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31.
The methodology of response reactions (RERs) introduced earlier from thermodynamic and kinetic considerations is used in this work to develop a new algorithm for the classification and enumeration of unique/direct reaction routes (RRs) and overall reactions (ORs). According to the RERs approach, a unique set of both RRs and ORs may be generated starting from any conceivable set of linearly independent RRs and ORs. In particular, the direct ORs may be most conveniently enumerated starting from the formula matrix of the terminal species (reactants and products), i.e., without any relation to the elementary reactions comprising the detailed mechanism. Depending on the type of ORs produced by the RRs one can distinguish between two distinct types of direct RRs. Namely, one option is to define a direct RR by specifying the intermediate species that need to be eliminated. This type of RR is referred to as Milner RRs. The other option is to require the direct RRs to produce RERs, thus resulting in RRs referred to as Happel-Sellers RRs. 相似文献
32.
In this research, the biosorption of phenol using the fibres of a Mediterranean seagrass Posidonia oceanica (L.) was studied. Batch experimental procedures were made to investigate the ability of this novel marine biomass to remove phenol from aqueous phase. The influences of pH and contact time at different initial concentrations were evaluated. The results showed that biosorption capacity was enhanced using solution pH equal to 5.2. The modelling results showed that pseudo‐second‐order and Redlich‐Peterson models were found to be the most suitable to satisfactory describe the kinetic and equilibrium adsorption data, respectively. 相似文献
33.
K. Scott 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1992,54(3):257-266
This paper presents a relatively straightforward approach to the modelling of electrochemical reactors operated in batch or continuous modes. The models are based on ideal flow assumptions of either well-mixed or plug flow and incorporate reaction rate models based on electrochemical kinetics and mass transport at one electrode. General characteristics of the reactor models are described, particularly with regard to the need for good mass transport in metal recovery applications. An example is given on the use of the model in the recovery of a heavy metal (Cd2+) from an acidified solution containing Cd(II) and Fe(III) ions. The reaction rate model is based on experimental data. 相似文献
34.
At high temperatures in clean oxidizing environments, SiC forms a very protective SiO2 film, but, in environments containing low levels of gaseous alkali salt contaminants or where condensed salts may deposit on the surface, the resistance of the film is significantly reduced. Oxidation kinetics of SiC were measured by continuous thermogravimetric analysis in a controlled environment containing CO2 , H2 O, and O2 plus low levels of potassium-containing salts. Potassium was found to be incorporated into the SiO2 scale and to significantly change its transport properties and its morphology. The rate of scale formation was found to increase directly in proportion to K in the scale. A change in mechanism was observed when water vapor was added to the reacting gas stream. 相似文献
35.
The ring-opening polymerization of hexamethylcyclodisilazane (D2NMe), initiated by methyl triflate in 1,2-dichloroethane, forms in the first, fast kinetic step both linear polymer and cyclic dimer (D4NMe). Subsequently a slow depolymerization process occurs leading to exclusively cyclotrisilazane (D3NMe). On the basis of kinetic measurements carried out using an adiabatic calorimetric technique and complementary experiments, mechanisms of both propagation, cyclization and back-biting reactions are proposed. The influence of the reaction temperature was also studied; it is demonstrated that, at low temperature, polymerization does not lead to cyclic oligomer formation. In such conditions, the polymerization presents a ‘living’ character. 相似文献
36.
37.
Anacardic acids, 6-pentadec(en)ylsalicylic acids isolated from the cashew Anacardium occidentale L. (Anacardiaceae) nut and apple, were found to possess preventive antioxidant activity while salicylic acid did not show this activity. These anacardic acids prevent generation of superoxide radicals by inhibiting xanthine oxidase (EC 1.1.3.22, Grade IV) without radical-scavenging activity. Notably, the inhibition kinetics of anacardic acids do not follow hyperbolic dependence of enzyme inhibition on inhibitor contents (Michaelis–Menten equation) but follow the Hill equation instead. Anacardic acid (C15:1) inhibited the soybean lipoxygenase-1 (EC 1.13.11.12, Type 1) catalyzed oxidation of linoleic acid with an IC50 of 6.8 μM. The inhibition is a slow and reversible reaction without residual enzyme activity. The inhibition kinetics indicate that anacardic acid (C15:1) is a competitive inhibitor and the inhibition constant, KI, was 2.8 μM. Anacardic acids act as antioxidants in a variety ways, including inhibition of various prooxidant enzymes involved in the production of the reactive oxygen species and chelate divalent metal ions such as Fe2+ or Cu2+, but do not quench reactive oxygen species. The C15-alkenyl side chain is largely associated with the activity. 相似文献
38.
The kinetics of the chlorination reaction of molybdenum trioxide with gaseous carbon tetrachloride has been studied at temperatures between 713 and 753 K. The effects of temperature, reaction time, residence time and gaseous reactant concentration on conversion were studied throughout the reaction. In all cases, there was an increase in conversion when the above operating variables were increased. The kinetic model proposed is consistent with and correlates the experimental data. In the range studied for the different variables, the step that controls the rate of reaction is the surface chemical reaction. Values of the rate constant and the activation energy were estimated. 相似文献
39.
A series of polyesters was prepared to evaluate hydrolytic stability as a function of cyclohexyl dibasic acid content. The
three cyclohexyl dibasic acids: 1,2; 1,3; and 1,4 were formulated into polyesters with two glycols. The proportion of cis
and trans isomers was evaluated via 1H NMR. The hydrolytic stability of short chain polyesters was evaluated in an acetone/water mixture which solubilized the
polyesters to mimic oligoester behavior within a thermosetting polyester coating environment. The rate of hydrolysis was monitored
by acid titration and corroborated by GPC. Surprisingly, 1,2-cylohexyl diacid-based polyesters were robust, and 1,3-cyclohexyl
diacid-based polyesters were the most susceptible to hydrolysis. Evidently, a 1,2-anchimeric effect for cyclohexyl dibasic
acid polyesters was not an important consideration, while the 1,3-cyclohexyl ester interaction was. Consequently, an anomeric
effect was proposed.
Presented at the 81st Annual Meeting of the Federation of Societies for Coatings Technology, November 12–14, 2003, in Philadelphia,
PA. 相似文献
40.