鱼类耳石扫描电镜样品制备与观察

本文介绍了一种鱼类耳石样品的扫描电镜制样方法，通过对草鱼耳石进行包埋，抛磨，并用合适的腐蚀剂处理，用ＳＥＭ成功地观察了耳石的日轮及超微结构，该方法简便易行，保证所观察耳石样品的微观结构完整与清晰。     

Photo-reversible Reaction in Polymer Langmuir-Blodgett Films

Preparation of photoreactive Langmuir-Blodgett (LB) films was carried out using polymers/oligomers prepared from long-chain dialkyl esters of di-and tetra-olefins and having cyclobutane rings in the main chain. These polymers/oligomers formed stable monolayers on a water surface when mixed with arachidic acid. These monolayers could be deposited onto a substrate successfully forming Y-type films. The oligomer LB films were polymerized on irradiation. The polymer LB films showed a photo-reversible process between polymers and oligomers, depending on wavelength of the irradiating light. On the basis of spectral data and molecular weight change, this behaviour was found to be caused by cleavage and formation of cyclobutane rings.     

A new approach to the mechanism of chlorine evolution: Separate examination of the kinetic steps using ac impedance on a rotating thin ring electrode

In the absence of a bulk diffusion effect, it is shown for the first time that the impedance spectra for the chlorine evolution reaction on a rotating thin ring electrode comprise three consecutive semicircles in the capacitive half of the complex plane. The first (highest frequency) semicircle is due to the charge-transfer resistance for chloride discharge and the simultaneous chlorine adsorption coupled to the double-layer capacitance. The second semicircle (around 5 Hz) is due to the adsorption and desorption of a chlorine intermediate. The third (lowest frequency, around 0.5 Hz) semicircle is due to the relaxation of surface oxygen species. The impedance data allow the steps of the overall reaction to be examined individually. On a Pt surface the rate of chloride discharge and simultaneous chlorine adsorption (the admittance of the first semicircle) is first order with respect to chloride concentration and has a potential-dependence close to 58 mV/decade. The rate of the adsorption and desorption process (the admittance of the second semicircle) is second order with respect to chloride concentration, and has a potential dependence close to 30 mV/decade. The time constant for the adsorption/desorption processes is ca 20 ms, independent of electrode potential in the range studied. These features are consistent with a mechanism in which a faster discharge reaction (Cl⁻ Cl_ad + e) is followed by a slower surface combination reaction (2Cl_ad → Cl₂), but inconsistent with mechanisms in which ion + atom desorption is predominant, the initial chloride discharge is slow, or a unipositively charged chlorine species is involved.     

减小磁滞损耗的偏转磁芯设计

本文通过对偏转磁芯用的铁氧体材料的磁滞损耗特性的分析 ,提出了通过改变偏转磁芯外表面形状以减小磁滞损耗的方法。优化计算结果表明 ,对于Philips 17″CMT的 3C2材料 5mm壁厚的磁芯 ,改用椭圆外表面的磁芯后 ,磁滞损耗降低了 2 7 5 %。     

Proton and hydrogen formation by cyclohexyl benzene during overcharge of Li-ion batteries

This study provides experimental evidence for proton and hydrogen formation caused by the anodic electropolymerization of cyclohexyl benzene (CHB), which is a popular electrolyte additive for overcharge protection of lithium-ion batteries (LIBs). It is found that considerable H₂ evolution is observed in overcharged LiCoO₂/graphite cells, especially when CHB is included as an electrolyte additive. In order to confirm the proton generation during the CHB oxidation, Pt/Pt-rotating ring disc electrode (RRDE) measurements are performed in 1 M Li(C₂F₅SO₂)₂N ethylene carbonate/ethyl methyl carbonate (1/2, v/v) solutions with and without CHB. The cathodic ring current is intimately correlated to the anodic disc current, and the cathodic reaction at the ring is determined to be the reduction of the proton. The proton generation efficiency during the CHB oxidation is as high as 90%. Proton liberation is also observed during the anodic decomposition of the electrolyte solvents, although it occurs in a much less stoichiometric way compared with that during the CHB oxidation.     

PLC在环锭捻线机上的应用

介绍了如何使用PLC和数字变频调速技术 ,对传统环锭捻线机进行技术改造 ,使锭速、捻度和卷绕成形变换实现数字化柔性控制 ,扩大了工艺参数的变化范围 ,使整个捻线加工车间实现信息化管理成为可能。     

CT引导下经皮穿刺骨骼活检时穿刺针的选择与应用

在行骨骼活检时，穿刺针的选择非常重要，甚至直接影响着活检的成功与否。笔者根据多次实践，应用环锯和Ackerman钻取外替代传统的活检方法取得了较好的效果。     

WDM光环形网络保护及实现方法

提出了WDM环形网络的几种保护方案,分析了利用1:1环路配置方式进行WDM光环形网络保护的实现方法,简单介绍APS在环保护中的应用。     

带纵向槽筒形件拉深方法的研究

针对传境拉深带纵向槽筒形件的方法的缺点,采用一次拉深成形的方法,并通过试验和计算获得毛坯的形状和尺寸。     

小孔矩形腔体屏蔽特性的研究

本文提出了有孔腔体远、近场电磁屏蔽效能的计算方法，体研究了矩形腔体的屏蔽特性，讨论了各类孔对屏蔽能的影响程度。数值结果表明，理论计算与实验数据吻合较好。