Monoalkyl Esters of Isoalkylphosphonic Acid as Extractants in Rare Earth Separation

Four monoalkyl esters of isoalkylphosphonic acids have been studied for the chromatographic separation ofrare earths (RE).The relationship between distribution ratios and acid concentration of the eluants forsamarium and ytterbium has been explored.The characteristics of these extractants loaded onto macroreticularpoly (methyl methacrylate) resin beads for the separation of lanthanum,cerium,praseodymium and neodymiumhave been compared.Among the extractants studied,mono(1-methylheptyl) ester of isooctylphosphonic acidwas found to be the best for RE separation.The acidity for separation is lower than any known P-containingextractants for the same purpose.For instance,with 1.73 mol·L~(-1) nitric acid as eluent,thulium,ytterbium andlutetium can be separated quantitatively.The extractant-loaded resins possess high column efficiency with goodkinetic characteristics.The extraction mechanism was also explored.     

生物降解塑料的研究现状及问题

生物降解塑料这一领域的研究和发展正成为人们普遍关注的焦点。生物降解塑料根据其降解机理和破坏形式，可分为完全生物降解塑料和生物崩坏性(致劣性)塑料两种。这种新型塑料涉及化工、高分子、生物学等多门学科，属于一项高新技术。尽管各国投入了较大的人力、物力，但至今还未普遍达到实用阶段，在研究开发、市场、应用等方面还存在许多问题。     

岩屑泊松比实验测定仪

针对目前地层泊松比测定方法的局限 ,提出了利用上返岩屑压实测定地层泊松比的设想 ,并研制出岩屑泊松比实验测定仪。某油田已有的压实岩屑泊松比与实际声波测井资料计算泊松比对比发现 ,运用岩屑泊松比实验测定仪所得的实验结果与原始地层的泊松比有很好的一致性(两者的误差在± 5 %之间 )。利用该测定仪 ,可实现对钻井过程中上返岩屑的连续快速测定 ,大大降低工程取心所增加的钻井成本 ,还可为钻井施工在第一时间提供相关的地层信息     

兴企之要 惟在用人

阐述了人力资源管理在企业发展中的重要作用;对如何引入竞争机制、知人善任、建立科学的激励机制和约束机制、改革管理体制等方面进行了论述。     

石油价格机制改革之对策

文章在阐述我国石油价格形成机制的演变过程的基础上,针对我国目前石油定价机制所导致的诸如石油价格变动滞后以及由此带来的市场信号失灵等问题思考了相应的改革对策,提出了调整政府价格管理职能、建立平等竞争的市场规则、完善稳定油价的调控体系以及加快建立石油战略储备等7个方面的建议。     

大庆蜡油在酸性催化剂上反应机理的研究

以大庆蜡油为原料，采用两种不同类型的催化剂，在流化床反应器实验装鬣上进行催化裂化反应。结果表明，大庆蜡油在酸性催化剂上反应所产生的干气组成与高烯烃催化裂化汽油相同，干气的产生主要是单分子裂化反应所造成的。从干气产率、组成以及液化气组成可以看出，大庆蜡油在不同类型的催化剂上明显地表现出裂化反应类型的差异。     

On a responsive replenishment system: a fuzzy logic approach

In today's competitive business environment, it is important that customers are able to obtain their preferred items in the shops they visit, particularly for convenience store chains such as 7–Eleven where popular items are expected to be readily available on the shelves of the stores for buyers. To minimize the cost of running such store chains, it is essential that stocks be kept to a minimum and at the same time large varieties of popular items are available for customers. In this respect, the replenishment system needs to be able to cope with the taxing demands of minimal inventory but at the same time keeping large varieties of needed items. This paper proposes a replenishment system which is able to respond to the fluctuating demands of customers and provide a timely supply of needed items in a cost–effective way. The proposed system embraces the principle of fuzzy logic which is able to deal with uncertainties by virtue of its fuzzy rules reasoning mechanism, thereby leveraging the responsiveness of the entire replenishment system for the chain stores. To validate the feasibility of the approach, a case study has been conducted in an emulated environment with promising results.     

A strategy for the electro-organic synthesis of new hydrocaffeic acid derivatives

Electrochemical treatment processes can significantly contribute to the protection of the environment through the minimization of waste and toxic materials in effluents. From a pharmaceutical point of view and due to the existing resemblance between the electrochemical and biological reactions, it can be assumed that the oxidation mechanisms on the electrode and in the body share similar principles. In this paper, the application of electrochemical studies in the design of an environmentally friendly method was delineated for the new hydrocaffeic acid (HCA, 3,4-dihydroxy hydrocinnamic acid) derivatives synthesis at carbon electrodes in an undivided cell. In this cell, the EC mechanism reaction was involved, comprising two steps alternatively; (1) electrochemical oxidation and (2) chemical reaction. In particular, the electro-organic reactions of HCA, an important biological molecule, were studied in a water–acetonitrile (90:10 v/v) mixture in the presence of benzenesulfinic acid (3) and p-toluenesulfinic acid (4). The research included the use of a variety of experimental techniques, such as cyclic voltammetry, controlled-potential electrolysis and product spectroscopic identification.     

山特维克可乐满公司切削刀具涂层技术的发展

介绍了山特维克可乐满公司切削刀具涂层技术的发展，并对该公司自1979年以来硬质合金涂层产品的发展情况进行了总结。     

Improving Neural Networks for Mechanism Kinematic Chain Isomorphism Identification

Detection of isomorphism among kinematic chains is essential in mechanical design, but difficult and computationally expensive. It has been shown that both traditional methods and previously presented neural networks still have a lot to be desired in aspects such as simplifying procedure of identification and adapting automatic computation. Therefore, a new algorithm based on a competitive Hopfield network is developed for automatic computation in the kinematic chain isomorphism problem. The neural approach provides directly interpretable solutions and does not demand tuning of parameters. We have tested the algorithm by solving problems reported in the recent mechanical literature. Simulation results show the effectiveness of the network that rapidly identifies isomorphic kinematic chains.