Phase behavior of ternary blends containing dimethylpolycarbonate,tetramethylpolycarbonate and poly[styrene‐co‐(methyl methacrylate)] copolymers (or polystyrene)

The miscibility and phase behavior of ternary blends containing dimethylpolycarbonate (DMPC), tetramethylpolycarbonate (TMPC) and poly[styrene‐co‐(methyl methacrylate)] copolymer (SMMA) have been explored. Ternary blends containing polystyrene (PS) instead of SMMA were also examined. Blends of DMPC with SMMA copolymers (or PS) did not form miscible blends regardless of methyl methacrylate (MMA) content in copolymers. However, DMPC blends with SMMA (or PS) blends become miscible by adding TMPC. The miscible region of ternary blends is compared with the previously determined miscibility region of binary blends having the same chemical components and compositions. The region where the ternary blends are miscible is much narrower than that of binary blends. Based on lattice fluid theory, the observed phase behavior of ternary blends was analyzed. Even though the term representing the Gibbs free energy change of mixing for certain ternary blends had a negative value, blends were immiscible. It was revealed that a negative value of the Gibbs free energy change of mixing was not a sufficient condition for miscible ternary blends because of the asymmetry in the binary interactions involved in ternary blends. Copyright © 2004 Society of Chemical Industry     

反渗透膜仓用韧性环氧树脂基体研究

工业上广泛使用反渗透膜仓制备高纯水,为了用玻璃钢替代不锈钢,研究了一种适合湿法缠绕的反渗透膜仓用韧性环氧基体。在配方中采用液体酸酐固化剂甲基四氢邻苯二甲酸酐和高效活性增韧剂,对树脂基体和复合材料力学性能及耐水性能的研究表明该树脂基体具有许多优良性能,如拉伸强度≥86.2MPa,断裂延伸率≥5.2%,弯曲强度≥139MPa,制得膜仓爆破时纤维强度转化率高达88.7%,耐疲劳达10万次而无损伤。此外,配方体系室温下粘度为0.35～0.4Pa·s,适用期≥8h,室温下在水中浸泡180d后吸水率低于0.5%,同不锈钢相比成本降低1/2。实验结果表明,该韧性环氧基体完全适用于反渗透膜仓使用。     

Electrical conductivity of ferroelectric sodium vanadate,rubidium vanadate,cesium vanadate and their solid solutions

The d.c. electrical conductivity of sodium vanadate, rubidium vanadate, cesium vanadate and their solid solutions sodium-rubidium vanadate and sodium-cesium vanadate were studied by a two-probe method in the temperature range covering their transition points. The electrical conductivity shows sharp change at the phase transition temperature of these materials. In NaVO₃, RbVO₃ and CsVO₃, increase in d.c. conductivity is observed in the ferroelectric region while nonlinearities are observed above transition temperatures. In solid solutions, the activation energy in the paraelectric state is higher than that in the ferroelectric state and depends upon sodium concentration.     

Al/Fe2O3反应合成材料热力学

运用CALPHAD技术，基于多组元多相复杂平衡体系的吉布斯自由能最小化原理，用大型集成数据库F^*A^*C^*T系统，考察了铝和氧化铁经典反应体系的热力学规律。针对材料的反应合成技术，计算了化学计量铝和氧化铁体系以及各种产物中物种的相变情况；分析了原料初始温度、配料比和SiO2含量对绝热温度和平衡组成的影响。     

Influence of nano-scaled dispersed second phase on substructure of deformed dispersion strengthened copper alloy

The deformation behavior of dispersion strengthened copper alloy Cu-Al2O3 was studied by TEM. The results show that nano-scaled dispersed second phase not only increases dislocation density in matrix, but also has an important influence on the dislocation substructure. The presence of fine dispersed Al2 O3 particles results in a uniform and random dislocation distribution in matrix copper and causes the difficulty in formation of dislocation cell structure and the decrease in the amount of cell structure during deformation. Deformation gives rise to much more dislocations and dislocation cells form more difficultly and the decrease in the cell size with the increase of dispersion degree.     

Preparation of BaMgAl10O17∶Eu2+ and Its Phase Behavior in Microemulsion System

BaMgAl10O17∶Eu2 (BAM) was prepared in the microemulsion system and its phase behavior was studied. There exists a small region in the reverse microemulsion system where the dispersed particles are of spherical form. In this way, BAM blue phosphor with good dispersion can be synthesized. The microemulsion phase diagrams of the pseudo-ternary system (Triton X-100/cosurfactant-oil-BAM brine) were first established intuitively by the dilution method. The microstructure of microemulsions was determined through eyeballing, conductance technique, and polar optical microscopy. Its phase behavior is affected by various factors, such as temperature (room temperature, 30, 40 ℃), oil, surfactants, and cosurfactants in microemulsions. According to the phase diagrams, the microemulsion system of Triton X-100/1-hexanol-hexane-BAM brine was chosen to prepare the precursor. The BAM phosphor can be obtained via sintering the precursor at a comparatively low temperature. The phosphors were characterized by XRD and vacuum ultraviolet (VUV) spectra.     

SHS of shape memory CuZnAl alloys

Aiming at preparation of shape memory alloys (SMAs), we explored the SHS of Cu_{1 − x} Zn_{1 − y} Al_{1 − z} alloys (0.29 < x < 0.30, 0.74 < y < 0.75, and 0.83 < z < 0.96). The most pronounced shape memory effect was exhibited by the alloys of the following compositions (wt %): (1) Cu(70.6)Zn(25.4)Al(4.0), (2) Cu(70.1)Zn(25.9)Al(4.0), and (3) Cu(69.9)Zn(26.1)Al(4.0). The effect of process parameters on the synthesis of CuZnAl alloys was studied by XRD, optical microscopy, and scanning electron microscopy (SEM). The grain size of CuZnAl was found to depend on the relative amount of the primary CuZn and AlZn phases. Changes in the transformation temperature and heat of transformation are discussed in terms of ignition intensity and compaction. Mechanism of the process depends on the level of the temperature attained relative to the melting point of components. At the melting point of AlZn, the process is controlled by the solid-state diffusion of AlZn into a product layer. The ignition temperature for this system depends on the temperature of the austenite-martensite transformation in CuZnAl alloys. The composition and structure of the products was found to markedly depend on process parameters. The SHS technique has been successfully used to prepare a variety of SMAs.      

Influence of a lipid phase on steam jet agglomeration of maltodextrin powders

The contribution of an oil phase to the agglomeration mechanisms of food powders was evaluated. Maltodextrin (DE 10), palm oil stearin and two palm oil oleins (up to 25% dry mass) were used as food models. Granulation runs were carried out in a pilot plant steam jet agglomerator. The powders containing oleins were more cohesive than those with stearin and the presence of oil changed the agglomeration mechanisms. The size increase mechanism of pure maltodextrin powder was controlled by surface plasticization and agglomerates with suitable instant properties were obtained. Small amount of oil degenerated drastically the rate of dispersion in water of the powders and their agglomerates but the average size and the mechanical resistance of the agglomerates increased when the oil content of the powders increased. SEM micrographs of agglomerates indicated that higher lipid content in the powders produced compact granules, favoring sinkability but hindering their disintegration. Agglomeration enhanced considerably the flowability of the particles containing oil. The dispersion behavior of the powders with higher lipid content could be correlated with the Hausner Number. A pre-agglomeration step favored the blend of the more cohesive powders producing larger and more resistant agglomerates.     

真空相变锅炉低排烟温度设计与低温腐蚀

真空相变锅炉是否会明显发生烟气低温腐蚀，一直众说不一。文章从锅炉发生低温腐蚀的机理人手，通过理论分析计算并通过实践检验，提出了真空相变锅炉虽然不能完全避免低温腐蚀问题，但不论排烟温度是否高于烟气露点，低温腐蚀的程度都很弱的观点；给出了真空相变锅炉沿烟气流程金属壁面的腐蚀速度与壁面温度的关系曲线，和烟气温度低于酸露点时金属壁面的腐蚀速度与壁面温度的关系曲线；同时，文章推荐真空相变锅炉的设计排烟温度取130℃左右的低排烟温度。根据上述观点设计的数百台产品已经过多年实际运行，未发现明显     

松辽盆地南部岩性圈闭识别技术及效果

寻找隐蔽油气藏一直是油气勘探中的难题,我国东部吉林油田的中浅层已进入高成熟勘探阶段,油气勘探已由早期的构造圈闭勘探转变为现今的以隐蔽圈闭勘探为主的阶段。本文针对松辽盆地南部的西部前缘带三维连片工区及伊通地堑岔路河断陷,综合应用构造精细解释、声波曲线重构波阻抗反演、层序地层学、地震相及沉积(微)相分析、模型正演、地震属性分析、频谱分解及三维可视化等技术手段,所提供的多口探井获得工业油气流或有良好的油气显示,取得了较好的解释效果。