硫化镉纳米粒子的制备

探索纳米硫化镉的制备方法,对纳米晶体形成机理、结构性能进行基础研究;分析了影响溶胶团簇性质的因素,包括体系温度、稳定剂比例、pH值和反应物用量.结果显示利用六偏磷酸钠为稳定剂,氯化镉和硫化钠为反应物在水相中反应可以制得稳定的硫化镉纳米溶胶团簇.     

Electron-Impact Cross Sections for Ground State to np Excitations of Sodium and Potassium

Cross sections for electron impact excitation of atoms are important for modeling of low temperature plasmas and gases. While there are many experimental and theoretical results for excitation to the first excited states, little information is available for excitation to higher states. We present here calculations of excitations from the ground state to the np levels of sodium (n = 3 through 11) and potassium (n = 4 through 12). We also present a calculation for a transition from the excited sodium level 3p to 3d to show the generality of the method. Scaling formulas developed earlier by Kim [Phys. Rev. A 64, 032713 (2001)] for plane-wave Born cross sections are used. These formulas have been shown to be remarkably accurate yet simple to use. We have used a core polarization potential in a Dirac-Fock wave function code to calculate target atom wave functions and a matching form of the dipole transition operator to calculate oscillator strengths and Born cross sections. The scaled Born results here for excitation to the first excited levels are in very good agreement with experimental and other theoretical data, and the results for excitation to the next few levels are in satisfactory agreement with the limited data available. The present results for excitation to the higher levels are believed to be the only data available.     

电渗析硫酸钠的试验研究

文章研究了在电渗析硫酸钠过程中,影响电流效率和槽电压的各因素对它们的影响规律,从而找到较好的电渗析条件。     

氟化钠和8-羟基喹啉联合掩蔽氢化物发生原子荧光法直接测定环境水样中的Sb(Ⅲ)和Sb(Ⅴ)

研究了氢化物发生原子荧光光谱法 (HG AFS)直接测定环境水样中Sb(Ⅲ )时Sb(Ⅴ )及其他元素的干扰情况 ,选择了最佳掩蔽剂及测定条件 ,表明采用氟化钠和 8 羟基喹啉联合掩蔽在 3mol·L- 1 的盐酸介质中可有效消除各种干扰 ,而且在测定过程中不会引起形态的改变 ,其检测限为 0 .1ng·ml- 1 ,加标回收率在 92 .2 %～ 1 0 5 .0 %之间。     

十六胺乙基磺酸钠的合成和性能研究

以十六胺和溴乙磺酸钠为原料合成了十六胺乙基磺酸钠,用单因素优选法研究了影响反应的因素,优化反应条件为n（十六胺）：n（溴乙磺酸钠）=1．0：1．3,反应温度80℃,反应时间7．0h,pH值9．0～10．0,产物质量收率89．64％,提纯后纯度93．25％,并对十六胺乙基磺酸钠的应用性能进行了测定．     

Vapor Species over Na2O-B2O3-SiO2-Cs2O Glass

Methods for suppression and control of the axisymmetric vertical positional instability are described on the basis of conceptural design studies with the International Tokamak Reactor (INTOR). The shell effect is well known to be useful for suppression of the fast instability. Here shell structures are presented and their usefulness is assessed. Included in the assessments are required modellings of the plasma current for determination of mutual inductances between the plasma and the inductive components around it. Three kinds of models are described and their features are compared to the shell effect. Two kinds of simplified reactor structures are described and studied by comparing them with some control characteristics of the slow instability by a pair of control coils. Their structures are selected so as to result in different shell effects between them, and are consequently found to produce different capacities of power supply, too.     

液钠沸腾两相流流型与临界热流密度(CHF)机理实验研究

通过大量的液态金属钠临界热流密度 (CHF)的实验研究 ,结合液钠两相传热流动特性及液钠的物性特点 ,分析了起始沸腾流型 ,泡状流 ,块状流 ,环状流和双向环状流的热工水力特性 ;并从实验结果出发 ,深入分析了液钠发生临界热流密度时的气泡爆炸和液膜撕裂或局部蒸干的两种传热恶化机理     

低COD处理沉钒废水回收低铁含铬渣冶炼金属铬

用焦亚硫酸钠、海波上层液分别处理沉钒废水,研究表明:海波上层液还原沉钒废水COD高达2 878 mg/L,远超排放标准;用焦亚硫酸钠还原沉钒废水,中和、沉淀能够获取低COD废水、低铁含铬渣。用焦亚硫酸钠处理沉钒废水工业运行技术条件:焦亚硫酸钠加入倍数3.1~3.2,还原反应时间15~30 min。处理后废水经汽提脱氨塔脱氨后,排向污水处理厂的废水未检出六价铬,COD平均值65 mg/L,符合辽宁省地方排放标准《污水综合排放标准》DB21/1627—2008排放限值,所得含铬渣中铁含量较低(以Fe2O3计0.27%),铬含量高(以Cr2O3计41.6%)。含铬渣经煅烧窑煅烧、炉外法冶炼出牌号JCr95金属铬(Cr≥95%)产品,质量合格。     

Corrosion Resistance of Sintered NdFeB Permanent Magnet With Ni-P/Tio22 Composite Film

The Ni-P/TiO₂ composite film on sintered NdFeB permanent magnet was investigated by X-ray diffraction (XRD), environmental scanning electron microscopy (ESEM), and energy dispersive X-ray spectrometer (EDX). The corrosion resistance of Ni-P/TiO₂ film coated on NdFeB magnet, in 0.5 mol/L NaCl solution, was studied by potentiodynamic polarization, salt spray test and electrochemical impedance spectroscopy (EIS) techniques. The self-corrosion current density (i_corr) and the polarization resistance (R_p) of Ni-P/TiO₂ film are 0. 22 μA/cm² (about 14% of that of Ni-P coating), and 120 kΩ • cm² (about 2 times of that of Ni-P coating), respectively. The anti-salt spray time of Ni-P/TiO₂ film is about 2.5 times of that of the Ni-P coating. The results indicate that Ni-P/Ti0₂ film has a better corrosion resistance than Ni-P coating, and the composite film increases the corrosion resistance of NdFeB magnet markedly.     

高效过滤器钠焰效率试验中NaCl浓度对测量精度的影响

在核级高效过滤器钠焰效率试验中,使用自制的稀释装置和研制的钠焰光度计,试验测量了NaCl浓度在4 ng/m³～13 mg/m³范围内,气溶胶燃烧光强与浓度之间的关系,然后用最小二乘法对测量值进行曲线拟合。研究结果表明：低浓度区,光电流与NaCl浓度间为线性关系,光谱的自吸收系数为1;中、高浓度区,光电流与NaCl浓度间不再符合线性关系,光谱的自吸收系数随浓度的增加而减小。研究结果要求：在高效过滤器效率测量时,如果使用国标的效率计算公式,须保证NaCl的原始浓度低于0.05 mg/m³;如果原始浓度高于0.05 mg/m³,则需使用实际标定的光电流与NaCl浓度间的关系曲线来代替国标的效率计算公式。