被动冷却系统于混凝土屋顶应用研究进展

在炎热气候条件下,由混凝土结构构成的建筑物往往会有不让人满意的热力学性质,比如说较高的内部温度,特别是没有那些主动的冷却系统。相比于混凝土层屋顶,添加被动冷却系统的屋顶显示了它慢热的时间响应,当热量传递减少时,这是一个理想的性质可以用来控制热的波动。探究多种被动式冷却系统于混凝土建筑的屋顶的应用。     

基于栈式稀疏自编码器的新型干扰识别

为了有效应对频谱弥散干扰(SMSP)和切片组合干扰(C&I)两种新型干扰,提出了一种基于栈式稀疏自编码器的识别算法。该算法首先对干扰与否的雷达接收信号进行双谱分析;然后对双谱特征进行降维,得到高维样本。预训练阶段,构造稀疏自编码器神经网络模型进行无标签样本的预训练;然后根据有标签数据对该模型参数进行有监督微调;最后利用Softmax分类器完成新型干扰的识别。仿真实验证明该方法有较高的识别率,特别是相较于其他文献方法,该方法受信噪比影响最小且识别效果最佳。说明了深度学习方法应用于雷达新型干扰信号识别领域的可行性和优越性。     

Defect reduction in Hg1−xCdxTe grown by molecular beam epitaxy on Cd0.96Zn0.04Te(211)B

A study on preparation of Cd_0.96Zn_0.04Te(211)B substrates for growth of Hg_1−xCd_xTe epitaxial layers by molecular beam epitaxy (MBE) was investigated. The objective was to investigate the impact of starting substrate surface quality on surface defects such as voids and hillocks commonly observed on MBE Hg_1−xCd_xTe layers. The results of this study indicate that, when the Cd_0.96Zn_0.04Te(211)B substrates are properly prepared, surface defects on the resulting MBE Hg_1−xCd_xTe films are reduced to minimum (size, ∼0.1 m and density ∼500/cm²) so that these MBE Hg_1−xCd_x Te films have surface quality as good as that of liquid phase epitaxial (LPE) Hg_1−xCd_xTe films currently in production in this laboratory.     

Carbon Black-Supported Single-Atom Co?N?C as an Efficient Oxygen Reduction Electrocatalyst for H2O2 Production in Acidic Media and Microbial Fuel Cell in Neutral Media

Single metal atom isolated in nitrogen-doped carbon materials (M N C) are effective electrocatalysts for oxygen reduction reaction (ORR), which produces H₂O₂ or H₂O via 2-electron or 4-electron process. However, most of M N C catalysts can only present high selectivity for one product, and the selectivity is usually regulated by complicated structure design. Herein, a carbon black-supported Co N C catalyst (CB@Co N C) is synthesized. Tunable 2-electron/4-electron behavior is realized on CB@Co-N-C by utilizing its H₂O₂ yield dependence on electrolyte pH and catalyst loading. In acidic media with low catalyst loading, CB@Co N C presents excellent mass activity and high selectivity for H₂O₂ production. In flow cell with gas diffusion electrode, a H₂O₂ production rate of 5.04 mol h⁻¹ g⁻¹ is achieved by CB@Co N C on electrolyte circulation mode, and a long-term H₂O₂ production of 200 h is demonstrated on electrolyte non-circulation mode. Meanwhile, CB@Co N C exhibits a dominant 4-electron ORR pathway with high activity and durability in pH neutral media with high catalyst loading. The microbial fuel cell using CB@Co N C as the cathode catalyst shows a peak power density close to that of benchmark Pt/C catalyst.     

Optimizing the Oxygen-Catalytic Performance of Zn–Mn–Co Spinel by Regulating the Bond Competition at Octahedral Sites

By using the more electro-negative Mn³⁺ ion to partially replace Co³⁺ at the octahedral site of spinel ZnCo₂O₄, i.e., forming ternary Zn–Mn–Co spinel oxide, the electrocatalytic oxygen reduction/evolution activity is found to be significantly increased. Considering the physical characterization and theoretical calculations, it demonstrated that the bond competition played a key role in regulating the cobalt valence state and the electrocatalytic activity. The partial replacement of octahedral-site-occupied Co³⁺ by Mn³⁺ can effectively modulate the adjacent Co–O bond and induce the Jahn–Teller effect, thus changing the originally stable crystal structure and optimizing the binding strength between the active center and reaction intermediates. Certainly, the Mn-substituted ZnMn_1.4Co_0.6O₄/NCNTs exhibit higher electrocatalytic oxygen reduction reaction (ORR) activity than that of ZnCo₂O₄/NCNTs and ZnMn₂O₄/NCNTs, supporting that the Co–O bond covalency determines the ORR activity of spinel ZnCo₂O₄. This study offers the competition between adjacent Co–O and Mn–O bonds via the B_Oh–O–B_Oh edge-sharing geometry. The ion substitution at octahedral sites by less electronegative cations can be a new and effective way to improve the electrocatalytic performance of cobalt-based spinel oxides.     

Understanding Boosted Selective CO2-to-CO Photoreduction with Pure Water Vapor over Hierarchical Biomass-Derived Carbon Matrix

Solar-driven CO₂ reduction reaction (CO₂RR) with water into carbon-neutral fuels is of great significance but remains challenging due to thermodynamic stability and kinetic inertness of CO₂. Biomass-derived nitrogen-doped carbon (N-C_b) have been considered as promising earth-abundant photocatalysts for CO₂RR, although their activities are not ideal and the reaction mechanism is still unclear. Herein, an efficient catalyst is developed for CO₂-to-CO conversion realized on diverse N-C_b materials with hierarchical pore structures. It is demonstrated that the CO₂-to-CO conversion preferentially takes place on positively charged carbon atoms next to pyridinic-N using two representatives treated pollens with the largest difference in pyridinic-N density and N content as model photocatalysts. Systematic experimental results indicate that surface local electric field originating from charge separation can be boosted by hierarchical pore structures, doped N, as well as pyridinic-N. Mechanistic studies reveal that positively charged carbon atoms next to pyridinic-N serve as active sites for CO₂RR, reduce the energy barrier on the formation of CO*, and facilitate the CO₂RR performance. All these benefits cooperatively contribute to treated chrysanthemum pollen catalyst exhibiting excellent CO formation rate of 203.2 µmol h⁻¹ g⁻¹ with 97.2% selectivity in pure water vapor. These results provide a new perspective into CO₂RR on N-C_b, which shall guide the design of nature-based photocatalysts for high-performance solar-fuel generation.     

基于粒矩阵的多输入多输出真值表快速并行约简算法

真值表是表征逻辑输入与输出之间因果关系的重要工具,真值表约简在数字逻辑电路的分析与设计中具有重要意义.该文将真值表看作逻辑信息系统,将真值表约简转化为逻辑信息系统的最简规则获取.采用粒计算分层粒化的思想,在不同粒度下,利用粒矩阵的知识表示形式、粒矩阵中的启发式知识以及粒矩阵运算,设计了多输入多输出真值表快速并行约简算法.以发光二极管七段数字显示器为例进行了算法说明,通过数学证明和算法复杂性分析证明了算法的正确性和有效性.     

（3+1）维广义KdV-Zakharov-Kuznetsev方程的对称、约化和精确解

利用直接对称方法得到了广义KdV-Zakharov-Kuznetsev方程（简写为mKdV-ZK）的对称约化、精确解,其中包括椭圆函数解,幂级数解,艾米儿函数解等. 利用得到的对称,求出了该方程的守恒律.     

计算无圈有向网络ST可靠性的一个新方法

本文考虑计算无圈有向网络的ＳＴ可靠性问题（至少存在一条从源点ｓ到汇点ｔ的正常运行道路的概率）。文章引进了深度优先搜索（Ｄｅｐｔｈ－ＦｉｒｓｔＳｅａｒｃｈ）有序根树的概念并提出一个新的计算无圈有向网络ＳＴ可靠性的拓扑公式。以该公式为基础,我们利用ＤＦＳ方法提出一个新的计算无圈有向网络ＳＴ可靠性算法,它能生成简洁的可靠性表达式,进而有效地计算无圈有向网络的ＳＴ可靠性。两个例子例证了我们的结论     

A cross-reference method of parameter estimation and noise reduction and its applications

This paper proposes a cross-reference method of nonlinear time series analysis, combining the tasks of dynamical system parameter estimation and noise reduction which were fulfilled separately before. With the positive interaction between the two processing modules, the method is somewhat superior. Some prior works can be viewed as special cases of this general framework and effective new algorithms may be devised according to it. Two examples of chaotic time series analysis are also given to show the applicability of the proposed method.