全文获取类型
收费全文 | 70750篇 |
免费 | 7869篇 |
国内免费 | 2815篇 |
专业分类
电工技术 | 1063篇 |
技术理论 | 1篇 |
综合类 | 3025篇 |
化学工业 | 26723篇 |
金属工艺 | 10120篇 |
机械仪表 | 1336篇 |
建筑科学 | 1974篇 |
矿业工程 | 1010篇 |
能源动力 | 1358篇 |
轻工业 | 9543篇 |
水利工程 | 373篇 |
石油天然气 | 1341篇 |
武器工业 | 346篇 |
无线电 | 2645篇 |
一般工业技术 | 16512篇 |
冶金工业 | 2915篇 |
原子能技术 | 252篇 |
自动化技术 | 897篇 |
出版年
2024年 | 438篇 |
2023年 | 1657篇 |
2022年 | 2413篇 |
2021年 | 3226篇 |
2020年 | 2989篇 |
2019年 | 2556篇 |
2018年 | 2834篇 |
2017年 | 3238篇 |
2016年 | 3242篇 |
2015年 | 3360篇 |
2014年 | 3972篇 |
2013年 | 5090篇 |
2012年 | 4551篇 |
2011年 | 5582篇 |
2010年 | 3748篇 |
2009年 | 4066篇 |
2008年 | 3392篇 |
2007年 | 3720篇 |
2006年 | 3547篇 |
2005年 | 2809篇 |
2004年 | 2740篇 |
2003年 | 2339篇 |
2002年 | 1915篇 |
2001年 | 1326篇 |
2000年 | 1184篇 |
1999年 | 916篇 |
1998年 | 822篇 |
1997年 | 695篇 |
1996年 | 535篇 |
1995年 | 462篇 |
1994年 | 345篇 |
1993年 | 254篇 |
1992年 | 263篇 |
1991年 | 212篇 |
1990年 | 246篇 |
1989年 | 237篇 |
1988年 | 84篇 |
1987年 | 57篇 |
1986年 | 59篇 |
1985年 | 69篇 |
1984年 | 67篇 |
1983年 | 33篇 |
1982年 | 55篇 |
1981年 | 7篇 |
1980年 | 35篇 |
1979年 | 7篇 |
1978年 | 6篇 |
1975年 | 6篇 |
1974年 | 6篇 |
1951年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
931.
Polymeric materials are being developed with renewable resources to promote industrial progress with environmentally friendly technologies. For this reason, polyurethane samples were prepared with 4,4′‐diphenylmethane diisocyanate (NCO/OH = 1), eucalyptus tar pitch (biopitch), castor oil as a polyol, and dibutyltin dilaurate as a catalyst. These materials were reinforced with different contents of short sisal fibers (0, 2.5, 5.0, 7.5, and 10.0%) and were prepared by resin‐transfer molding. The composites were characterized by IR absorption spectroscopy, thermal analysis (thermogravimetry and differential scanning calorimetry), impact resistance, scanning electron microscopy, and water absorption resistance. These materials showed hydrophobic characteristics, despite the addition of sisal fibers. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 3797–3802, 2003 相似文献
932.
A crosslink‐able elastomeric polyester urethane (PEU) was blended with a thermoplastic, polyacrylonitrile (PAN), and electrospun into nanofibers. The effects of the PEU/PAN ratio and the crosslinking reaction on the morphology and the tensile properties of the as‐spun fiber mats were investigated. With the same overall polymer concentration (9 wt %), the nanofiber containing higher composition of PEU shows a slight decrease in the average fiber diameter, but the tensile strength, the elongation at break and tensile modulus of the nanofiber mats are all improved. These tensile properties are further enhanced by slight crosslinking of the PEU component within the nanofibers. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
933.
Preparation and characterization of multi-walled carbon nanotubes supported PtRu catalysts for proton exchange membrane fuel cells 总被引:1,自引:0,他引:1
A series of PtRu nanocomposites supported on H2O2-oxidized multi-walled carbon nanotubes (MWCNTs) were synthesized via two chemical reduction methods—one used aqueous formaldehyde (HCHO method) and the other used ethylene glycol (EG method) as the reducing agents. The effects of the solvents (water and ethylene glycol) and the surface composition of the MWCNTs on the deposition and the dispersion of the metal particles were investigated using N2 adsorption, TEM, ICP-AES, FTIR and TPD. The wetting heats of the MWCNTs in corresponding solvents were also measured. The characterizations suggest that combination of the surface chemistry of the MWCNTs with the solvents decides the deposition and the dispersion of the metal nanoparticles. These nanocomposites were evaluated as proton exchange membrane fuel cell anode catalysts for oxidation of 50 ppm CO contaminated hydrogen and compared with a commercial PtRu/C catalyst. The data reveal superior performances for the nanocomposites prepared by the EG method to those by the HCHO method and even to that for the commercial analogue. Structure–performance relationship of the nanocomposites was also studied. 相似文献
934.
This study was devoted to the prediction of polymer material aging. The prediction of the shelf time of tire rubber is used as an example in this article. The main steps of the whole procedure are described. They are the design of the experiment, accelerated aging testing, the construction of a multiresponse mathematical model and parameter estimation, and the extrapolation of the model in real‐life settings. The main pitfalls were deduced, and techniques to overcome these pitfalls are described. Novel methods of data modeling, such as evolutionary design of experiment and successive Bayesian estimation, were used. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 95: 1275–1284, 2005 相似文献
935.
加成型硅橡胶灌封料流变性能的研究 总被引:2,自引:0,他引:2
研究了加成型硅橡胶灌胶封料的注性能。测定了硅橡胶灌封料的粘度,讨论了配制工艺条件及组份对硅橡胶灌封料流变性能的影响,分析了白炭黑在硅橡胶灌封料中的分散状态,实验结果表明,通过改进配制工艺条件,优化组分,可以制备出满足特定需要并具有高流动性的硅橡胶灌封料。 相似文献
936.
Mechanical properties of wood plastic composites (WPCs) manufactured from sawdust and virgin and/or recycled plastics, namely high density polyethylene (HDPE) and polypropylene (PP), were studied. Sawdust was prepared from beech industrial sawdust by screening to the desired particle size and was mixed with different virgin or recycled plastics at 50% by weight fiber loading. The mixed materials were then compression molded into panels. Flexural and tensile properties and impact strength of the manufactured WPCs were determined according to the relevant standard specifications. Although composites containing PP (virgin and recycled) exhibited higher stiffness and strength than those made from HDPE (virgin and recycled), they had lower unnotched impact strengths. Mechanical properties of specimens containing recycled plastics (HDPE and PP) were statistically similar and comparable to those of composites made from virgin plastics. This was considered as a possibility to expand the use of recycled plastics in the manufacture of WPCs. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3641–3645, 2006 相似文献
937.
Nutthakan Pongrakananon Nathaporn Somrang Worakanya Visitsart Pitt Supaphol Manit Nithitanakul Brian P. Grady 《应用聚合物科学杂志》2004,91(4):2216-2222
The effect of methyl acrylate content in ethylene–methyl acrylate–acrylic acid (E–MA–AA) terpolymers and acrylic acid content in ethylene–acrylic acid (E–AA) copolymers was investigated in blends of these two materials. The E–MA–AA terpolymer with 8 mol % methyl acrylate was not miscible with any E–AA material no matter what the AA content, whereas the terpolymer with only about 2 mol % methyl acrylate was miscible, at least to some extent, with the E–AA copolymer at high acrylic acid contents. Evidence supporting this conclusion derived from gloss, differential scanning calorimetry testing, and dynamic mechanical measurements. For the E–AA polymer material with the highest acid content, there was a synergistic effect for some properties at low added amounts of E–MA–AA copolymer; the tensile strength and hardness were 10% higher than values for the E–AA copolymer, even though the E–AA copolymer was much stiffer. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 2216–2222, 2004 相似文献
938.
Porous carbon beads were prepared by carbonizing at 700 and 1000 °C under N2 (NN-series) or CO2 atmospheres (CO-series) and a subsequent oxidization with boiling nitric acid solution (13%, v/v) for 3 h (ANN- and ACO-series). BET surface area of both CO- and NN-series samples tends to increase with increasing carbonization temperature, but CO-series samples show higher BET surface areas (700 °C: 610 m2/g, 1000 °C: 780 m2/g) compared with those of NN-series samples (700 °C: 380 m2/g, 1000 °C: 580 m2/g). After acid oxidation, BET surface areas of NN-series samples increased from 580 to 650 m2/g, whereas those of CO-series samples decreased from 780 to 600 m2/g. On subsequent acid oxidation, acidic surface functional groups increased in both CO- and NN-series samples, but the CO-series samples tend to have much more acidic surface functional groups. Adsorption of halogenated methanes, such as tetra-, tri- and dichloromethanes, onto the samples of CO-, NN-, ACO- and ANN-series was thought to be driven initially by the basicity, but the acidic functional groups that could attract adsorbates via dipole-dipole interaction might hinder the adsorption of subsequently incoming adsorbates. 相似文献
939.
Dong-Wan Kim Do-Kyun Kwon Kug Sun Hong Deug Joong Kim 《Journal of the American Ceramic Society》2003,86(5):795-799
Samples of 1/6Ba5 Nb4 O15 ·5/6BaNb2 O6 along with the pure end members, Ba5 Nb4 O15 and BaNb2 O6 , were sintered under low oxygen partial pressure. The degradation mechanisms of dielectric loss in this reducing atmosphere have been studied. We found that the degradation occurred primarily due to the formation of oxygen vacancies caused by the reduction of Nb5+ . This was determined by measuring the electrical conductivity, and through X-ray photoelectron spectroscopy. More importantly, the dielectric loss of 1/6Ba5 Nb4 O15 ·5/6BaNb2 O6 samples with higher temperature stability was further decreased on sintering in a reducing atmosphere. This observation has been explained by considering the increased porosity and formation of a reduced second phase, Ba0.65 NbO3 . 相似文献
940.
High‐abrasion furnace black (HAF, grade N330)–filled powdered styrene butadiene rubber [P(SBR/HAF)] was prepared and the particle size distribution, mixing behavior in a laboratory mixer, and mechanical properties of P(SBR/HAF) were studied. A carbon black–rubber latex coagulation method was developed for preparing carbon black–filled free‐flowing, noncontact staining SBR powders, with particle diameter less than 0.9 mm, under the following conditions: carbon black content > 40 phr, emulsifier/carbon black ratio > 0.02, and coating resin content > 2.5 phr. Over the experimental range, the mixing torque τα of P(SBR/HAF) was not as sensitive to carbon black content and mixing temperature as that of HAF‐filled bale SBR (SBR/HAF), whereas the temperature build‐up ΔT showed little dependency on carbon black content. Compared with SBR/HAF, P(SBR/HAF) showed a 20–30% mixing energy reduction with high carbon black content (>30 phr), which confers to powdered SBR good prospects for internal mixing. Carbon black and the rubber matrix formed a macroscopic homogenization in P(SBR/HAF), and the incorporation step is not obvious in the internal mixing processing results in these special mixing behaviors of P(SBR/HAF). A novel mixing model of carbon black–filled powdered rubber, during the mixing process in an internal mixer, was proposed based on the special mixing behaviors. P(SBR/HAF) vulcanizate showed better mechanical properties than those of SBR/HAF, dependent primarily on the absence of free carbon black and a fine dispersion of filler on the rubber matrix attributed to the proper preparation conditions of noncontact staining carbon black–filled powdered SBR. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 2494–2508, 2004 相似文献