Synthesis and characterization of EuBa2Ca2Cu3O9−x: The influence of temperature on dielectric properties and charge transport mechanism

High dielectric constant materials have a crucial importance for various microelectronic applications such as memory devices, supercapacitors etc. Among other insulators, perovskite structured oxide materials attract great interest not only for their high dielectric constants but also their unique electrical and magnetic properties such as superconductivity etc. From this point of view, a new Europium based copper oxide layered material with perovskite structure (EuBa₂Ca₂Cu₃O_9−x coded as Eu-1223) has been synthesized by solid state reaction method in this work. The physical and chemical properties of Eu-1223 have been determined by FTIR, SEM, XRF, XRD, TGA and DTA techniques. The influence of temperature on impedance and dielectric properties of Eu-1223 has been investigated by impedance spectroscopy measurements performed within the frequency interval of 5 Hz–13 MHz between 298 K and 408 K temperatures. It has been found that the Eu-1223 material has high dielectric constants at each temperature operated. In addition, Eu-1223 sample behaves as a colossal dielectric material up to 300 kHz for 408 K due to observation of dielectric constant values which are greater than 10³. Furthermore, it has been revealed that Eu-1223 material can be used as thermally sensitive resistors in electronic circuits due to its decreasing resistance with increasing temperature. Moreover, it has been observed that the relaxation frequency of the system shifts from 46.5 kHz (low frequency radio wave band) to 1.57 MHz (mid frequency radio wave band) as the temperature increasing from 298 K to 408 K. According to dc conductivity investigations, the variation of dc conductivity with the inverse of temperature satisfies linear relationship that indicates a thermally activated nearest neighbor hopping conduction. On the other hand, it has been determined that ac conductivity has frequency dependent relation which obeys ω^s for the high frequency region. Furthermore, the frequency exponent, s, which takes values between 0.7 and 0.4, shows a decreasing behavior with increasing temperature. In conclusion, ac charge transport mechanism has been predicted as correlated barrier hoping for Eu-1223.     

Preparation, characterization and application of advanced isoconversional kinetics to epoxy/1,4-Bis(3-aminopropoxy) butane/MWCNT nanocomposite

A novel nanocomposite consisting bisphenol A diglycidyl ether/1,4-Bis(3-aminopropoxy) butane (1,4-APB)/multiwall carbon nanotube (MWCNT) was synthesized and characterized. Kinetics of the reaction was described by applying differential scanning calorimetry (DSC) data to isoconversional methods of Flynn-Wall-Ozawa (FWO), advanced isoconversional method of Vyazovkin, and non-linear integral isoconversional algorithm (NLN). It was found that at the presence of MWCNT the thermal decomposition temperature increased by rising the curing temperature and time. Data from dynamic mechanical thermal analysis (DMTA) showed that the glass transition temperature of the cured nanocomposite is 7 °C higher than that value found for the system without carbon nanotube. Scanning electron microscopy (SEM) was used to observe the fracture surface morphology and results indicated evidence of the interfacial interaction improvement and adhesion strength due to good dispersion of MWCNT.     

Determination and Analysis of Ustiloxins A and B by LC-ESI-MS and HPLC in False Smut Balls of Rice

Ustiloxins are cyclopeptide mycotoxins produced by the pathogenic fungus Villosiclava virens of rice false smut. Ustiloxins A and B as two main mycotoxins were determined conveniently by LC-ESI-MS in the water extract from rice false smut balls which were mostly composed of the chlamydospores and mycelia of the pathogen. Both ustiloxins A and B in the water extract were also quantitatively analyzed by HPLC. This is the first report on the determination and analysis of ustiloxins A and B simultaneously by LC-ESI-MS and HPLC in false smut balls of rice.     

Electromagnetic shielding effectiveness and mechanical property of polymer–matrix composites containing metallized conductive porous flake-shaped diatomite

The porous flake-shaped diatomite particles with different micropores diameter were used as forming templates for the fabrication of the conductive core–shell functional fillers by electroless silver plating. The surface morphologies and phase structures of the surface coatings onto diatomite particles with different micropores diameter were evaluated. The effects of micropores diameter on electrical resistivity, electromagnetic shielding effectiveness and mechanical property of polymer–matrix composites containing silver-coated diatomite particles were also investigated in detail. The results show that the micropores onto initial diatomite particles after plating are completely covered with the coating, while the micropores onto diatomite particles with expanding pores are still visible. The expanding micropores onto diatomite particles in certain size range have less impact on the phase structures, electrical resistivity and electromagnetic shielding effectiveness. However, the mechanical properties of composites are improved significantly after expanding micropores by HF acid corrosion.     

Numerical optimization of strengthening disturbed regions of dapped-end beams using NSM and EBR CFRP

This paper presents a parametric investigation, based on non-linear finite element modeling, to identify the most effective configuration of carbon fiber-reinforced polymers (CFRP) for strengthening reinforced concrete (RC) dapped-end beams. Following a field application and laboratory tests, it focuses on effects of 24 externally bonded (EBR) and near surface mounted reinforcement (NSMR) configurations on yield strain in steel and the capacity and failure mode of dapped-end beams. The investigated parameters were the mechanical properties of the CFRP, the strengthening procedure and the inclination of the fibers with respect to the longitudinal axis. Two failure scenarios were considered: rupture and debonding of the FRP. The results indicate that high-strength NSM FRPs can considerably increase the capacity of dapped-end beams and the yielding strains in reinforcement can be substantially reduced by using high modulus fibers.     

A~2O法处理焦化废水的成本分析和控制

以太原煤气化股份有限公司第二焦化厂为例,综合分析了A2O法处理焦化废水的成本,包括电费、药剂费、资源费等,以2010年实际生产运行数据为基准,经计算可知,每生产1 t焦炭需处理0.58 t焦化废水,水处理的费用为6.5元/t;对A2O法处理焦化废水成本的控制关键是对药剂和用电设备的控制。     

Circular braiding take-up speed generation using inverse kinematics

Circular overbraiding of composite preforms on complex mandrels currently lacks automatic generation of machine control data. To solve this limitation, an inverse kinematics-based procedure was designed and implemented for circular braiding machines with optional guide rings, resulting in a take-up speed profile for a given braid angle distribution on mandrels with complex 3D shapes including non-axisymmetric, optionally eccentric cross-sections that can vary in shape and size along an optionally curved mandrel centerline, allowing a curved machine movement. This procedure reduces the problem size, resulting in a short computation time, fit for CAE process chain integration. Numerical control data was generated for a complex mandrel with a specified braid angle and a triaxial braid. A simulation using this control data yields a braid angle that deviates a few degrees from the specified braid angle. The simulation was validated experimentally, using the generated instructions to control the braiding machine. This showed a deviation from the simulated braid angle of 3 degrees in the centered, non-tapered mandrel regions, up to 10 degrees in tapered regions and an experimental scatter of 7 degrees. The deviation is mainly attributed to the neglect of yarn interaction and guide ring contact friction in the model, leading to an incorrectly modeled convergence zone length.     

Modelling of the bond behaviour of tuff elements externally bonded with FRP sheets

The performance of fibre reinforced plastic (FRP) materials used for external strengthening depends strongly on the bond behaviour at the FRP-substrate interface. In this paper, the results of an analytical model and of two Finite Element (FE) models (bi-and three-dimensional) for simulating bond behaviour in FRP-strengthened masonry elements using zero-thickness interface elements are presented. The primary parameters of bilinear and nonlinear bond-slip laws were determined from experimental results of single shear bond tests that the authors conducted on masonry blocks of yellow tuff bonded with FRP carbon and glass fabrics. Several parametric analyses were conducted to estimate the effect of the primary bond law parameters on the global behaviour of the specimens and to determine the effective bonded length for the investigated masonry support.