Electro-organic synthesis without supporting electrolyte: Possibilities of solid polymer electrolyte technology

The application of ion exchange membranes as solid polymer electrolytes (SPE) in fuel cells is state-of-the-art. This technology needs no supporting electrolyte; consequently it can be applied for electro-organic syntheses in order to save process steps. In this case the process is not predetermined to a maximized energy efficiency so that the selection of the cell design, of the electrode materials and of the operating conditions can be focused on a high selectivity of the electrode reactions. The electro-osmotic stream, which is caused by the solvation shells of the ions during their migration through the membrane, and hence is a typical property of SPE technology, has a significant effect on the electrode reactions. It generates enhanced mass transfer at the electrodes, which is beneficial for reaction selectivity. It can be influenced by the choice of, and possibly by the preparation of, the membrane. An additional remarkable advantage of SPE technology is the exceptional long durability of oxide coated electrodes. By combination of several process engineering methods stable operation of SPE cells has been realized, even for examples of non-aqueous reaction systems. Experiments up to 6000 h duration and in cells of up to 250 cm² membrane area show the potential for industrial application.     

一个新颖的轮廓线跟踪算法

提出了一个新颖的基于隐马尔科夫模型与光流的轮廓线跟踪算法。曲线描绘由B样条形状空间向量来表达,能够捕捉全局和局部变形。提出应用沿曲线的光流计算来预测曲线在下一帧的位置,在预测曲线的基础上,提出应用隐马尔科夫模型来准确定位曲线的位置。隐马尔科夫模型提供了一种有效的概率手段来融合多种量测特征比如边缘,曲线平滑性,区域灰度或颜色统计信息等等,能够更准确的定位曲线位置。基于仿射形状空间的实验了表明本文所提出算法的有效性。     

掺气减蚀保护作用的新概念

利用针式掺气流速仪测量原型和模型掺气浓度场、流速场，气泡尺寸及其概率分布的研究成果表明，原型水流韦伯数高，形成微小气泡的能力比模型强，气泡上浮慢，接近底部的小尺寸气泡概率及掺气浓度比模型大。初步研究认为：0.2mm或0.5mm以下的微小气泡在掺气减蚀中起着主要作用，可能只要很小掺气浓度即可达到掺气减蚀的效果。因此以小尺寸气泡的掺气浓度，作为判断掺气减蚀保护作用的指标将更为准确。     

Collection Conduits Including Subsurface Drains

Numerous types of pipes and channels with spatially increasing flows in environmental engineering applications are identified by type and function and referred to as collection conduits. An overview of methods for designing and analyzing collection conduits is provided. Full conduits with nonuniform and uniform inflow are first considered. Dimensional analysis is then employed to demonstrate the relationship between variables for open channels; that leads to the identification of possibilities for generalized numerical solutions. Prior collection conduit applications are discussed within the framework of the dimensional analysis (which also pertains to some constant-flow applications). A previously unpublished generalized numerical solution for rectangular collection conduits is presented. Subsurface drains are addressed with particular emphasis, including the use of numerical methods to develop a new generalized chart and relation to other design methods. Among the important conclusions for subsurface drains is that the somewhat common practice of using Manning’s equation alone for such problems is not generally adequate. Examples and practical design suggestions are included, and the use of computer-based numerical methods is discussed more generally.     

Effects of diacrylate monomers on the bond strength of polymer concrete to wet substrates

The bond strengths of polymer concretes containing up to 15% (based on polymer resin) of diacrylate (DA) monomers were examined and compared with those without DA. A change occurring with the addition of DA monomers was an increase in the bond strength of polymer concrete to wet substrates. Zinc diacrylate (ZDA) and calcium diacrylate (CDA) were each used as an additive to monomers and resins [methyl methacrylate (MMA), polyester, and two kinds of epoxies]. The variables were amount of the DA monomers and surface conditions (wet or dry and smooth or rough). Bond strengths were measured by tension bond. ZDA was found to improve the bond strength of MMA and polyester, whereas CDA improved the bond strength of epoxies. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 991–1000, 2003     

大型连杆流线简易试验方法

介绍了一种大型连杆流线的简易试验方法及其评价原则。该方法可清晰显示流线，并适合任何尺寸和形状的锻造连杆的流线试验。     

哈得4联合站技术改造

位于塔克拉玛干大沙漠腹地的哈得4油田,2004年成为全国最大的沙漠油田,2005年产量达到200×104t。在对联合站存在问题逐一分析的基础上,提出了技术改造的措施。现场采集的运行数据表明技术改造效果明显,增强了流程可靠性,提高了自动化水平,降低了能耗。     

自喷井电动清蜡绞车的研制

针对目前石油钻采用清蜡绞车总体结构设计不合理以及实用性不强等技术难题,研制开发了自喷井电动清蜡绞车。该绞车的核心部件包括过载保护安全装置、牙嵌离合器轴套、自动/手动互换装置、计量装置以及密封装置。在清蜡绞车自动工作中,当清蜡刮刀遇到较大阻力时,清蜡绞车将接收到反馈信号,可实现智能停车,自动转换为手动状态,以便操作人员检查和排除故障,从而确保了操作的安全性,延长了设备的使用寿命。1000余台电动清蜡绞车的现场应用表明,该产品可以大大降低原油的开采成本,具有良好的经济效益和社会效益。     

WuM1-1羽状分支水平井充气钻井液技术

WuM1-1井由1口多分支水平井和1口采气的直井组成。该井斜井段短,井斜率在30°/100 m以上,主井眼和10个分支井段总进尺6182 m,98%以上在煤层中钻进,煤层脆、压实性较好,更易发生掉块。为满足钻井对井壁稳定性、润滑性、井眼净化以及煤层保护等的要求,采用钾铵基聚合物防塌钻井液进行充气欠平衡钻井,在钻进中保持钻井液有合适的粘度、切力,选用合适的注气压力和注气量以及当量钻井液密度;每钻完一个立柱坚持循环几分钟,上下划眼一次,并泵入CMC高粘钻井液,配合有效使用固控设备,尽量使井眼干净;复配使用粉末状固体润滑剂和液体润滑剂。该钻井液性能稳定,易于维护,悬浮携岩能力强,润滑性好,井眼畅通,保证了WuM1-1井安全、快速、优质施工。该井在煤层钻进中无阻卡现象,井壁稳定,没有出现井壁掉块或井垮现象,水平连通一次成功,10口分支井悬空侧钻一次成功,只用57 d即顺利完井,比该地区常规钻井快49倍。     

Spin probe study of semi‐interpenetrating polymer networks based on polyurethane and polymethacrylate functional prepolymers

The motional transition and heterogeneity of semi‐interpenetrating networks (SIPNs) based on polyurethane (PU) with carboxylic groups and methacrylic copolymer (PM) with tertiary amine groups were studied by the electron spin resonance (ESR) spin probe method. The concentration of functional groups in both prepolymers varied from 0 to 0.45 mmol g^?1. Spin‐probed SIPNs show that the temperature‐dependent spectra are sensitive to polymer interactions imposed by functional groups. These interactions determine the free volume distribution in the matrix and temperature at which motional transition takes place. The fraction of free volume increases with functional group concentration and reaches its maximum at 0.25 mmol g^?1. Further increases in the functional group concentration reduce the free volume. The results of the networks with strong interactions are discussed in terms of the interference of the plasticizing effect of the PU component and the formation of possible cluster cross‐links, which restricts segmental motions. Copyright © 2003 Society of Chemical Industry