Novel blood-compatible waterborne polyurethane using chitosan as an extender

A series of novel block polymers of polyurethane (PU) and chitosan have been prepared in two steps. The first step is the preparation of PU prepolymer, obtained from polytetramethylene oxide glycol (PTMO, M_n = 1000), isophrone diisocyanate (IPDI), and 2,2′-dimethylol propionic acid (DMPA), followed by ionizing PU prepolymer with triethylamine (TEA). The second step involves PU chain-extended by water-soluble chitosan of low molecular weight (M_n = 5000) by self-emulsion polymerization method. The sizes of the latex particles, morphology, and copolymer architecture have been characterized by dynamic light scattering (DLS), general tensile test, infrared spectroscopy (IR), surface contact angle measurement, and transmission electron microscopy (TEM). Furthermore, it shows that the addition of chitosan remarkably increases anticoagulative property of PU elastomers confirmed by the recalcification time. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

二甲基乙醇胺在高回弹聚氨酯泡沫中的应用

分别采用二甲基乙醇胺(DMEA)和二月桂酸二丁基锡(DBTL) 2种催化剂制备了高回弹聚氨酯(HRPU)泡沫塑料.探讨了DMEA和DBTL对HRPU泡沫组合料反应活性、流动性及制品物理性能、热稳定性的影响.结果表明,以DMEA作催化剂的HRPU泡沫物理性能、热老化性及工艺稳定性优于DBTL催化剂,DMEA可以替代DBTL应用于HRPU泡沫塑料.     

光纤光栅视觉系统

利用光学衍射原理，研制成了光纤光栅衍射屏，并与计算机神经网络相结合，开发了了一种识别立体形状的视觉系统。本文介绍了光纤光栅的设计原理及计算方法，给出了系统的总体结构及工作原理，完成了三棱 柱，三棱锥、四棱柱，四棱锥和球等立体形状学习与识别，并讨论了实验结果。     

六通道瞬态光学高温计

六通道瞬态光学高温计是在可见光和近红外光谱范围内 ,把光源的热辐射取出六个波段进行测量。每个波段信号通过各自的光纤传输、光电倍增管探测和记录仪器记录。系统的时间分辨率小于 30 ns,冲击温度测量范围为 2 30 0～ 90 0 0 K,测量误差小于 5 % ,给出了以碘化钠、硝基甲烷和空气为样品的若干实验结果     

组合式光纤流量传感器

提出了一种新型的组合式光纤流量传感器，介绍了它的工作原理，详细讨论了光脉冲转换器的设计要点，据此设计了传感头，并给出了它的实验结果。     

The effect of fibre alignment on composite strength: II. The strength of angle-ply laminates

Experiments have been carried out on relatively wide angle-ply laminate samples with very short gauge lengths. These proved to be very much stronger than samples tested in earlier work, and which form the basis for our present design with these materials. It is highly likely that the early results for strength were more indicative of edge effects than true laminate strength. This is confirmed by data from tests on pressurized tubes. A review of the literature on this shows that such tests produced results which can be an order of magnitude higher than the early laminate tests. Thus our design calculations could well be severely underestimating the potential strength of angle-ply laminates. This may be having serious consequences for the aerospace industry, through the use of design criteria for strength which may be too conservative. Single-fibre experiments may pave the way for more realistic estimates of angle-ply laminate strengths. These indicate that a simple one-third power rule can be used to estimate the potential strength. However, this is purely ad hoc at present, and needs to be put on a firmer footing through both theoretical and experimental studies. Furthermore, if this approach is adopted, edge effects will still have to be allowed for, and estimated on the basis of the aspect ratio of the part.     

贮存稳定的聚氨酯干式复合胶粘剂的研究

研制了一种具有高固含量、低粘度的干式复合用双组分聚氨酯胶粘剂，考察了聚酯多元醇，扩链剂丙三醇／乙二醇（摩尔比）、NCO／OH（摩尔比），双组分胶配比以及缓凝剂等因素对该胶粘剂性能的影响，并用红外光谱对胶的固化过程进行了表征。结果表明，该胶粘剂具有较高的粘接强度，优良的低温流动性和贮存稳定性。     

Pultruded fibre reinforced polyurethane composites II. Effect of processing parameters on mechanical and thermal properties

This paper presents a novel process for the fabrication of pultruded polyurethane (PU) composites. The effects of the processing parameters on the mechanical properties (flexural strength and flexural modulus, etc.) and thermal properties (HDT) of the fibre reinforced PU composites by pultrusion have been studied. The processing parameters investigated include pulling rate (in-line speed), die temperature, filler type and content, and post-cure time and temperature. Results show that the composites possessed various optimum pulling rates at different die temperatures. On the basis of the DSC diagram, the swelling ratio, the mechanical properties and the thermal properties of composites, the optimum die temperature can be determined. It is found that the mechanical and thermal properties increase with filler content for various types of filler. The mechanical and thermal properties increase at a suitable post-cure temperature and time. Furthermore, the properties which decreased due to the degradation of composite materials for a long post-cure time will be discussed.