Glass transition evaluation of commercially available epoxy resins used for civil engineering applications

The paper presents a study about the glass transition of commercially available epoxy resins used for structural strengthening of concrete members for instance by means of Carbon Fiber Reinforced Polymer (CFRP) strips. Prior to an experimental investigation with a dynamic mechanical analysis (DMA), an overview on differences between definitions for the glass transition temperature T_g is given. Several testing recommendations are listed in this respect. Subsequently, DMA tests on three commercially available products are presented. A first focus is put on the different evaluation methods for one specific test result. It is visible that considerable differences in the finally adapted glass transition temperature might arise if one or the other procedure is followed. Additional parameters, such as curing procedure, specimen age, temperature history, and ultimate temperature during heating are considered, too. In all the above mentioned cases, differences in the glass transition can be found. Higher specimen age, higher ultimate temperature during testing, accelerated curing, as well as a lower heating rate implicate higher glass transition temperatures, showing that the glass transition temperature is not a fixed material characteristic. In a final step, the relevance for T_g for civil engineering applications is described. The various design code provisions for defining the service temperature in structures related to T_g are presented. The overall aim of the investigation is to show that structural engineers and end users have to be aware of the different influential parameters on the final results regarding the glass transition temperature, which also highlights the need of a potential deeper product investigation in case technical data sheets lack detailed information.     

Improved mechanical properties of an epoxy glass–fiber composite reinforced with surface organomodified nanoclays

An organomodified surface nanoclay reinforced epoxy glass-fiber composite is evaluated for properties of mechanical strength, stiffness, ductility and fatigue life, and compared with the pristine or epoxy glass-fiber composite material not reinforced with nanoclays. The results from monotonic tensile tests of the nanoclay reinforced composite material at 60 °C in air showed an average 11.7% improvement in the ultimate tensile strength, 10.6% improvement in tensile modulus, and 10.5% improvement in tensile ductility vs. these mechanical properties obtained for the pristine material. From tension–tension fatigue tests at a stress-ratio = +0.9 and at 60 °C in air, the nanoclay reinforced composite had a 7.9% greater fatigue strength and a fatigue life over a decade longer or 1000% greater than the pristine composite when extrapolated to 10⁹ cycles or a simulated 10-year cyclic life. Electron microscopy and Raman spectroscopy of the fracture and failure modes of the test specimens were used to support the results and conclusions. This nanocomposite could be used as a new and improved material for repair or rehabilitation of external surface wall corrosion or physical damage on piping and vessels found in petrochemical process plants and facilities to extend their operational life.     

Failure analysis of fiber-reinforced composite laminates subjected to biaxial loads

A nonlinear constitutive model for a single lamina is proposed for the failure analysis of composite laminates. In the material model, both fiber and matrix are assumed to behave as elastic-plastic and the in-plane shear is assumed to behave nonlinearly with a variable shear parameter. The damage onset for individual lamina is detected by a mixed failure criterion, composed of the Tsai-Wu criterion and the maximum stress criterion. After damage takes place within the lamina, the fiber and in-plane shear are assumed to exhibit brittle behavior, and the matrix is assumed to exhibit degrading behavior. The proposed nonlinear constitutive model is tested against experimental data and good agreement is obtained. Then, numerical analyses are carried out to study the failure behavior of symmetric angle-ply composite laminates and symmetric cross-ply composite laminates subjected to biaxial loads. Finally, the conclusions obtained from the numerical analysis are given.     

Cellular glass obtained from non-powder preforms by foaming with steam

Cellular glass, or foamed glass, has been obtained as a result of the heating (to 700–800 °C) of heavy and strong preforms formed due to the binding properties of the silicate additives. Durability of the preforms reached 6 MPa at the density of 1.8 g/cm³. The main expanding agent in the composition is steam, which can also be a carbon oxidizer and increase the amount of the evolved gases and decrease the density of the foamed glass obtained. As a result of changing the initial composition structure, the density of the obtained foamed glass varied from 0.14 to 0.6 g/cm³, its breaking strength - from 0.6 to 5.0 MPa. and heat conductivity – from 0.045 to 0.15 W/(m·К), respectively. The speed of expansion of the preforms had an extreme character with the induction period typical for topochemical reactions. The obtained cellular materials possessed a distinct crystalline structure. The experiments showed the possibility of obtaining cellular materials with acceptable properties from different types of glass for the solution of environmental tasks. Various technological methods of obtaining cellular material blocks from preforms of various forms were tested to use them for thermal insulation and facing materials.     

Dynamic particle analysis for the evaluation of particle degradation during compounding of wood plastic composites

A dynamic image analysis method was applied for particle characterisation to study the effect of different process conditions during twin-screw compounding of WPC. The use of distributions based on different types of quantity is discussed with respect to their sensitivity to reveal the effects of different process conditions on particle degradation. Distributions based on length proved to be most suitable to represent the initially broad length distribution of the particles before processing. Sensitivity was strong enough to show differences in particle size after processing depending on process conditions. Particle size was reduced by more than 97% compared to initial size. Degradation was stronger with increasing wood content and when the screw design contained more mixing elements. The effect of screw speed and feed rate was dependent on filler content and screw design.     

Modeling of continuous ultrasonic impregnation and consolidation of thermoplastic matrix composites

Ultrasonic propagation was used to provide heat and pressure in order to perform impregnation and consolidation during production of thermoplastic matrix composites. For this purpose, a new experimental set-up, integrating a laboratory filament winding machine with a horn and a compaction roller, was developed.The heat transfer phenomena occurring during continuous impregnation and consolidation were simulated solving by finite element (FE) analysis the energy balance equations in 2D accounting for the heat generated by ultrasonic waves, the melting characteristics of the matrix and the movement of the thermoplastic commingled roving.The temperature distribution in the composite, predicted by the numerical simulations, was validated by temperature measurements during the production of E-glass/polypropylene cylinders, with the optimized parameters obtained by the FE analysis. The ultrasonic consolidated composite cylinders were characterized by low void content and a shear modulus comparable with that obtained by the micromechanical analysis.     

Facile size-controlled synthesis of well-dispersed spherical amorphous alumina nanoparticles via homogeneous precipitation

Well-dispersed spherical amorphous alumina nanoparticles with a narrow size distribution were obtained by facile homogeneous precipitation and subsequent calcination. In the synthesis, formamide was used as the precipitant, and mixtures of aluminum sulfate and aluminum nitrate with different molar ratios were used as the aluminum sources. The average size of the amorphous alumina nanoparticles was successfully controlled by adjusting the amount of formamide and the sulfate/nitrate molar ratio. The particle size decreased with increasing amount of formamide and decreasing sulfate/nitrate molar ratio. Dispersed spherical amorphous alumina nanoparticles with average sizes of 23, 34, 45, and 57 nm were prepared using 100 mL formamide at sulfate/nitrate molar ratios of 1:9, 2:8, 3:7, and 4:6, respectively.     

Review of the recent developments in cellulose nanocomposite processing

This review addresses the recent developments of the processing of cellulose nanocomposites, focusing on the most used techniques, including solution casting, melt-processing of thermoplastic cellulose nanocomposites and resin impregnation of cellulose nanopapers using thermoset resins. Important techniques, such as partially dissolved cellulose nanocomposites, nanocomposite foams reinforced with nanocellulose, as well as long continuous fibers or filaments, are also addressed. It is shown how the research on cellulose nanocomposites has rapidly increased during the last 10 years, and manufacturing techniques have been developed from simple casting to these more sophisticated methods. To produce cellulose nanocomposites for commercial use, the processing of these materials must be developed from laboratory to industrially viable methods.     

A systematic investigation into a novel method for preparing carbon fibre–carbon nanotube hybrid structures

By electrospraying solvent dispersed carbon nanotubes (CNTs) with a binder onto carbon fibre (CF), hybrid structures, with an end aim to improve interfacial bonding in composites, were formed. The electrospray parameters controlling the modification of the CNT morphologies were studied. High-speed camera observations found applied voltage was critical for determining spray mode development. Electric field simulations revealed a concentrated electric field region around each fibre. Both voltage and distance played an important role in determining the CNT morphology by mediating anchoring strength and electric field force. The forming mechanism investigation of different surface morphologies suggested that binder with appropriate wetness gives freedom to the CNTs, allowing them to orientate radially from the CF surface. Linear density (LD) measurements and thermogravimetric analysis revealed that a 10 min coating increased the LD of a single CF filament by up to 31.7% while a 1 h treatment increased fibre bundle mass by 1%.     

Interlaminar fracture of CF/EP composite containing a dual-component microencapsulated self-healant

We present an experimental study of the self-healing ability of carbon fibre/epoxy (CF/EP) composite laminates with microencapsulated epoxy and its hardener (mercaptan) as a healing agent. Epoxy- and hardener-loaded microcapsules (average size large: 123 μm; small: 65 μm) were prepared by in situ polymerisation in an oil-in-water emulsion and were dry-dispersed at the ratio 1:1 on the surface of unidirectional carbon fabric layer. The CF/EP laminates were fabricated using a vacuum-assisted resin infusion (VARI) process. Width-tapered double cantilever beam (WTDCB) specimens were used to measure mode-I interlaminar fracture toughness of the CF/EP composites with a pre-crack in the centre plane where the microcapsules were placed. Incorporation of the dual-component healant stored in the fragile microcapsules provided the laminates with healing capability on delamination damage by recovering as much as 80% of its fracture toughness. It was also observed that the recovery of fracture toughness was directly correlated with the amount of healant covering the fracture plane, with the highest healing efficiency obtained for the laminate with large capsules.