigation of the effect of the different crystalline phases of each blend component on miscibility when blending poly(vinylidene fluoride) (PVDF) and its copolymer poly[(vinylidene fluoride)‐ran‐trifluorethylene] [P(VDF–TrFE)] containing 72 mol % of VDF. It was found that, when both components crystallized in their ferroelectric phase, the PVDF showed a strong effect on the crystallinity and phase‐transition temperature of the copolymer, indicating partial miscibility in the crystalline state. On the other hand, immiscibility was observed when both components, after melting, were crystallized in their paraelectric phase. In this case, however, a decrease in crystallization temperatures suggested a strong interaction between monomers in the liquid state. Blend morphologies indicated that, in spite of the lack of miscibility in the crystalline state, there is at least miscibility between PVDF and P(VDF–TrFE) in the liquid state, and that a very intimate mixture of the two phases on the lamellar level can be maintained upon crystallization. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 1362–1369, 2002     

The effect of nitrogenous fertilizers on the nitrification of forest soils

The effect of fertilization with urea and ammonium nitrate on nitrogen mineralization was studied in a series of laboratory incubation experiments. The samples (humus layer) were collected from field experiments with different applications of fertilizers during a period of 11–14 years. The nitrogen fertilization influenced some chemical properties of the humus layer such as pH, N-Kjeldahl content and the content of inorganic nitrogen, especially in the samples from North Sweden. Nitrate nitrogen was formed in humus samples classified as non-nitrifying in several cases, usually after urea fertilization.     

Efficacy of tertiary butylhydroquinone on the storage and heat stability of liquid canola shortening

The sensory (odor and flavor) and physicochemical characteristics of tertiary butylhydroquinone (TBHQ) treated and butylated hydroxyanisole/toluene (BHA/BHT) treated liquid canola shortenings, subjected to accelerated storage (Schaal oven test at 65°C) and deep fat heating (at 185°C), were determined. Data for the Schaal oven test indicate that TBHQ was effective in retarding oxidative rancidity in liquid canola shortenings. However, addition of the commonly used mixture of BHA/BHT to canola shortenings resulted in only a slight decrease in oxidation during schaal oven storage. The results obtained from deep fat heating of canola liquid shortening show that neither TBHQ nor BHA/BHT was effective in enhancing oxidative and thermal stability of this product.     

基于Modbus/TCP协议实现人机界面与下位机通信

在以通用伺服电机控制系统为下位机的基础上,开发了以实时内核μC/OS-II、DSP、CPLD控制模块为核心的软硬件平台。通过移植uIP协议栈到DSP,在通信应用层上将Modbus帧嵌入到TCP帧中,简单可靠地实现了Modbus/TCP协议。同时将Modbus/TCP协议与μC/OS-II实时内核进行整合,更好地保证了系统调度的实时性。     

基于物联网技术的智能家居系统的研究

随着国际信息技术的发展,物联网已成为发展的主流;其中的智能家居系统,作为物联网发展的十大重点领域之一,也得到快速的发展.克服传统的智能家居系统内部有线组网的弊端,本文研究采用无线通信技术来组建家庭无线局域网的硬件系统,先对设计了总体的系统图,然后分别对硬件系统和软件系统分别进行设计,其中软件系统基于UC/OS-Ⅱ嵌入式操作系统的应用软件的开发,使用户操作起来更加方便,界面更加友好.     

Fabrication and Microstructure Characterization of Ti3SiC2 Synthesized from Ti/Si/2TiC Powders Using the Pulse Discharge Sintering (PDS) Technique

Ti/Si/2TiC powders were prepared using a mixture method (M) and a mechanical alloying (MA) method to fabricate Ti₃SiC₂ at 1200°–1400°C using a pulse discharge sintering (PDS) technique. The results showed that the Ti₃SiC₂ samples with <5 wt% TiC could be rapidly synthesized from the M powders; however, the TiC content was always >18 wt% in the MA samples. Further sintering of the M powder showed that the purity of Ti₃SiC₂ could be improved to >97 wt% at 1250°–1300°C, which is ∼200°–300°C lower than that of sintered Ti/Si/C and Ti/SiC/C powders using the hot isostatic pressing (HIPing) technique. The microstructure of Ti₃SiC₂ also could be controlled using three types of powders, i.e., fine, coarse, or duplex-grained, within the sintering temperature range. In comparison with Ti/Si/C and Ti/SiC/C mixture powders, it has been suggested that high-purity Ti₃SiC₂ could be rapidly synthesized by sintering the Ti/Si/TiC powder mixture at relatively lower temperature using the PDS technique.     

基于B/S的资料信息管理系统的设计和实现

该文介绍了基于B/S资料信息管理系统的设计和开发,重点阐述了资料信息管理系统的开发设计的难点和要点,同时提供了部分数据库表信息和代码。     

基于Web网的高校安全管理系统的设计与开发

为了解决高校安全保卫工作办公方式落后、管理水平低下等问题,开发了一套基于Web网的高校安全管理系统。介绍了系统设计和架构框图,并对系统功能做了进一步的实现,最后展示了运行效果。     

具有完整TCP/IP协议支持的U-Boot

在保护装置中最为稳定的引导程序U-Boot中实现了对该通用调试软件的通信协议的支持。基于U-Boot提供的独立应用开发框架,将独立的具有完整TCP/IP协议支持的lwIP协议栈移植至U-Boot。基于该协议栈以及U-Boot的独立应用开发框架,实现了对通用调试软件的复杂通讯协议的完整支持。经过上述技术改进,极大地扩展了通用调试软件的适用范围,加快了变电站工程实施中遇到的各种装置类似问题的解决速度。