Synthesis and physicochemical characterization of amphiphilic block copolymer self‐aggregates formed by poly(ethylene glycol)‐block‐poly(ϵ‐caprolactone)

Diblock copolymers with different poly(ε‐caprolactone) (PCL) block lengths were synthesized by ring‐opening polymerization of ε‐caprolactone in the presence of monomethoxy poly(ethylene glycol) (mPEG‐OH, MW 2000) as initiator. The self‐aggregation behaviors and microscopic characteristics of the diblock copolymer self‐aggregates, prepared by the diafiltration method, were investigated by using ¹H NMR, dynamic light scattering (DLS), and fluorescence spectroscopy. The PEG–PCL block copolymers formed the self‐aggregate in an aqueous environment by intra‐ and/or intermolecular association between hydrophobic PCL chains. The critical aggregation concentrations of the block copolymer self‐aggregate became lower with increasing hydrophobic PCL block length. On the other hand, reverse trends of mean hydrodynamic diameters were measured by DLS owing to the increasing bulkiness of the hydrophobic chains and hydrophobic interaction between the PCL microdomains. The partition equilibrium constants (K_v) of pyrene, measured by fluorescence spectroscopy, revealed that the inner core hydrophobicity of the nanoparticles increased with increasing PCL chain length. The aggregation number of PCL chain per one hydrophobic microdomain, investigated by the fluorescence quenching method using cetylpyridinium chloride as a quencher, revealed that 4–20 block copolymer chains were needed to form a hydrophobic microdomain, depending on PCL block length. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 99: 3520–3527, 2006     

Effects of fullerenes and single-wall carbon nanotubes on murine and human macrophages

The discovery in 1985 of C-fullerenes, a novel carbon allotrope with a polygonal structure made up solely by 60 carbon atoms, and in 1991 of C-nanotubes, thin carbon filaments (1-3 μm in length and 0.001 μm in diameter) with extraordinary mechanical properties, opened a wide field of activity in carbon research. While toxicity and biocompatibility of C-fullerenes have been widely investigated, literature data concerning the biological properties and biotoxicity of C-nanotubes are poor and contradictory. Here we test the ability of highly purified C-Single-Walled-Nanotubes (SWNTs) and C-fullerenes to elicit an inflammatory response by murine and human macrophage cells in vitro. In order to determine the potential of these C-derivatives as biological inducers of inflammatory reactions we evaluate the ability of C-single-walled nanotubes and C-fullerenes to induce the release of NO by murine macrophages cells, to stimulate the phagocytic activity of human macrophage cells and to be cytotoxic against these cells. We show that SWNTs-C-nanotubes, when highly purified, as well as C-fullerenes, do not stimulate the release of NO by murine macrophage cells in culture, their uptake by human macrophage cells is very low, and they possess a very low toxicity against human macrophage cells.     

Encapsulation of titanium dioxide in styrene/n‐butyl acrylate copolymer by miniemulsion polymerization

Miniemulsion copolymerization of styrene/n‐butyl acrylate was investigated as a means of encapsulating hydrophilic titanium dioxide (TiO₂) in a film‐forming polymer. Dispersion studies of the TiO₂ were first carried out to determine the choice of stabilizer, its concentration, and the dispersion process conditions for obtaining stable TiO₂ particles with minimum particle size. Through screening studies of various functional stabilizers and shelf‐life stability studies at both room and polymerization temperatures, Solsperse 32,000 was selected to give relatively small and stable TiO₂ particles at 1 wt % stabilizer and with 20–25 min sonification. The subsequent encapsulation of the dispersed TiO₂ particles in styrene/n‐butyl acrylate copolymer (St/BA) via miniemulsion polymerization was carried out and compared with a control study using styrene monomer alone. The lattices resulting from the miniemulsion encapsulation polymerizations were characterized in terms of the encapsulation efficiencies (via density gradient column separations; DGC) and particle size (via dynamic light scattering). Encapsulation efficiencies revealed that complete encapsulation of all of the TiO₂ by all of the polymer was not achieved. The maximum encapsulation efficiencies were 79.1% TiO₂ inside 61.7% polystyrene and 63.6% TiO₂ inside 38.5% St/BA copolymer. As the density of the particles collected from the DGC increased from one layer to another, both the average particle size and the number of the TiO₂ particles contained in each latex particle increased. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 3479–3486, 2006     

超分散稳定纳米ZnS的非水原位构筑及摩擦学性能

设计并合成了油溶性环烷酸锌和异氰酸酯类超分散稳定剂,采用原位构筑方法获得了非水纳米ZnS分散系,用冷冻蚀刻电镜对其进行了表征,用离心实验对其分散稳定性进行了考察.对纳米粒子的形成过程、分散稳定机理进行了阐述.用环块和四球摩擦试验机对纳米ZnS分散系的摩擦学性能进行了研究.结果表明:ZnS为40 nm的粒状颗粒,大小均匀,在介质中呈单粒子分散;纳米分散系经72 h普通离心和56 h非连续超离心均未发生沉降,表现出理想的分散稳定性;试验显示超分散稳定纳米ZnS的存在,能明显改善油样的抗磨减摩性能和承载能力.在试验范围内,添加的纳米ZnS的量越大,其抗磨减摩性能也越好,但当n-ZnS的质量分数大于0.25%时,其承载能力趋于稳定.     

硅基上金粒子诱导的聚氧硅烷纳米线的合成

采用液相法以硅基上原位合成的金纳米粒子作为催化剂和模板,在不同的反应条件下,用十八烷基硅烷（Octadecylsilane）作为前驱体合成了纳米线状化合物．研究了不同反应条件对该线状化合物形貌的影响,能量散射光谱实验结果表明该线状化合物为聚氧硅烷,扫描电镜结果显示当反应温度控制在110℃和反应时间90min的条件下,可得到均匀的纳米线状化合物．最后提出了聚氧硅烷化合物可能的形成机理,同时也为制备硅基上的硅氧纳米线状化合物提供了一种方便而简单的方法．     

二硫化钼纳米颗粒的制备与润滑性能研究

利用超声化学方法制备的类球形三氧化钼（MoO3）纳米颗粒为前驱物,采用在氧气氛下的硫化还原反应制备纳米二硫化钼（MoS2）粉体。纳米粉体颗粒的形貌、几何特征和尺寸等通过场发射扫描电子显微镜（FE-SEM）和透射电子显微镜（TEM）进行表征,用x-ray射线衍射（XRD）和能谱分析（EDX）分析物质的结构及成分。将制备出的类球形纳米级MoS2作为添加剂,添加到基础油中。通过仪器测试其在不同载荷下的摩擦系数,与基础油的摩擦系数进行对比,研究纳米MoN对复合润滑油润滑性能的影响。结果表明：MoS2纳米颗粒能够显著提高润滑油的润滑性能。     

对苯二酚在金、银纳米粒子修饰的玻碳电极上电化学响应的比较

制备了柠檬酸钠保护的金和银纳米粒子,并用自组装法制备了金和银纳米粒子修饰的玻碳电极,在近中性的磷酸缓冲溶液中,比较研究对苯二酚在金和银纳米粒子修饰玻碳电极上的电化学响应情况。结果表明金和银纳米粒子均对对苯二酚的电氧化过程具有优越的电催化效果;与银纳米粒子修饰电极相比,金纳米粒子修饰电极表现出了良好的稳定性;对苯二酚在金纳米粒子修饰玻碳电极上的电化学反应是受扩散控制的。     

硅基底上制备纳米镍粒子

采用微波加热法在单晶硅基底上制备纳米镍粒子。考察了镍源、还原剂、表面活性剂、加热方式等实验条件对单晶硅基底上制备纳米镍粒子的影响。对硅基底上纳米镍粒子的成分、结构及表面形态进行了表征。结果表明:以水合肼为还原剂、氯化镍为镍源,微波加热3 min在硅基底上可以制备出直径为30 nm的均匀单一分布的纳米镍粒子。     

梳棉机前棉网清洁器风量的确定

研究了梳棉机前罩板处棉网清洁器风量大小对生条质量影响的问题,用premier aQura棉结和短纤维测试仪对前棉网清洁器采用三档风量(单双侧吸风形式)时所加工的生条质量进行了检测,经过对检测结果分析得出(1)与后罩板处棉网清洁器风量相比较,前棉网清洁器的风量要相对小些选择对生条质量的提高较为有利;(2)无论是单侧还是双...     

W/O型反相微乳法制备纳米材料及其应用

简要介绍了反相微乳液的结构、性质、相行为及微观结构的检测方法；阐述了在W／O型反相微乳液中制备纳米材料的反应原理、制备方法及影响纳米微粒成核、增长的因素；综述了近年来国内外使用该方法制备纳米材料的研究进展。