水性核（PMMA）／壳（PU）聚氨酯丙烯酸酯杂化乳液的合成研究

合成高Tg低成膜温度的水性聚氨酯丙烯酸酯杂化乳液,研究了合成工艺、—N CO和—O H的比例、丙烯酸酯含量等因素对乳液稳定性和其他性能的影响。     

Synthesis and characterization of poly(butyl acrylate)/silica and poly(butyl acrylate)/silica/poly(methyl methacrylate) composite particles

Poly(butyl acrylate)/poly(methyl methacrylate) (PBA/PMMA) core–shell particles embedded with nanometer‐sized silica particles were prepared by emulsion polymerization of butyl acrylate (BA) in the presence of silica particles preabsorbed with 2,2′‐azobis(2‐amidinopropane)dihydrochloride (AIBA) initiator and subsequent MMA emulsion polymerization in the presence of PBA/silica composite particles. The morphologies of the resulting PBA/silica and PBA/silica/PMMA composite particles were characterized, which showed that AIBA could be absorbed effectively onto silica particles when the pH of the dispersion medium was greater than the isoelectric potential point of silica. The critical amount of AIBA added to have stable dispersion of silica particles increased as the pH of the dispersion medium increased. PBA/silica composite particles prepared by in situ emulsion polymerization using silica preabsorbed with AIBA showed higher silica absorption efficiency than did the PBA/silica composite particles prepared by direct mixing of PBA latex and silica dispersion or by emulsion polymerization in which AIBA was added after the mixing of BA and silica. The PBA/silica composite particles exhibited a raspberrylike morphology, with silica particles “adhered” to the surfaces of the PBA particles, whereas the PBA/silica/PMMA composite latex particles exhibited a sandwich morphology, with silica particles mainly at the interface between the PBA core and the PMMA shell. Subsequently, the PBA/silica/PMMA composite latex obtained had a narrow particle size distribution and good dispersion stability. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 99: 3425–3432, 2006     

Morphological characterization of the core–shell latex particle by transmission electron microscopy and image analysis

To describe the morphology of the core–shell latex particle of methyl methacrylate–butadiene–styrene graft copolymer (MBS) quantitatively, we propose four parameters, that is, the diameter of the core, the shell thickness (TH), the roundness of the core, and the eccentricity (E); we calculated these parameters with geometrical parameters determined by the analysis of transmission electron microscope images. The mean values and distributions of the four parameters based on a certain amount of particles were used for quantitative characterization of MBS latex samples. With increasing monomer‐to‐polymer ratios of the graft polymerization, both the MBS TH and the numbers of homopolymer particles increased, and the core–shell morphology tended to be irregular. For the MBS latices derived from poly(styrene–butadiene) latex with a wide distribution of particle sizes, the core–shell structures of the larger particles were different from those of smaller ones to a certain extent, and both the TH and the E decreased with increasing core size. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 855–861, 2003     

Preparation and properties of microcapsule with EVA core‐PU shell structure

Microcapsule with poly(ethylene‐co‐vinylacetate) (EVA) core‐polyurethane (PU) shell structure was synthesized by interfacial polymerization in aqueous polyol dispersion with ethylene diamine as the chain extender of toluene diisocyanate in poly(vinyl alcohol) aqueous solution as the stabilizing agent. The effects of polyol constituent on the average particle size and distributions, morphologies, color strength, and friction fastness of core‐shell particles were investigated to design microcapsule. The friction fastness of printed fabrics with EVA core‐PU shell microcapsules became the increase to 4–5 grades. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 893–902, 2007     

Effects of cashew nut shell liquid as a plasticizer on cure characteristics,processability, and mechanical properties of 50 : 50 NR/EPDM blends: A comparison with paraffin oil

50 : 50 natural rubber (NR) and ethylene–propylene–diene monomer rubber (EPDM) blends were prepared with different contents of cashew nut shell liquid (CNSL), a natural product obtained from the shells of the cashew nut, as a plasticizer. For comparison, a commercial paraffin oil plasticizer was also used. The effect of plasticizer content on the cure characteristics, processability, and mechanical properties such as tensile strength, elongation at break, and Young's modulus before and after ageing was investigated. Scanning electron microscopy (SEM) was used to observe the blend morphology. The results indicated that the CNSL plasticizer resulted in lower Mooney viscosity and lower cure time of the 50 : 50 NR/EPDM blends. The incorporation of CNSL into 50 : 50 NR/EPDM blends improved tensile strength and elongation at break but decreased Young's modulus. On addition of CNSL the resistance of the blends to heat and weathering ageing improved. Scanning electron micrographs revealed that the morphology of the blend plasticized with CNSL is finer and more homogeneous compared with the blend plasticized with paraffin oil. Overall results indicate that CNSL can be used as a cheaper plasticizer to replace paraffin oil in NR/EPDM blends with improved processability and mechanical properties. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

大跨双曲混凝土组合扭壳屋盖施工拆模优化分析

由于混凝土抗拉能力较差,双曲组合扭壳抵抗悬垂线方向的主拉应力控制至关重要.如果拆模顺序不当,可能会使壳体结构产生过大的拉应力.为解决此问题,以华工扭壳为例,对平行四边形底面双曲组合扭壳的满堂脚手架施工拆模顺序进行全面优化分析,并与工程实测进行对比,得出较为合理的拆模方式.     

新型半刚性网壳锚喷支护技术在软岩巷道中的适用性研究

通过对钢筋网壳锚喷支护的技术特色、结构特点、支护原理的研究,分析了半刚性网壳支护结构对软岩支护的适应性。并完成了室内整架载荷试验。结合在桃园矿的应用情况,阐述了其支护参数选择和施工工艺,并对其进行现场监测,分析了这种新型支护形式的支护性能。实践证明,空间网壳锚喷支护结构与围岩相互作用的整体性好,具有良好的力学性能与较高的承载能力,是软岩巷道中的一种既经济又安全可靠的支护结构形式。     

Characteristics of shell thickness in a slab continuous casting mold

The key to reduce shell breakout in the continuous casting process is to control shell thickness in the mold.A numerical simulation on the turbulent flow and heat transfer coupled with solidification in the slab mold using the volume of fluid (VOF) model and the enthalpy-porosity scheme was conducted and the emphasis was put upon the flow effect on the shell thickness profiles in longitudinal and transverse directions.The results show that the jet acts a stronger impingement on the shell of narrow face,which causes a zero-increase of shell thickness in a certain range near the impingement point.The thinnest shell on the slab cross-section locates primarily in the center of the narrow face,and secondly near the comer of the wide face.Nozzle optimization can obviously increase the shell thickness and make it more uniform.     

钢拱壳穹顶结构在集中荷载作用下随厚度变化应力趋势预测

目的 研究钢拱壳结构在向心集中力作用下的力学行为.方法 引入弹性无矩球壳理论,以及对其实现假设条件的介绍,提出当结构无法满足无矩理论时的特例情况(在有集中力出现)时,分析半球壳结构,在同级荷载作用下,壳体厚度等因素变化对结构内部最大Mises应力的影响程度,并做出对其发展趋势的预测分析.结果 随着壳体厚度的增加,球壳结构在同级荷载作用下,最大Mises应力随之减小;球壳结构曲率半径的变化,也会对结构承载力有相当的影响.结论 钢拱壳结构的厚度及曲率半径的变化对结构承载力和随之而产生的位移都有较大的影响.通过曲线拟合后可以较为准确预测出结构承载力的发展趋势,为钢拱壳穹顶结构设计者提供设计参考依据.     

索穹顶与单层网壳组合结构的模型试验研究

研究索穹顶与单层网壳组合的新型空间结构的受力性能.设计肋环型索穹顶与肋环双斜杆型单层网壳组合的结构,对其进行下部索穹顶预应力张拉试验以及结构在全跨和半跨荷载下的静力性能试验.根据试验结果对试验的计算模型进行修正,并将结构在全跨和半跨荷载下的试验实测数据与理论分析结果进行比较.结果表明,实测数据与理论分析之间差异较小,模型设计和试验方法合理,理论分析方法正确.修正的计算模型能准确反映结构的力学性能.