聚乙烯工艺及催化剂新进展

综述国内外聚乙烯生产工艺及其催化剂的最新进展，对国内如何开展这方面的工作提出了几点建议。     

无间隙原子钢的微观结构特征和塑性应变比

采用Ｘ射线衍射的ＯＤＦ和ＬＰ分析技术，ＳＥＭ电子通道花样和蚀坑技术观测，研究了超深冲无间隙原子钢板的微观结构特征。结果表明：控制化学成分、保证基体纯净、优选工艺参数，促进强的γ－〈１１１〉∥Ｎ．Ｄ纤维织构的形成是获得优异成型性的关键。用ＣＭＴＰ方法，由ＯＤＦ织构数据从理论计算了塑性应变比（ｒ），表明ｒｍ值高达３．１８。文中讨论了再结晶织构形成机制。     

Degradation of polyethylene terephthalate films in the presence of lubricants for HFC 134a: a critical issue for hermetic motor insulation systems

Earlier studies conducted in the use of sealed tubes with polyalkylene glycol lubricants and polyethylene terephthalete (PET) films revealed that the PET films exhibited embrittlement and (visual) degradation. This led to an investigation of PET embrittlement mechanisms with the new lubricants used with HFC 134a. The lubricants studied were three polypropylene glycols (the monol, the diol and the completely end-capped glycols), pentaerythritol ester and a blend of monol and ester. The effects of moisture content, temperature and lubricant structure were studied. All lubricants in this study were of viscosity grade ISO-32 (150 SUS). The results were compared to PET film embrittlement in the presence of CFC 12 and mineral oil. This study reconfirmed the earlier findings that the PET films must be dried to lower than 0.1 wt.% moisture content for use in hermetic systems. This paper discusses the effect of the moisture content of the lubricant and the effect of the lubricant structure on PET films. The dependence of the various mechanisms on temperature is shown. Esters and end-capped polyalkylene glycols are recommended for use with HFC 134a.     

Influence of Storage Time and Temperature on Absorption of Flavor Compounds from Solutions by Plastic Packaging Materials

ABSTRACT: Linear low-density polyethylene (LLDPE), oriented polypropylene (OPP), polycarbonate (PC), polyethylene terephthalate (PET film and PET bottle), and polyethylene naphthalate (PEN) were stored in a model solution containing 10 flavor compounds at 4, 20, and 40 °C and flavor absorption by the plastic materials was followed in time. The absorption rate and/or total amount absorbed increased considerably with temperature from 4 to 40 °C. Depending on storage temperature, total flavor absorption by the polyolefins (LLDPE and OPP) was 3 to 2400 times higher than by the polyesters (PC, PET, and PEN). Therefore, in the factor of flavor absorption, polyesters are preferred over polyolefins as packaging material.     

Polyethylene mixed crystal infra-red spectroscopy: The influence of matrix isotopic species on guest conformation

The chain conformation of solution-crystallized polyethylene has previously been confirmed by infra-red spectroscopy, using the CD₂ bending bandshape for samples with a minority of the deuterated species^1–3. The method of calculating the i.r. band profile from molecular conformational models is now developed to give a more accurate representation of doublet splittings and to include the singlet component. The CH₂ bending profile is calculated for samples with a deuterated matrix, and the good agreement with experimental data indicates that the same molecular model is applicable for samples with the deuterated polymer as either guest or matrix, for identical crystallization conditions. This result implies that isotopic fractionation is unimportant under these conditions.     

N.m.r. study of the ferroelectric phase transition in a 7030mol% copolymer of vinylidene fluoride (VF2) and trifluoroethylene (TrFE)

Nuclear magnetic resonance (n.m.r.) studies of ¹⁹F nuclei in a $\text{70}\text{30}\text{mol}\text{\%}$ random copolymer of vinylidene fluoride and trifluoroethylene were performed at 9.14 MHz and 20.0 MHz. The free induction decays (FIDs) were analysed in terms of two T₂ components attributed to the amorphous and crystalline portions of the polymer. The changes in crystallinity as well as the effects of the ferroelectric transition were observed during cycles of heating and cooling between 20°C and 140°C. The crystalline component of the FID lengthens by a factor of 2 at 100°C on heating and decreases by this factor at 60°C on cooling, thus exhibiting the thermal hysteresis of this ferroelectric transition. The spin-lattice relaxation was also investigated. From measurements at 9.14 MHz the observed longitudinal relaxation time T₁ appears to be dominated by the dynamics of the amorphous phase and exhibits no anomaly through the phase transition. However, from measurements at 20 MHz, well defined minima of T₁ were observed, which are associated with the ferroelectric transition (especially after repeated annealing of the samples). Results are discussed in terms of the crystalline phase structure, which appears dynamically disordered above the ferroelectric phase transition. An analogy is considered with the plastic phase transitions encountered in molecular crystals.     

In Situ Formation of a Novel Nanocomposite Structure Based on MCM-41 and Polyethylene

M41S materials are prepared by in situ assembly of inorganic precursors and organic template and can be viewed as nanocomposites of the siliceous phase and organic surfactant. Calcination of these precursors gives the M41S materials that have been used to prepare novel nanocomposite structures, in which the organic phase inside the nano-sized pores is isolated by the nano-sized inorganic pore walls. The nanocomposite structures can be formed by in situ polymerization of monomers inside the channels. Polymerization of ethylene takes place inside the nano-sized pores, producing the desired nanocomposite structure. The resulting polyethylene was found to be a mixture of crystalline and amorphous phases.     

掺染料激光介质的研究

以PMMA为基质，在助溶剂的作用下掺杂激光染料Rh6G制备出了塑料激光介质样品，采用YAG激光器作为泵浦源测试了塑料激光介质的发射光谱，讨论了其激光发射机理。