处理器验证激励在线筛选技术

如何生成高质量的验证激励是功能验证中的核心问题之一.随着功能验证的不断进行,验证激励的有效性也随之降低.为了提高验证激励的质量,提出一种在线筛选技术来处理验证激励.该技术采用单分类支持向量机来在线地构建分类器,以对新生成的验证激励是否冗余进行预测,如果是冗余的,则不进入仿真阶段进行仿真.在此基础上,进一步提出指令序列核函数来衡量不同指令序列的相似程度.实验结果表明,与约束随机生成技术相比,文中技术可以减少约83%的验证激励及79%的验证时间.     

基于软测量的化工精馏过程推断控制策略

针对化工精馏过程产品成分无法在线检测及其用温度间接控制产品成分的常规控制策略存在着控制精度低的问题,提出基于软测量的精馏过程成分非线性串级推断控制策略。该控制策略首先提出核岭回归的实时软测量方法,即利用满足Mercer条件的核函数改进线性岭回归算法,实现精馏过程产品成分的在线检测;然后在此基础上,提出一种新的非线性串级推断控制策略,即副环采用常规的温度间接控制,主环采用基于核岭回归软测量的推断控制策略。通过Mejedell等建立的精馏塔动态模型分别对单端和双端成分非线性串级推断控制策略性能进行分析,仿真结果表明,与传统控制方案比较,新控制策略的控制质量有了较大提高,控制结构简单,易于实施。     

烧结法赤泥-沥青粉固化剂稳定粉土的路用性能研究

为解决黄河冲积平原地区粉土粘聚力低、水稳定性差等工程应用问题,采用烧结法赤泥和基质沥青为主材制备粉土固化剂(RAC)对粉土进行综合稳定。按5%水泥优选掺量并附加0,2,4,6,8% RAC成型稳定粉土试件,经过标准养护、浸水软化、循环加热、低温冻融、高温自愈等特定试验条件后,进行3d、7d和28d龄期的抗压强度与压缩模量试验,对比分析不同掺量RAC稳定粉土路用性能的变化规律。采用扫描电镜(SEM)分别观察粉土、水泥稳定粉土和RAC稳定粉土的微观结构形貌和孔隙特征,进而探讨固化稳定机理。结合实体工程的应用实践对RAC稳定粉土的路用性能进行测试分析与验证。结果表明：与单掺水泥相比,RAC稳定粉土具有良好的力学性能,2,4,6,8%RAC稳定粉土标准养护3d强度分别提高110%,146%,156%,161%,28d龄期浸水强度损失率均小于20%;当RAC掺量高于4%时,循环加热5次以上可使稳定粉土的强度增长超过140%,低温冻融强度损失率小于15%;试件加载至90%极限荷载,循环加热5次后,2,4,6,8%RAC稳定粉土强度变化率分别是-8.3%,-2.3%,+8.0%,+12.9%。SEM图像显示RAC稳定使粉土形成密实的胶结凝聚体和均匀分布的孔径小于1μm非连通微孔结构,有利于稳定粉土水稳定性和抗冻性的提高;高温条件下沥青组分发生湿润粘结包裹粉土颗粒及水化产物,同时加速扩散填充内部孔隙和微裂缝,实现土体的损伤修复和结构补强。实体工程中RAC稳定粉土结构层取芯测试抗压强度为1.7MPa,压缩模量为1360MPa,路面弯沉为18~23(0.01mm),未出现裂缝、坑槽、松散等损坏现象。     

A new application of Hydroxyapatite extracted from dromedary bone: Adsorptive removal of Congo red from aqueous solution

The aim of this paper is to evaluate the efficiency of the natural hydroxyapatite powder for anionic dye (Congo red) elimination from water and optimization of adsorption process parameters that are contact time (0-360 min), solution pH (4-9), initial dye concentration (400-2400 mg/l), and adsorbent dosage (0.4-20 g/l). Natural hydroxyapatite with high surface area was prepared from animal agriculture waste dromedary bone. X-ray diffraction, transmission electron microscopy, transform infrared spectroscopy, and elemental analysis characterizations of the powder prepared show a hexagonal structure, the irregular form of hydroxyapatite and presence of other elements as trace element. The results of adsorption tests demonstrated the high efficiency of natural hydroxyapatite for removal of Congo red from water solution whose maximum experimental capacity adsorption of Congo red by natural hydroxyapatite is 900 mg/g at pH 4.5, equilibrium time 240 min and adsorbent dosage 2 g/l. According to the correlation coefficient value, the pseudo-second order kinetic model identified the sorption mechanism of pollutant used on natural hydroxyapatite. The Freundlich isotherm is the best representative theoretical model of the dye molecules’ adsorption on the natural hydroxyapatite support.     

固结赤泥碾压坝排灰渣的试验研究

本试验研究，通过来统试验，确定固结破碎碾压赤泥的各种物理力学指标。成功地运用了固结赤泥进行破碎碾压筑坝，解决了生产中的燃眉之急，为同类企业充分利用现有堆场及设施提供了经验。     

Decolorization of reactive brilliant red X-3B by heterogeneous photo-Fenton reaction using an Fe–Ce bimetal catalyst

Decolorization of reactive brilliant red X-3B was studied by using an Fe–Ce oxide hydrate as the heterogeneous catalyst in the presence of H₂O₂ and UV. The decolorization rate was in the order of UV–Fe–Ce–H₂O₂ > UV–Fe³⁺–H₂O₂ > UV–H₂O₂ > UV–Fe–Ce ≥ Fe–Ce–H₂O₂ > Fe–Ce. Under the conditions of 34 mg l⁻¹ H₂O₂, 0.500 g l⁻¹ Fe–Ce, 36 W UV and pH 3.0, 100 mg l⁻¹ X-3B could be decolorized at efficiency of more than 99% within 30 min. The maximum dissolved Fe during the reaction was 1 mg l⁻¹. From the fact that the decolorization rate of the UV–Fe–Ce–H₂O₂ system was significantly higher than that of the UV–Fe³⁺–H₂O₂ system at Fe³⁺ = 1 mg l⁻¹, it is clear that the Fe–Ce functioned mainly as an efficient heterogeneous catalyst. UV–vis, its second derivative spectra, and ion chromatography (IC) were employed to investigate the degradation pathway. Fast degradation after adsorption of X-3B is the dominant mechanism in the heterogeneous catalytic oxidation system. The first degradation step is the breaking down of azo and CN bonds, resulting in the formation of the aniline- and phenol-like compounds. Then, the breaking down of the triazine structure occurred together with the transformation of naphthalene rings to multi-substituted benzene, and the cutting off of sulphonic groups from the naphthalene rings. The last step includes further decomposition of the aniline structure and partial mineralization of X-3B.     

A Modified Nonparametric Prewhitened Covariance Estimator

Abstract. This paper proposes a fully modified version of the spectral matrix estimator (and the long‐run variance estimator as a special case) proposed originally by Xiao and Linton [Journal of Time Series Analysis (2002) Vol. 23, pp. 215–250], and derives its asymptotic results. A striking feature of the modified spectral matrix estimator is to achieve the convergence rate of O(T ^?8/9) in the mean squared error (MSE), which is usually achieved under the fourth‐order spectral window. However, this estimator does not sacrifice the positive definiteness of the resulting estimate for the rate improvement; it is Hermitian and positive definite in finite samples by construction. The faster convergence rate is established by a multiplicative bias correction of the crude spectral estimator under the second‐order spectral window. The approximations to some sensible definitions of the MSE of the estimator and the bandwidths that minimize the asymptotic MSEs are also derived. Monte Carlo results indicate that for a wide variety of processes the modified spectral matrix estimator reduces the bias without inflating the variance and thus improves the MSE, compared with the crude, bias‐uncorrected estimator.     

基于TW-SVM预测模型的某堆石坝变形预测分析

为提高监测资料有缺失的大坝变形预测模型精度,采用支持向量机方法建立一种具有小样本、高维、非线性的预测模型,并结合对其重要组成部分核函数的分析应用,提出一种根据结构风险最小化的TW-SVM预测模型。以某堆石坝为例进行研究,利用坝坡垂直位移和水平位移的监测数据,分别采用TW-SVM方法和BP神经网络(NET)方法建立相应预测模型进行比较分析。结果表明:采用TW-SVM方法和NET方法预测的垂直位移最大绝对误差分别为0.58 mm和6.18 mm,最大相对误差分别为270.00%和1 286.22%;采用TW-SVM方法和NET方法预测的水平位移最大绝对误差分别为0.25 mm和14.91 mm,最大相对误差分别为31.25%和1 189.85%;TW-SVM预测模型比NET预测模型更适合于影响因素为时间、水位的小样本预测分析。研究结果为堆石坝变形预测与分析提供参考。     

脲醛树脂微胶囊包覆红磷阻燃剂制备工艺的研究 Ⅰ.预聚物合成工艺研究

研究了脲醛树脂的预聚物通过原位聚合对红磷进行包覆的一些影响因素。实验表明影响预聚物质量的主要因素是第一阶段尿醛比(F/U)1,第二阶段尿醛比(F/U)2,反应温度和pH值。制备预聚物的最佳条件为:第一阶段尿醛比为2.3∶1(摩尔比),第二阶段尿醛比为1.3∶1(摩尔比),pH值为5.1,反应温度为75℃。制备的预聚物来包覆红磷,颜色为白色;用微胶囊红磷阻燃聚乙烯,当含量为9%时,在500℃下残余物为4.85%。