Effect of hyperbranched poly(citric polyethylene glycol) with various polyethylene glycol chain lengths on starch plasticization and retrogradation

A series of hyperbranched poly(citric polyethylene glycol) (PCPEG) materials with varied polyethylene glycol (PEG) chain lengths as plasticizers were mixed with maize starch (MS) via cooking and film‐forming. The structure, pasting property, plasticization, aging property, moisture absorption and compatibility of plasticized starches were studied by means of Fourier transform infrared spectroscopy, X‐ray diffraction, rapid viscosity analysis, tension testing, moisture absorption measurements and scanning electron microscopy. Compared with PEG and citric acid, PCPEG was more effective in promoting starch chain movement and inhibiting the retrogradation of starch film. Also, PCPEG/MS had smaller moisture content. The longer the plasticizer chain, the better were the aging resistance and moisture resistance of starch. But with an increase of PEG chain length, mechanical properties of PCPEG/MS deteriorated and the compatibility between PCPEG and MS decreased. The hyperbranched derivative of PEG with longer chain exhibited improved plasticization and compatibility with starch. © 2019 Society of Chemical Industry     

水对食品相变的影响

水是食品材料中最重要的成分。本文介绍了食品中水的性质以及水对食品相变的影响，并从水活性、水的吸附性以及水的增塑性三方面描述了水在食品相变中所起的作用。另外，还着重分析了水对食品冻结温度的影响。     

高镁瓷工艺特性研究和应用

本文总结了ＭｇＯ－ＳｉＯ２－Ａｌ２Ｏ３系的高镁瓷配方、增塑及烧成工艺特性的研究过程与应用结果；介绍了适应大生产的高镁瓷制作工艺。     

聚氧化乙烯—聚磷酸钠共混物的钠离子导电性

研究了聚氧化乙烯-聚磷酸钠共混物的钠离子导电性和低分子量多缩乙二醇对共混物导电性的改进作用。结果表明,降低多缩乙二醇的分子量以及增加其含量都有利于提高共混物的离子导电率。增塑剂改进共混物导电性的实质是提高共混物的非晶相含量,共混物内钠离子传导发生在非晶区,聚合物链段运动是离子传导的主要推动力。     

Diluent effects on carbonate mobility in bisphenol-A polycarbonate in the solid state

The effect of miscible low molecular weight additives on the mobility of the carbonate group in bisphenol-A polycarbonate (BPAPC) has been studied using n.m.r. and dielectric relaxation experiments in the solid state. Proton-enhanced dipolar-decoupled carbon-13 n.m.r. spectra of BPAPC, isotopically enriched at the carbonate position, are obtained without magic-angle sample spinning. The resolved chemical shift anisotropy allows study of nuclear spin relaxation for the carbonate groups in the polymer that have different orientations relative to the static magnetic field in the laboratory frame. The spin-lattice relaxation time in the rotating frame (T_1?) is measured at a motional-probe frequency of 50 kHz for the undiluted polymer and for BPAPC-diluent blends containing either dibutylphthalate or dinitrobiphenyl. The T_1? exhibits some dependence on orientation in all systems studied. In the blend containing dibutylphthalate (DBP), T_1? is decreased by a factor of two for all orientations of the carbonate group. This implies that DBP substantially increases the spectral density of 50 kHz motions in the carbonate region of the polymer at ambient temperature. In contrast, dinitrobiphenyl does not significantly alter the Fourier component of thermal fluctuations at 50 kHz. Dielectric relaxation measurements at 10 kHz reveal that the primary (T_g) and secondary (β) motional processes in BPAPC are affected by low molecular weight additives. An intermediate relaxation process appears in the temperature interval between the glass transition temperature (T_g) and the sub-T_g β-relaxation (T_β) in the polymer-diluent blends. The n.m.r. spin-lattice relaxation rate in the rotating frame, T^?1_1?, correlates well with the relative magnitude of the dielectric dissipation factor (tan δ_ε) between T_g and T_β.     

Optimizing the mechanical and physical properties of thermoplastic starch via tuning the molecular microstructure through co‐plasticization by sorbitol and glycerol

Nowadays, environmental hazards caused by plastic wastes are a major concern in academia and industry. Utilization of biodegradable polymers derived from renewable sources for replacing common petroleum‐based plastics is a potential solution for reducing the problem. In this regard, starch has become one of the most promising alternatives to non‐biodegradable polymers for depleting plastic waste thanks to its low expense, abundance, renewability and biodegradability. However, the main drawbacks of starch are its poor processability, weak mechanical properties and severe hydrophilicity. In this work, thermoplastic starch (TPS) samples have been prepared using glycerol and sorbitol as co‐plasticizers in a laboratory co‐rotating twin screw extruder. Based on the mechanical test results, glycerol caused higher elongation to break but had lower tensile strength and elastic modulus compared to sorbitol plasticized starch. Fourier transform infrared spectroscopy and DSC results indicated that the hydrogen bond interaction between starch chains and plasticizers could be improved by replacing glycerol by sorbitol, which resulted in higher resistance against retrogradation proved by XRD results. TGA illustrated that the higher the sorbitol to glycerol ratio was, the more stable was the TPS. Using a proper amount of plasticizers (42 wt% total plasticizer, sorbitol to glycerol ratio 2:1) led to the preparation of a TPS sample with optimized properties including enhanced mechanical properties, high thermal stability, strong hydrogen bond formation and high resistance against retrogradation. © 2017 Society of Chemical Industry     

填充系数对橡胶连续塑炼机塑炼效果的影响

以新型连续塑炼机为实验平台,天然橡胶为生胶原料,考察了填充系数对天然橡胶连续塑炼效果的影响。结果表明,在塑炼段、销钉段和挤出段3段机筒和机头冷却水温度依次为40,50,60,70℃,转子转速为30 r/min,填充系数为60%的工艺条件下,连续塑炼机具有最好的塑炼效果,天然橡胶门尼黏度的下降幅度最大,塑炼胶更加均匀。     

换能器结构参数对聚合物超声塑化黏弹生热的影响

为研究超声换能器结构参数对聚合物超声塑化过程黏弹性生热的影响,首先确定超声黏弹性生热系统的组成,进行纵振超声换能器结构设计;然后分析超声黏弹性生热过程及超声黏弹性生热原理;最后采用单一变量法分析超声换能器的主要结构参数对其纵振频率及工具头前端质点最大振幅的影响,将其实际输出的纵振激励加载于熔融聚合物,研究其结构参数对聚合物超声黏弹性生热过程及达到聚合物玻璃化转变温度所用时间的影响。结果表明,随纵振激励作用时间的增加,聚合物温度非线性升高;放大比对聚合物温度变化影响最大,前盖板厚度和工具头长度次之,影响最小的是变幅杆长度。     

Adhesive Joint Durability Assessed Using Open-faced Peel Specimens

This paper presents an investigation of the durability of two aluminum-epoxy adhesive systems by means of open-faced peel specimens. A peel analysis model was used to determine the fracture energy from the peel data. Both wet and dry peel tests were conducted in order to distinguish between the reversible and the permanent effects of water. The effects of water on the cohesive properties of the adhesives were also assessed by tension tests. It was found that, for the two-part epoxy adhesive, which plasticized to a large extent, the peel testing should be carried out in a dry state to assess the interfacial weakening. It was also observed that the two-part adhesive was much stiffer in the dry, degraded state, and it was important to take account of such permanent changes in the cohesive properties associated with water uptake when determining the fracture energy from the peel data. In contrast, the one-part epoxy system did not suffer from appreciable cohesive changes, either reversible or permanent. In this case, both wet and dry failure loci were interfacial, and some of the interfacial damage was found to be reversible. Finally, surface analyses of the peel failure surfaces were carried out, and the formation of micro-debonds was identified as a possible mechanism of degradation for the two-part system.     

Design of New Cardanol Derivative: Synthesis and Application as Potential Biobased Plasticizer for Poly(lactide)

A novel biobased plasticizer made of cardanol is designed for poly(lactide) (PLA). This cardanol‐derived plasticizer, i.e., methoxylated hydroxyethyl cardanol (MeCard), is synthesized through methoxylation of the double bonds on the side chain of cardanol, and characterized by ¹H NMR and mass spectrometry. The plasticization effect of MeCard on the molecular structure, morphology, thermal and mechanical properties of PLA is evaluated and compared to that of a commercial cardanol, i.e., hydroxyethyl cardanol (pCard). The plasticization efficiency of MeCard is demonstrated by a substantial decrease of the glass transition temperature and storage modulus together with a significant increase of the elongation at break as compared to neat PLA. Moreover, MeCard exhibits higher plasticization performance than pCard toward PLA. Such behavior is related to a higher miscibility and compatibility between PLA and MeCard thanks to the methoxylation of the double bonds on the side chain of cardanol as shown by SEM micrographs.