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91.
Julian Kosacki Dimitri Feys Fatih Dogan 《International Journal of Applied Ceramic Technology》2022,19(4):2029-2035
Due to its rheological properties, positive lead-acid battery paste can be difficult to spread on lead current collectors accurately and efficiently under industry machinery and setting. Sodium polymethacrylate dispersant was studied as an effective positive paste additive that could lower the yield stress of the paste without affecting paste density and battery performance. Under a four-blade vane rheometer setup, stress growth and oscillatory amplitude strain sweep experiments evaluated the rheological properties of positive paste with the addition of varying amounts of sodium polymethacrylate. Further, the electrochemical effects of sodium polymethacrylate were also evaluated in 2V batteries by testing positive active material utilization and cycle life. 相似文献
92.
A carbon paste electrode was modified with red algal specie of Porphyridium cruentum and then characterization of its electrocatalytic activity was demonstrated with cyclic voltammetric studies of potassium ferricyanide (K3[Fe(CN)6]) system. Stable and fast response of modified electrode to redox couple of [Fe(CN)6]3?/[Fe(CN)6]4? was highlighted by performing experiments in comparison to bare carbon paste electrode. Fourier transform infrared spectra revealed the functional moieties of bare and modified electrode. Electrochemical surface area and surface coverage capacity were calculated for both electrodes. The effect of scan rate helped evaluate the nature of electrode process, electron transfer mechanism, and kinetic parameters (rate constant, charge transfer coefficient). 相似文献
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Electroactive behavior assessment of poly(acrylic acid)‐graphene oxide composite hydrogel in the detection of cadmium
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Areli Bejarano‐Jiménez Vladimir A. Escobar‐Barrios J. Mieke Kleijn Cesar A. Ortíz‐Ledón Luis F. Cházaro‐Ruiz 《应用聚合物科学杂志》2014,131(19)
Super absorbent polymers of acrylic acid‐graphene oxide (PAA‐GO) were synthesized with different percentage of chemical neutralization (0, 10, and 20%) of the acrylic acid monomer before its polymerization. The influence of their swelling and adsorption/desorption capacity of cadmium ions in aqueous solutions were studied and revealed that the GO enables greater mechanical stability in the materials. The PAA hydrogels, with the same degrees of neutralization, were also prepared without GO to compare with the composites. Additionally, carbon paste electrodes (CPE) modified with the composites PAA‐GO were used to asses and compare their adsorption properties with cadmium(II). The anodic stripping voltammetry (ASV) peak, in the differential pulse voltammetry mode, for cadmium oxidation was found to be influenced by the presence of GO into the polymer, and also by their percentage of neutralization. The accumulation of cadmium(II) on the surface of the modified CPEs was performed under open‐circuit conditions taking an account the preconcentration time of the metal cation. The presence of GO enhances the electrical signal of the electrodes in short times of immersion in cadmium(II) solutions. This property contributed to get linear responses of the CPEs modified with the composites, which were influenced by their degrees of neutralization. The PAA‐GO 10N electrode with 10% of neutralization combined the influence of GO and the degree of neutralization in the same matrix, and also showed good performance in terms of its mechanical stability, it was chosen for preliminary studies on the selectivity of the electrode toward Zn(II) and Cu(II). © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40846. 相似文献
95.
The last decade has seen a growing interest in hybrid electrically conducting nanocomposites. This article aims to provide a detailed overview of the present status of research in carbon nanotube–polyaniline (CNT/PANI) composites, from processing to structural and property evaluations. CNT/PANI are synthesized by electrochemical and chemical processing. When chemical methods are used, the main challenge is to obtain processable CNT/PANI in the emeraldine salt (ES) form composites. Stable dispersions of ES–CNT in organic media are prepared using the post doping method, inverse emulsion polymerization, or ex situ polymerizations. On the contrary, stable water dispersions of CNT/ES are prepared using hydrophilization of a preformed CNT/ES composite, direct synthesis of micelle–CNT hybrid templates, interfacial polymerization, covalent functionalization of CNT with a water soluble polymer, or using electrostatic interactions between two oppositely charged ES and CNT aqueous colloids. Moreover, the strategies for the synthesis of ternary CNT/PANI composites incorporating noble metal nanoparticles, metal oxide, or graphene sheets are also presented and analyzed in depth. Finally, we give a review of potential applications, including chemical sensors, capacitors, fuel cells and electronic devices. 相似文献
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《Journal of the European Ceramic Society》2014,34(2):373-379
Apatite-type lanthanum silicate based films have attracted significant interests to use as an electrolyte of solid oxide fuel cells (SOFCs) working at intermediate temperature. We have prepared Mg doped lanthanum silicate (MDLS) films on NiO–MDLS cermet substrates by spin coating and sintering of nano-sized printable paste made by beads milling. Changes in crystal structure and microstructure of the paste films with the sintering temperature have been investigated to show that porous network structure with a grain growth evolves up to 1300 °C, whereas densification occurred above 1400 °C. Anode supported SOFCs using the pasted MDLS films were successfully fabricated: an open circuit voltage of 0.91 V and a maximum power density of 150 mW cm−2 measured at 800 °C were obtained with the electrolyte film sintered at 1500 °C. 相似文献
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针对传统二水法磷酸副产的磷石膏杂质含量高、色泽差、资源化利用率低的问题,发明了湿法磷酸副产白石膏技术,所产的白石膏杂质含量低,可全部资源化利用。以我国目前湿法磷酸年产量计,年可产出白石膏5 000万t,市值达数百亿元,经济与社会效益好。 相似文献