纳米碳酸钙制备过程中添加剂作用机理探讨

采用鼓泡碳化法 ,在最佳反应温度、反应物浓度的条件下 ,考察了添加剂对产物形状及粒径大小的影响 ,得到了直径为 2 0～ 30nm、长径比在 2 0左右且分散性能良好的针状纳米碳酸钙 ,并对添加剂作用机理进行了分析。     

PEG20000中试放大的工艺研究

在一定温度和催化剂作用下 ,分别利用本体聚合和溶剂聚合的方法 ,在 1L、10 0L不锈钢高压反应釜中合成了相对分子质量为 2 0 0 0 0的聚乙二醇 ,并讨论了聚合反应机理 ,研究了催化剂用量、反应温度、反应时间对聚合反应的影响。经过红外、核磁共振、凝胶色谱、化学分析等方法对产物进行了表征。     

硼酸铝晶须增强环氧树脂和双马来酰亚胺树脂体系的研究

本文以硼酸铝晶须为增强剂，以4，5-环氧环己烷-1，2-二甲酸二缩水甘油酯(TDE-85)，甲基纳狄克酸酐(MNA)、N，N’-二胺基二苯甲烷型双马来酰亚胺(BMI)/O，O′-二烯丙基双酚A(BA)体系分别作为基体制备晶须增强复合材料。研究了晶须对树脂的尺寸、表面处理方法、含量对树脂体系力学性能和热性能的影响；通过扫描电子显微镜(SEM)分析了浇注体的弯曲、冲击断口，研究晶须的增强机理。     

石油工程项目管理机制

为了妥善处理石油工程项目中的委托-代理关系,研究了委托-代理模型和石油工程项目管理中的激励约束机制,分析了激励机制、监督机制和选择机制在石油工程项目运行管理中的重要性.只有用有效的契约去激励技术服务公司,才能使服务公司在追求自身效益最大化的同时也为实现石油公司的最大效益而尽最大努力;只有对技术服务公司的作业实施监督,才能形成对技术服务公司的有效约束;采用激励性承包方式、实施综合性评标和组建工程项目动态联盟能够防止逆向选择.分析表明,在最优激励安排下,激励强度与项目面临的不确定性、承包商的边际成本及其风险规避系数负相关,与承包商的边际生产率正相关,还与其他可观测变量相关.在最优监督水平下,作业公司的边际生产率越高,边际成本越低,越容易监督,监督带来的边际收益越高.对于那些监督比较困难的项目,可以通过加强惩罚力度的方式弥补难以有效监督的不足.激励性承包方式可以减小逆向选择造成的危害,组建动态联盟可以进一步加强激励作用,降低道德风险,解决逆向选择问题.参8     

Corrosion Inhibition Mechanism with Spilt Cell Technique of Rare Earth Metal on LC4 Al Alloy

A new method of studying the corrosion inhibition mechanism of rare earth metal(REM) on LC4 Al alloy with the spilt cell technique was studied. The principle and experimental method of the spilt cell technique were analyzed. By measuring the change of net-electric current between the two electrodes caused by the change of the amount of oxygen in the solution and the addition of CeCl₃, the influence of corrosive performance of CeCl₃ on LC4 super-power aluminum alloy in the 0.1 mol·L⁻¹ NaCl solution was investigated. Meanwhile, the conditional changes of pH values, CeCl₃ solution, additire and time of performance were also studied. Finally, the features of electrode surface were revealed by using SEM and X-ray energy-dispersive spectrometry (EDS). By combining these with other electric chemical techniques, such as potential-time curve, polarization curve et al.     

真空制盐蒸发结晶器的设计与实践

真空蒸发制盐外热式强制逆循环轴向出料蒸发结晶器，经多个厂家生产应用实践证明是成功的，具有生命力的。这种新型结构，作为一项新技术新设备应加强研究，总结提高，推广应用。不断完善。文章从流体力学、结晶机理角度要求，到具体工程设计参数和材质选用。论述了该罐的特点。     

Effect of calcination conditions on phase formation and particle size of nickel niobate powders synthesized by solid-state reaction

The solid-state mixed oxide method via a rapid vibro-milling technique is explored in the preparation of single-phase nickel niobate (NiNb₂O₆) powders. The formation of the NiNb₂O₆ phase in the calcined powders has been investigated as a function of calcination conditions by TG-DTA and XRD techniques. Morphology, particle size and chemical composition have been determined via a combination of SEM and EDX techniques. It has been found that the minor phases of unreacted NiO and Nb₂O₅ precursors and the Ni₄Nb₂O₉ phase tend to form together with the columbite NiNb₂O₆ phase, depending on calcination conditions. More importantly, it is seen that optimization of calcination conditions can lead to a single-phase NiNb₂O₆ in an orthorhombic phase.     

Potential of vibro-milling technique for preparation of electroceramic nanopowders

The potential of the vibro-milling technique as a simple method to obtain usable quantities of single-phase electroceramic powders with nanosized particles was examined. A detailed study considering the role of both milling time and firing condition on phase formation and particle size of the final product was performed. The calcination temperature for the formation of the desired phase was lower when longer milling times have been applied. More importantly, by employing an appropriate choice of the milling time and calcination condition, high purity electroceramic nanopowders have been successfully prepared with a simple solid-state reaction method.     

论剪切质量的提高

通过对飞剪剪切长度，精度，剪刃间隙和压板机构等参数的优化，来提高钢板的剪切质量。     

论我国大学不良竞争的形成及控制

大学在办学资源、办学过程、办学质量、办学形象的竞争中出现大量的不良倾向。大学的不良竞争是由于政府主导资源配置、资源和制度供给不足、大学系统重构等因素导致。必须通过控制主体、控制手段的转变和控制对象的发展形成新的控制机制，以保证大学竞争的秩序化和规范化。