Oxidation and reforming reactions of CH4 on a stepped Pt(5 5 7) single crystal

The oxidation and reforming kinetics of methane by O₂, CO₂ and H₂O were studied on a stepped Pt(5 5 7) single crystal from 623 to 1050 K under methane rich conditions. The rate of carbon deposition was followed by ex-situ Auger electron spectroscopy under non-oxidative conditions. The apparent activation energy for methane decomposition was significantly lower than the apparent barriers measured for both total oxidation, CO₂ and H₂O reforming. Total oxidation of methane to CO₂ and H₂O followed by combined dry and steam reforming (combined combustion-reforming) led to CO production rates which were higher than direct CO₂ or H₂O reforming rates. The enhanced rates are most likely due to the ability of adsorbed oxygen to prevent carbon nucleation and/or scavenge carbon enabling the reforming reaction to turnover on a larger fraction of sites. Comparable amounts of carbon were found by Auger electron spectroscopy measurements after both direct dry or steam reforming, while combined oxidation-reforming had considerable less carbon. During direct dry or steam reforming, CO₂ and H₂O serve only to scavenge adsorbed atomic carbon, while in the presence of oxygen, carbon is removed by both combustion and reforming routes.     

高收率合成DADE的新方法

在比较DADE的3条文献合成路线基础上，研究了以2-甲基-4，6-嘧啶二酮为母体用硝硫混酸硝化生成中间体2-(二硝基亚甲基)-5，5-二硝基-2H-嘧啶-4，6-二酮、中间体水解合成DADE的方法。DADE总收率达到83％以上，用IR、MS、NMR及元素分析鉴定了其结构。     

Effects of apitong (Dipterocarpus spp.) extractives on bond strength development and curing rate of adhesives

Emulsion polymer isocyanate ( ), polyvinyl acetate ( ) and resorcinol-formaldehyde ( ) adhesives were used to produce single lap shear specimens using resinous and non-resinous apitong (Dipterocarpus spp.) timbers. Tests showed that joints made with highly resinous apitong were about 40% weaker than similar joints made with non-resinous apitong. The resinous apitong was treated with different solvents to yield five different extractives which were characterized by infra-red analysis. Apitong extractives were then added to and adhesives and joints made with buna (Fagus crenata), a timber known to be low in extractives and easy to bond. Joints prepared using extractive-containing adhesives were generally weaker than those made with the unmodified adhesives. RF adhesives containing extractives cured more slowly than unmodified . It is thought that the acidic nature of the extractives changes the pH of the system sufficiently to affect the curing mechanism     

计算机仿真在高频电子线路教学中的应用

针对传统高频电子线路教学中存在的问题,提出在教学中引入计算仿真进行辅助分析与设计．阐述了Multisim的主要功能与特点,并利用Multisim对高频电路中的典型电路单调谐回路谐振放大器、环形调幅器进行了仿真,各项结果与理论推导相符．形象、生动的演示达到提高学生学习兴趣的效果．     

基于统计的中文机构名实体识别的研究

针对中文机构名实体的识别提出了利用隐马尔科夫统计模型的方法.同时,在此方法的基础上通过构建一元模型来补充识别那些缩写的和没有核心词的机构名,弥补了单一统计模型在机构名实体识别中的不足.实验证明二者相结合的方法能获得较高的准确率和召回率,具有可行性.     

660MW超临界机组循环水系统运行优化分析

结合沧东公司循环水系统的运行条件,以及优化循环水系统的运行方式,提出了低负荷单机单泵运行方式.同时根据相关计算和试验,对该类型机组采用单泵运行的可行性、安全性、经济性进行了分析,结果表明,660 MW同类型机组低负荷时采用单台循环水泵运行完全能满足机组正常运行的需要.     

Effective prediction of DEA model by neural network

In this paper,a fast neural network model for the forecasting of effective points by DEA model is proposed,which is based on the SPDS training algorithm.The SPDS training algorithm overcomes the drawbacks of slow convergent speed and partially minimum result for BP algorithm.Its training speed is much faster and its forecasting precision is much better than those of BP algorithm.By numeric examples,it is showed that adopting the neural network model in the forecasting of effective points by DEA model is valid.     

螺纹桩在软弱地层中的应用

分析了螺纹桩的受力机理,探讨了螺纹桩单桩承载力的确定方法,指出螺纹桩单桩承载力高、节约材料显著、能充分利用地基土的特性,在软弱地层中的应用优势显著,并通过实际工程实例给予具体说明.     

斜跨拱桥的力学特性及工程实践

斜跨拱桥外形独特、新颖,是颇有竞争力的城市景观桥型。该类桥型拱肋斜跨主梁。本文针对该桥型的结构形式和受力特点,就其概念设计、细部构造等关键性技术问题展开讨论。最后以大连市红星海世界观景观桥为例对该桥型各部分结构的力学性能进行了分析,旨在使斜跨拱桥体系的设计得到进一步的优化。     

用于队列管理的模糊增益神经元自适应控制器

针对具有参数时变及非线性特性的网络拥塞控制系统,提出了一种模糊增益神经元主动队列管理算法(FNAQM). 采用路由器队列长度及数据流速作为拥塞度量,在检测当前拥塞信息的同时,预测未来拥塞的状况. 结合神经元控制和模糊控制的优点,利用单神经元计算数据包标记概率,采用有监督的Hebb学习规则在线调整加权系数. 设计的模糊控制器可动态调整神经元增益,能获得更好的控制性能. FNAQM具有结构简单、易于实现、自适应能力强等优点. 仿真实验结果表明,FNAQM能快速将队列调整至目标值,并维持较小的队列抖动,对动态数据流和非响应流具有良好的鲁棒性.