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991.
对比研究了电解加钛和含钛或硼中间合金对铝的晶粒细化效果及抗高温衰退能力的影响.结果表明,电解加钛和Al-5Ti中间合金在熔体温度较低时具有较好的晶粒细化效果,但随着熔体温度的升高,细化效果均迅速衰退;电解加钛再熔配加Al-4B中间合金可在熔体温度为720℃时获得最佳的细化效果,随着熔体温度的升高细化效果有所衰退,但衰退速度较慢;在加入Al-5Ti的同时加入Al-4B中间合金可明显提高Al-5Ti的晶粒细化效果和抗高温衰退能力,但效果不如电解加钛加Al-4B中间合金;Al-5Ti-1B中间合金具有最强的抗高温衰退能力,随着熔体温度的升高,晶粒不但不粗化反而有所下降,当熔体温度高于900℃时,才出现衰退现象.对试验结果及晶粒细化机制进行了分析. 相似文献
992.
The crystallization process of Pd74Si18Au8 amorphous alloy has been investigated by transmission electron microscopy, small angle X-ray scattering and three-dimensional atom probe techniques. Although literature suggests that the alloy decomposes into two glassy phases prior to the crystallization, we found that the crystallization occurs directly from a single amorphous phase by the primary crystallization of fcc Pd–Au solid solution, followed by the polymorphous crystallization of the remaining amorphous phase to a Pd3Si phase. 相似文献
993.
研究贝氏体相变的特点,弄清贝氏体相变反应与共析分解的区别极为重要。本文应用QUANTA--400环扫电镜和JEM-2010高分辨电镜观察了多种钢的珠光体和贝氏体组织形貌和亚结构。综合以往的研究资料,从表象到本质上分析了贝氏体相变的特征,阐述了贝氏体相变与共析分解的区别。认为:贝氏体相变具有过渡性特征,贝氏体相变绝非共析分解。有的学者将贝氏体相变说成是共析分解的延续,那是不正确的。从贝氏体的物理本质出发,提出了钢中的珠光体、贝氏体、共析分解、钢中贝氏体相变等重要概念的新定义。 相似文献
994.
不同应力状态下铝合金变形及损伤机理的研究 总被引:3,自引:1,他引:3
利用改装的Arcan夹具对铝合金(6063)的蝶形试样进行0°,30°,45°,60°,90°的拉伸及拉伸卸载试验,研究了铝合金在不同应力状态下变形及损伤机理。结果表明:铝合金在不同应力状态下的工程应力一应变曲线明显不同。0°加载时,在蝶形中心产生微孔洞,微孔洞之间剪切,从而产生了微裂纹。随着微裂纹的扩展、连接导致试样断裂。随着试样中三轴应力度的减小,在蝶形试样中心的剪切应力不断增大,同时在蝶形试样中的剪切变形带越来越集中。显微裂纹首先在剪切带中产生,随着微裂纹的扩展导致试样的断裂。90°拉伸时,在蝶形中心形成明显的剪切变形带。90°加载时,在试样中产生的剪切带是形变剪切带而非相变剪切带。利用有限元软件ABAQUS对不同角度拉伸试验进行模拟,从而得出了不同应力状态下的塑性区的形状和大小。 相似文献
995.
Hydrogen entry and permeation into iron were measured by an electrochemical method during atmospheric corrosion reaction. The hydrogen permeation was enhanced on passive films because the hydrogen adsorption increased by the hydrogen evolution mechanism which is different from that on a bear iron surface. The permeation rate during a wet and dry corrosion cycle showed a maximum in the drying process depending upon the surface pH and the corrosion potential. The pollutant such as Na2SO3 which decreases the pH and the corrosion potential causes an increase in the permeation rate. The mechanism of the change in the permeation rate during the wet and dry cycles is explained by the polarization diagram of the electrode covered by thin water layer. 相似文献
996.
介绍了2006年上半年国际、国内钼市场的产量、供需平衡及进出口情况。西方世界钼产量平稳,钼价格呈现出上涨趋势。西方世界钼铁平均价格1月份为53.5~55.8美元/kg,6月份为58.71~60.07美元/kg,上涨9.72%;中国产钼铁在鹿特丹仓库现货价格1月份为50.99~53.70美元/kg,6月份为58.51~60.03美元/kg,上涨14.74%。分析了上半年国际、国内钼市场的形势,预测下半年国际钼市场钼精矿供应仍将紧张,副产钼供应平缓,因此下半年的钼市场将得到支撑。 相似文献
997.
C. Cagran B. Wilthan G. Pottlacher B. Roebuck M. Wickins R. A. Harding 《Intermetallics》2003,11(11-12):1327
The families of titanium aluminide intermetallic alloys have attractive high temperature mechanical properties which make them potential candidate materials for a wide range of applications, particularly in the aeronautic and automobile sectors. The development of appropriate manufacturing techniques is an essential stage in the engineering exploitation of these materials, e.g., Induction Skull Melting is one of the techniques which needs to be optimised for the casting of titanium aluminides. Research is underway to develop a computer model of this process but data are required for the key thermophysical properties. Pulse-heating techniques have been used to measure properties for the Ti–44Al–8Nb–1B system. Rectangular samples have been prepared and are resistively heated as part of a fast capacitor discharge circuit. Time-resolved measurements with sub-μs resolution of currents through the specimen were made with a Pearson probe current monitor using the induction principle. Voltages across the specimen were determined with knife-edge contacts and voltage dividers, and radiance temperatures of the sample were measured with a pyrometer. These measurements allow the calculation of specific heat and dependencies between enthalpy, electrical resistivity and temperature of the alloy up into the liquid phase. Data for thermal diffusivity have been obtained by using the Wiedeman–Franz relation. The results are compared with those obtained using DSC and the four-probe method to measure the temperature dependence of the resistivity. 相似文献
998.
采用共混法制备聚乙烯/镁铝水滑石纳米复合材料。XRD、SEM、TEM和性能测试表明:镁铝水滑石纳米晶体分散在聚乙烯基体中,且有少部分发生插层;阴离子表面活性剂对水滑石的处理效果要优于偶联剂;pH值对处理效果有一定影响;镁铝水滑石阻燃剂填充聚乙烯体系阻燃效果,要优于填充A1(OH)3阻燃剂。 相似文献
999.
Solid-solution hardening and softening by Fe additions to NiAl 总被引:3,自引:0,他引:3
Solid-solution hardening in the case of a ternary alloy addition to a B2 compound with the triple defect structure has been investigated. The fact that the ternary element may occupy either of two sublattices or may affect the concentration of other types of point defects present in the material makes this a very interesting problem to consider. Ni-rich (40 at% Al), stoichiometric (50 at% Al), and Al-rich (52 at% Al) alloys were doped with up to 12 at% Fe. Lattice parameter, bulk density and hardness measurements were performed on samples quenched from 1000 °C. It was found that solid-solution softening actually occurs in the Ni-rich alloys, while hardening was observed in the stoichiometric and Al-rich alloys. The vacancy concentration was determined from the experimental data, and the site occupancies of the Fe atoms were estimated from a thermodynamic model. Through careful consideration of all point defect concentrations the solid-solution hardening and softening behaviors could be effectively rationalized. 相似文献
1000.