氯醇法环氧丙烷产品除醛方法的研究探讨

工业用环氧丙烷GB/T 14491-2015颁布实施后,下游聚醚客户对环氧丙烷质量要求更高。通过优化氯醇法环氧丙烷工艺降低环氧丙烷产品总醛质量分数,满足客户需求。     

海藻酸钠与纳米晶纤维素共混膜制备与性能研究

借助冷冻干燥技术制备了海藻酸钠与纳米晶纤维素共混膜以达到增强目的;探讨了不同含量的纳米晶纤维素与海藻酸钠共混膜的微观形貌、力学性能、吸水性能及孔隙率的变化;综合评价确定最佳的纳米晶纤维素含量在0.75%至1.00%之间。     

石英与长石在酸性介质中的浮选分离研究

以十二烷基磺酸钠(SDS)和N-十二烷基-1,3-丙二胺(DN12)作为混合捕收剂,采用单矿浮选实验分离石英与长石,探究DN12和SDS对长石和石英浮选回收率的影响及其浮选分离的机理。结果表明,在p H为2.0,DN12浓度为4.739×10-4mol/L,SDS浓度为2.38×10-4mol/L时,长石和石英回收率的差值最大,达62.3%。紫外光谱的分析得出,SDS和DN12捕收剂在长石表面仅存在物理吸附,在石英表面不仅存在物理吸附,还存在化学吸附,表明该捕收剂对石英具有更强的捕收能力。     

双水相分离纯化R-藻红蛋白

为了获得优于食品级的R-藻红蛋白(R-PE),采用双水相体系从坛紫菜中分离纯化R-PE.结果表明,聚乙二醇(PEG)/酒石酸钾钠双水相体系,当PEG相对分子质量为1 500且p H为8.06、系线长22.30%、体积比0.12时纯化效果最佳,R-PE纯度由细胞破碎液的0.43提高到1.47,回收率为84.42%.经过二次双水相纯度达1.55,纯化因子为3.60.得到的R-PE具有较高的生物活性.PEG相对分子质量1500/酒石酸钾钠双水相体系成功分离纯化R-PE,操作简单,成本低,适于工业化.     

高铁酸钠对生活污水中阴离子合成洗涤剂的去除研究

通过自制的高铁酸钠对生活污水中的阴离子合成洗涤剂进行去除实验研究。采用国标方法亚甲蓝分光光度法进行测定,结果发现:高铁酸钠对生活污水中的阴离子合成洗涤剂有较好的去除作用,每100 m L生活污水中,加入10 m L浓度为1.41 g/L的高铁酸钠,水样中阴离子合成洗涤剂的去除率为69.28%。     

杯[4]芳烃磺酸钠催化合成乙酸正丁酯

以杯[4]芳烃磺酸钠为催化剂,以乙酸与正丁醇为原料,通过酯化反应合成乙酸正丁酯,考察了催化剂用量、原料配比和反应时间对酯化反应的影响,产品进行折光指数检测。结果表明,杯[4]芳烃磺酸钠作为催化剂,乙酸物质的量为0.1mol,醇酸物质的量比为1.2,催化剂质量为1g,反应时间为4h时,酯化率可达81.41%,杯[4]芳烃磺酸钠可以重复使用多次。     

发电厂在线钠表的准确度检验

分析了发电厂在线钠表准确性检验存在的问题,介绍了一种在线钠表准确度检验装置,通过原子吸收分光光度计的对比实验,检测了该装置产生的低浓度标准溶液,并利用该装置分析了ThermoORION公司生产的2111LL型在线微钠表的在线检测准确度.试验结果表明,该装置可以提高在线钠表的可靠性和检验的准确性.     

超细Al（OH）3的粒度控制研究

采用铝酸钠种子分解法制备超细Al（OH）3.用X射线衍射仪（XRD）表征了样品的晶相组成,用扫描电子显微镜（SEM）观察了样品的形貌,用激光粒度分析仪测定样品的粒度分布.研究了NaOH浓度、NaOH/Al（OH）3摩尔比,分解温度,分解时间、晶种率和搅拌速率等因素对Al（OH）3的粒度的影响.结果表明：NaOH浓度越高,分解温度越低,NaOH/Al（OH）3摩尔比越小,得到的Al（OH）3颗粒的粒度越小.试验条件为：NaOH浓度180 g/L,NaOH/Al（OH）3摩尔比1.15,分解温度40℃,分解时间26 h,晶种率8％,搅拌速率200 rpm时,氢氧化铝颗粒的平均粒度为2.89 μm.     

High-efficiency ammonium polyphosphate intumescent encapsulated polypropylene flame retardant

The flame retardant polypropylene containing the micro-envelope core-shell structure flame retardant, which encapsulated ammonium polyphosphate into melamine-formaldehyde resin and sodium silicate through in situ polymerization was prepared with polyamide 6, added as a carbon-forming agent. The composition of ammonium polyphosphate, encapsulated ammonium polyphosphate with melamine-formaldehyde resin and the micro-envelope core-shell structure flame retardant were characterized. The fire safety and thermal stability were investigated and showed an improvement including limiting oxygen index, thermogravimetric analysis, vertical burning tests, and microscale combustion calorimeter. The burned compounds were also studied to confirm the burning mechanism. The results showed the flame retardant performance had been greatly improved, while polyamide 6 had better char-forming effect. Besides, the water solubility of flame retardants and their influence on the mechanical properties of polypropylene were also investigated. The results on the effects of additives demonstrated a high efficiency flame retardant to polypropylene. A core-shell flame retardant that sodium silicate and melamine-formaldehyde resin-coated ammonium polyphosphate had been constructed. The effect of the built flame retardant system on the combustion performance of polypropylene was studied from the mechanism and performance. The LOI of the most flame retardant polypropylene reached 28.6%, and UL-94 reached the V-0 level.     

Supercritical carbon dioxide assisted fabrication of biomimetic sodium alginate/silk fibroin nanofibrous scaffolds

In this study, biomimetic sodium alginate (SA)/silk fibroin (SF) scaffolds were successfully fabricated by supercritical CO₂ technology. The SA/SF scaffolds exhibited an interconnected porous and extracellular matrix (ECM)-like nanofibrous structures. Moreover, the SA microparticles were embedded in the SF scaffolds. Increasing the content of SA microparticles could improve tensile strength and compressive strength of the SF scaffolds and reduce the porosity of the SF scaffolds. The addition of the SA microparticles could also regulate the degradation rate of the SA/SF scaffolds. Furthermore, the results of in vitro biocompatibility evaluation, indicated that the SA/SF scaffolds exhibited no obvious cytotoxicity and higher cell adhesion ability and were more favorable for L929 fibroblasts proliferation than pure SF scaffolds. Therefore, the SA/SF scaffolds with ECM-like nanofibrous and interconnected porous structure have potential application in skin tissue engineering.