煤层注水促抽瓦斯及其影响因素的数值模拟

为有效预防煤矿瓦斯灾害,获取煤层注水促抽瓦斯的合理参数,以常村煤矿2103工作面为例,依据多相渗流理论,采用Fluent软件的VOF模型及多孔介质模型耦合求解,对煤层注水促抽瓦斯技术及其影响因素进行数值模拟,并将模拟结果应用于现场,对比分析数值模拟与现场实测数据,二者基本吻合.研究结果表明:煤层瓦斯含量以注水孔为中心径向逐步降低,以抽采孔为中心径向逐步升高;注水前抽采阶段,随着抽采时间的增加,抽采范围逐渐增大,抽采孔瓦斯流量先快速下降,后逐步缓慢降低;注水促抽阶段,随着注水时间的增加,注水范围逐渐增大,注水流量逐步降低,煤层瓦斯含量缓慢升高,抽采孔瓦斯流量逐渐增加;注水后抽采阶段,随着抽采时间的增加,压力水覆盖范围持续增大,煤层瓦斯含量逐渐降低,抽采孔瓦斯流量逐渐减小.注水时机、注水时间、注水压力、注水方式、布置方式及钻孔间距是影响煤层注水促抽瓦斯效果的6个主要因素.瓦斯正常抽采20 d后,按照一注一抽方式及5 m间距布置注抽钻孔,在8 MPa煤层注水压力下间歇注水10 d,煤层注水促抽瓦斯效果较好.     

裸置海底自沉降热油管道泄漏扩散的数值研究

根据计算流体力学建立海底海泥区域与海水区域的流固耦合传热多相流模型,海泥区域视为饱和含水多孔介质。运用软件模拟了裸置在海底的热油管道在输送过程中泄漏后原油在海泥和海水中的分布情况和温度场的变化情况,并对不同的泄漏点进行了分析。模拟时考虑了裸置海底管道的自沉降和海水中压强的影响。模拟结果表明,泄漏点对泄漏原油的扩散分布有很大影响;当泄漏点在土壤区域开始泄漏时,原油在土壤中呈弧形分布,过一段时间后沿土壤与管道外保温层流入海水中,顶端呈现喷射形,两侧呈螺旋状,并逐渐向海面流动;当泄漏点在海水区域时,泄漏的原油呈现喷射形,在浮力的作用下逐渐向海面流动;泄漏位置不同,海水和海泥温度场的分布有很大差异。海水区域和海泥区域的交界面对原油分布和温度场分布有很大影响。     

不同造孔剂对CaCu3Ti4O12多孔陶瓷介电性能的影响

以碳粉和蛋清作为造孔剂,利用固相法制备CaCu3Ti4O12(CCTO)多孔陶瓷.研究了造孔剂含量对CCTO多孔陶瓷体积密度、显微结构和介电性能的影响.结果表明,随着碳粉含量增加,体积密度先增加后减小;而随着蛋清含量增加,体积密度先减小后增加.和碳粉相比,蛋清加入制备的试样具有较小、较均匀的孔隙.当频率大于331.5KHz时,添加碳粉可以降低介电损耗.当频率大于4KHz时,添加碳粉介电常数有所下降.当频率大于2KHz时,添加蛋清可以增大介电损耗,但是增加幅度较小.添加蛋清可以增大介电常数.     

Numerical Simulation and Analysis of Migration Law of Gas Mixture Using Carbon Dioxide as Cushion Gas in Underground Gas Storage Reservoir

One of the major technical challenges in using carbon dioxide（ CO2） as part of the cushion gas of the underground gas storage reservoir（ UGSR） is the mixture of CO2and natural gas. To decrease the mixing extent and manage the migration of the mixed zone,an understanding of the mechanism of CO2and natural gas mixing and the diffusion of the mixed gas in aquifer is necessary. In this paper,a numerical model based on the three dimensional gas-water two-phase flow theory and gas diffusion theory is developed to understand this mechanism. This model is validated by the actual operational data in Dazhangtuo UGSR in Tianjin City,China.Using the validated model,the mixed characteristic of CO2and natural gas and the migration mechanism of the mixed zone in an underground porous reservoir is further studied. Particularly,the impacts of the following factors on the migration mechanism are studied： the ratio of CO2injection,the reservoir porosity and the initial operating pressure. Based on the results,the optimal CO2injection ratio and an optimal control strategy to manage the migration of the mixed zone are obtained. These results provide technical guides for using CO2as cushion gas for UGSR in real projects.     

多孔碳板气-气增湿器新型设计方法

多孔碳板是一种具有高孔隙率和高导热性能的多孔材料,适合制作燃料电池增湿器,针对这一特性,提出了一种多孔碳板气-气增湿器的基本结构,以停留-扩散时间比和流道内气体流速为设计依据,提出了多孔碳板气-气增湿器的优化设计流程。通过优化设计,使增湿器在燃料电池所需气体流量的条件下工作时,停留-扩散时间比与气体流速均在一定范围之内,既保证增湿器的增湿效率较高,又保证增湿器体积不至于过大。根据该设计方法为一个25 kW燃料电池系统设计了多孔碳板气-气增湿器,能满足增湿要求。     

乙二醇和不同相对分子质量聚乙二醇对聚氨酯多孔膜性能的影响

采用乙二醇和不同相对分子质量的聚乙二醇作为聚氨酯多孔膜的致孔剂,通过对聚氨酯多孔膜的电镜图、透湿性、接触角以及拉伸性能的表征与分析,探究乙二醇和不同分子量聚乙二醇的用量对聚氨酯微孔膜结构和性能的影响。结果表明：采用乙二醇,添加量在50％时,透湿量达到2929 g/（m2· d ）;断裂强力与断裂伸长率分别在5．77 M Pa ,451．3％,说明得到的聚氨酯多孔膜具有较高的透湿量、孔隙率以及较强的拉伸性。     

Atomic and micro-structure features of nanoporous aluminosilicate glasses from reactive molecular dynamics simulations

Long-term chemical durability of borosilicate glasses that makes them a widely accepted form of nuclear waste disposal is achieved through the formation of a porous aluminosilicate gel layer that provides passivity and limits the transport of water to the reaction front. Detailed understanding of the porous silicate gel layer is thus critical in elucidating the corrosion mechanism of these glasses and to design of new glass composition for waste immobilization and other applications. In this paper, we use the diffuse charge reactive potential to generate porous aluminosilicate glass structures with compositions equivalent to the gel layers formed at the glass-water interface with an aim to understand the processing condition on the microstructure and atomic structure of these systems. We demonstrate the use of the charge scaling techniques is an effective approach to generate these porous structures with controllable pore mophologies. After initial validation of the potentials and calcium aluminosilicate glass structures using neutron diffraction, we created gel structures with compositions similar to well-known model nuclear waste borosilicate glasses. The porosities and the pore size distribution bear a strong correlation to the processing temperature, as well as to the local atomic structure. Thus, by controlling the processing parameters, the generated porous structures can be customized to closely resemble gel structures due to borosilicate glass corrosion. These results provide insights of the micro- and atomic structure features of the porous aluminosilicate glasses and on the optimal procedure to generate porous structures that can be comparable to experimentally observed gel layer structures thus to elaborate on the correlations between the structure and phenomena in glass-water interactions.     

Effects of thickness and hydrophobicity of double microporous layer on the performance in proton exchange membrane fuel cells

In this paper, a multi-layer gas diffusion layer (GDL) is designed. The GDL consists of a single carbon paper backing layer and dual microporous layers (MPLs). Moreover, the effects of thickness and hydrophobicity of double MPL on the performance of proton exchange membrane fuel cells are investigated. From the test results of the water contact angle, conductivity, pore size distribution, and the polarization curve, it is found that the thickness adjustment increases the number of 0.5 to 7 μm and 20 to 100 μm pores in GDL, which is more conducive to water discharge. Therefore, the thickness adjustment is more favorable to the cell performance under high humidity. While the gradient hydrophobic design makes the MPL of the modified intermediate layer have a certain water-retaining capacity to humidify the reaction gas, which has better effect under low humidity. At last, the results show that the optimized GDL meets a limit power density of 1.772 W/cm² under 60% humidification and 1.600 W/cm² under 100% humidification.     

Effects of the molecular structure from pitch fractions on the properties of pitch-based electrospun nanofibers

Mesophase pitch was separated into different pitch fractions to investigate the effect of pitch fractions on the properties of their nanofibers prepared by electrospinning. The evolution of different pitch fractions-derived nanofibers during stabilization and carbonization were explored, and the properties of the resultant carbon nanofibers (CNFs) as electrode materials for supercapacitor were compared. Results indicated that the hexane insoluble-toluene soluble (HI-TS) and toluene insoluble-tetrahydrofuran (THF) soluble (TI-THFS) fractions had good spinnability due to their narrow molecular weight distribution. Moreover, compared with HI-TS and THF insoluble (THFI), TI-THFS consisted of appropriate aromaticity and branched alkyl groups which promoted the stabilization and carbonization behaviors of its nanofibers, resulting in maintaining ideal fiber morphology of TI-THFS-derived nanofiber due to the mitigation of their exothermic reactions. Meanwhile, the TI-THFS-derived CNFs presented the highest surface area of 543 m² g⁻¹ and exhibited an excellent specific capacitance of 167 F g⁻¹ at 0.5 A g⁻¹ in 6 M KOH electrolyte.     

Rapid preparation of hierarchically porous ceramic microspheres based on UV-curing-assisted molding

Ceramic microspheres have attracted significant attention, while the preparation of hierarchically porous ceramic microspheres with high porosity, good sphericity, and controllable size or shape in a short time remains a challenge. Herein, we developed a highly adaptable methodology for the preparation hierarchically porous ceramic microspheres with high porosity and favorable shape in a short time. The UV-curing assisted molding method combined with the Pickering emulsion method was utilized to prepare hierarchically porous ceramic microspheres. Under the irradiation of a UV-curing lamp (395 nm, 50 W), the Pickering emulsion can be cured within as short as 10 s. The microstructures of the three microspheres with different shapes were characterized by scanning electron microscopes (SEM). The as-prepared microspheres had a high sphericity, the interconnectivity of pores was as high as 54 %, and its porosity was as high as 73.4 % ± 3.0 %, while the density was quite low at ∼ 1.02 g/cm³.