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151.
对直接法生产两钠(硝酸钠和业硝酸钠)的工艺过程作了简介,分析了原设计中尾气分离装置存在的缺陷,对尾气分离装髓进行了改造并取得了良好的效果。 相似文献
152.
介绍了一种新的氨化-还原试剂———二烷基胺硼氢化锂,讨论了它在卤代苯腈中的应用,其结果为o 卤代苄腈在与通用的新氨化-还原试剂反应得到相应的氨基苄胺。 相似文献
153.
介绍了FP—640火焰光度计采用低、高标法钠含量的测定。与标准曲线法钠含量测定相比较,该法具有方便、快速、准确度高的特点。 相似文献
154.
M. D. Kurkuri J. N. Nayak M. I. Aralaguppi B. V. K. Naidu T. M. Aminabhavi 《应用聚合物科学杂志》2005,98(1):178-188
Blend membranes of poly(vinyl alcohol) (PVA) and sodium alginate (NaAlg) were prepared by solution casting and crosslinked with glutaraldehyde (GA). Polymer blend compatibility was studied in water by measuring solution viscosity at 30°C. From the viscosity data, interaction parameters were determined to find the blend compatibility. Thickness of the membranes ranged between 35 and 40 μm. Circular disc‐shaped samples were cut from the thin membranes to perform gravimetric sorption experiments in water + 1,4‐dioxane and water + tetrahydrofuran mixtures at 30°C. Diffusion coefficients were calculated using Fick's equation. Concentration profiles of liquids were computed by solving Fick's equation under suitable boundary conditions. Diffusion coefficients show a dependence on the composition of the blends as well as composition of binary mixtures. A correlation was attempted between concentration profiles and diffusion coefficients of the transporting liquids. Degree of swelling and sorption coefficients were calculated from the gravimetric sorption data. Sorption kinetics was studied using an empirical equation to understand the nature of sorption–diffusion anomalies. Membrane selectivity for water + 1,4‐dioxane and water + tetrahydrofuran mixtures were calculated from the pervaporation experiments. A correlation between sorption and membrane selectivity was attempted. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 178–188, 2005 相似文献
155.
The micellar properties of aqueous binary mixed solutions for two systems consisting of sodium cholate (NaC)-octaoxyethylene
glycol mono n-decyl ether (C10E8) and sodium glycocholate (NaGC)-C10E8 have been studied on the basis of surface tensions, polarity of the micelle interior and the mean aggregation number. Application
of two theoretical treatments, based on regular solution and excess thermodynamic quantities for critical micellar concentration
(CMC) data from surface tension curves of two mixed systems showed that the mole fraction of each bile salt in the mixed micelles
near the CMC is lower than that of the corresponding prepared mole fraction in the mixed solution. The polarity of the interior
suggested that the hydrophobicity of intramicelles increased with the increase of the mole fraction of bile salt in the mixed
solution and that the mixed micelles become dramatically more hydrophobic at a mole fraction of 0.68 for NaGC−C10E8 system and 0.75 for NaC−C10E8 system, respectively. This implies that the micelles become richer in the bile salt molecules and the tendency appears strongly
for NaGC−C10E8 system due to the strong cohesion between the conjugated glycines in the NaGC molecules. The decrease of aggregation number
with the increase of the mole fraction of bile salts shows that the micelles approach those of the single system of each bile
salt. This supports the previously mentioned facts. 相似文献
156.
157.
Anandrao R. Kulkarni Kumaresh S. Soppimath Tejraj M. Aminabhavi Ashok M. Dave 《应用聚合物科学杂志》2002,85(5):911-918
Novel polymeric sodium alginate (Na‐Alg) interpenetrating network (IPN) beads have been prepared by crosslinking Na‐Alg blend with gelatin (GE) or egg albumin (EA) using glutaraldehyde (GA) as the crosslinking agent. These beads were used for the controlled release of chlorpyrifos. The swelling experiments were performed in water at different temperatures, and these data were used to calculate the molecular mass (MC) between crosslinks as well as diffusion coefficients. Diffusion coefficients calculated from desorption data were lower by about two orders of magnitude than those calculated from sorption results. Higher values of MC were obtained for the gelatin‐based IPNs than the neat Na‐Alg and egg albumin‐based matrices. Size of the beads did not vary significantly either by the network or by increasing the exposure time to the crosslinking agent. The scanning electron microscopy (SEM) was used to understand the surface characteristics of the beads. Differential scanning calorimetry (DSC) indicated a molecular level dispersion of chlorpyrifos in the polymer matrix. The percentage entrapment efficiency showed a dependence on the type of network polymer as well as time of exposure to the crosslinking agent. The encapsulation efficiency decreased with an increase in time of exposure to the crosslinking agent. In vitro release experiments have been performed to follow the release kinetics of chlorpyrifos from the matrices. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 911–918, 2002 相似文献
158.
以壳聚糖和木质素磺酸钠为囊材,以三氟氯氰菊酯为囊芯,采用复凝聚法制备了微胶囊。考察了壳芯质量比、温度、搅拌速度、对包药率的影响,确定最佳工艺条件,并对其性能进行了研究。 相似文献
159.
The wettability, surfactivity and the correlation between wettability and surfactivity of sodium diethylhexylphosphate, sodium
diethylhexyl polyoxyethylene phosphate and their complex in NaOH solutions were studied. A complex alkali resistant phosphate
surfactant with good permeability was prepared. The wettability of surfactants was investigated by measuring the immersion
time, sinking time and capillary effects of nature cotton grey fabric in NaOH solutions. The surfactivity of the surfactants
was characterized by measuring the surface tension. The effect of the complex on the surface appearance of cotton grey fabric
was also investigated with a scanning electron microscope (SEM). The results show that all the surfactants exhibit good wettability
for cotton grey fabric in 0.5–5.0 mol/L of NaOH solutions, the complex system exhibits better wettability in 5.0–7.0 mol/L
of NaOH solutions, in comparison with either corresponding single surfactant component employed, and wettability is well correlative
with the surfactivities of the surfactant. SEM images indicate that the cotton grey fabric is well wetted by the alkaline
surfactant solution and the quality of fabric is improved. 相似文献
160.
A new additive of sodium hexametaphosphate (SHMP) was introduced to the paste of zinc electrode, with the purpose of preventing
the zinc active materials from agglomerating and improving the stability of batteries. The properties of the zinc electrodes
were characterized by scanning electron microscopy (SEM), constant current charge/discharge measurement, self-discharge test
and hydrogen collection experiment. The photographs of zinc electrode show that SHMP can significantly break up the agglomeration,
uniformize the particle distribution and increase the surface area, which are advantageous to improve the electrochemical
performance of zinc electrode. The experimental battery shows a 97 times cycling life and a 30.2% remaining capacity after
4 d storage. The hydrogen collection experimental results indicate that the SHMP can decrease the ratio of hydrogen evolution.
Therefore, the corrosion of zinc electrode is suppressed and the charge/discharge efficiency is enhanced. 相似文献