塑料土工格栅力学行为研究--Ⅰ.短周期力学行为的分析

测试并记录土工格栅试样的蠕变伸长随时间的变化情况,得到试样应变和时间的关系.应变-时间关系显示载荷较小时,蠕变发展缓慢;载荷较大时,蠕变应变较大且发展较快.由应变-时间关系得到了应变速率-应变关系和等时载荷-应变关系,由此可评价试样蠕变发展的趋势,确定蠕变应变极限.这些工作为进一步对土工格栅长期蠕变行为研究做好了准备.     

世界塑料添加剂行业的发展动向

回顾了过去一年来世界塑料添加剂行业的发展变化；讨论了塑料行业及添加剂行业目前的一些特点，诸如整合、涨价、发展重点东移、中国因素的影响，新产品、新技术发展的市场及法规方面的推动力；简述了在新产品方面的最新发展，包括PP纤维及无纺材料专用添加剂、PET及工程塑料用添加剂、PVC用添加剂、耐候性阻燃体系、紫外线阻隔剂、纳米无机粉体等产品。同时还讨论了立法及环保方面的进展。     

Ways of strengthening biodegradable soy‐dreg plastics

Biodegradable plastics (GSD) based on soy dreg (SD) were prepared by compression‐molding, with glycerol as the plasticizer and glutaraldehyde (GA) as the cross‐linker. The structure and properties of the GSD sheets were investigated by Fourier‐transform infrared spectroscopy (FTIR), X‐ray diffraction (XRD), differential scanning calorimetry (DSC), dynamic mechanical thermal analysis (DMTA), scanning electron microscope (SEM), and tensile test methods. The results indicate that when GA content was 6.8%, the tensile strength (σ_b) of the sheet reached the maximum value of 14.5 MPa. Moreover, the strength and water resistance of the sheets coated with castor‐oil‐based polyurethane/nitrochitosan interpenetrating network (IPN) coating were significantly enhanced to 24.6 MPa in the dry state and 9.8 MPa in the wet state. Simultaneously, the test of biodegradability of the GSD sheet in a mineral salts medium containing microorganisms and agar proved that GSD could be fully biodegradable. This work has provided a novel way to utilize low‐cost SD to prepare biodegradable plastics. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 422–427, 2003     

火焰喷涂塑料粉末

介绍了塑料粉末火焰喷涂的原理、装置及工艺,聚乙烯、EVA树脂、尼龙、聚苯硫醚、氯化聚醚等涂层材料,以及这些涂层材料的耐腐蚀性能。     

Mechanical properties of biorenewable fiber/plastic composites

Plastic fiber composites, consisting of polypropylene (PP) or polyethylene (PE), and pinewood, big blue stem (BBS), soybean hulls, or distillers dried grain and solubles (DDGS), were prepared by extrusion. Young's modulus, tensile and flexural strengths, melt flow, shrinkage, and impact energy, with respect to the type, amount, and size of fiber on composites, were evaluated. Young's moduli under tensile load of wood, BBS, and soybean‐hull fiber composites, compared with those of pure plastic controls, were either comparable or higher. Tensile strength significantly decreased for all the PP/fiber composites when compared with that of the control. Strength of BBS fiber composites was higher than or comparable to that of wood. When natural fibers were added there was a significant decrease in the melt flow index for both plastic/fiber composites. There was no significant difference in the shrinkage of all fiber/plastic composites compared to that of controls. BBS/PE plastic composites resulted in higher notched impact strength than that of wood or soybean‐hull fiber composites. There was significant reduction in the unnotched impact strength compared to that of controls. BBS has the potential to be used as reinforcing materials for low‐cost composites. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 2484–2493, 2004     

塑料老化性能及使用寿命预测的新方法

提出了利用人工神经网络方法对塑料自然老化性能时间序列进行预测的方法，并建立了计算模型，在此基础上本方法也可对塑料使用寿命进行预测。实例计算证实了这种方法具有良好的精度。     

塑料充模流动粘性模型研究

对多种塑料在不同温度下的剪切速率一稳态剪切粘度数据进行Cross粘性模型参数拟合，得到了表征材料粘度的模型参数(B，Tb，τ^*，n)。其拟合效果良好，能较准确地描述塑料熔体在一定剪切速率和温度范围内的粘流特性，为工程计算和塑料熔体模流分析提供了数据支持。结果表明，该方法有较广泛的适用性。     

泡沫塑料加工过程中的气泡成核理论(Ⅱ)——剪切能成核理论及其发展

介绍了剪切流场中泡沫塑料加工的气泡成核理论,分析评述了剪切流场中泡核拉伸模型、空穴成核模型对气泡成核机理的解释及存在的不足;对静态熔体中气泡成核过程进行了能量描述;介绍了最新的气泡成核中的剪切能成核理论,该理论较完善地解释了剪切流场中气泡成核过程;最后指出了气泡成核理论研究的发展方向。     

塑料抗菌剂国内外开发现状及市场分析

阐述了抗菌剂的种类及其作用机理,详细介绍了塑料抗菌剂的国内外市场、开发现状及发展趋势,对今后国内市场进行了预测,并提出了我国塑料抗菌剂的发展建议。     

我国塑料助剂生产现状与发展趋势

简述了我国塑料助剂生产现状、市场供需及发展方向，“十五”期间我国塑料助剂工业发展势头强劲，目前已基本满足我国塑料工业的发展需求，但是在品种和产品质量等方面与国外先进水平相比仍有较大的差距。提出了提高我国塑料助剂国际市场竞争力的措施。