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91.
92.
探讨了用X射线荧光光谱分析法(XRF法)测定聚乙烯中所含的微量金属Fe、Ti、Al的方法,简 分析条件及实验方法。 相似文献
93.
This paper reports the development of a method for simultaneously measuring zeolite, silicate, and phosphate in laundry detergent
products by inductively coupled plasma atomic emission spectrometry. A sample is decomposed under alkaline oxidative conditions
to decompose zeolite, silicate, phosphate, and organic substances. Then hydrochloric acid is added to the decomposed solution
to dissolve aluminum hydroxide precipitate before analysis. This sample preparation procedure was investigated by using a
total organic carbon analyzer and was confirmed to be applicable to simultaneous measurements of zeolite, silicate, and phosphate.
Relative standard deviation for the analysis is less than 2.1%, recovery is more than 99.0%, and the calibration curve gives
a correlation coefficient ofR=1.000. The detection limit of this method for aluminum and silicon is 0.1%, and for phosphorus, 0.2% by weight in the product.
This method is applicable to various laundry detergent products that contain zeolite, silicate, or phosphate and is five times
faster than the three wet chemical methods. 相似文献
94.
A few Ca-containing mono-metallofullerenes, i.e. Ca@C76, Ca@C88, Ca@C90 (I, II), were synthesized by an improved DC arc discharge method and isolated by a multi-stage HPLC method for the first time. These isomer-separated metallofullerenes were characterized by LD-TOF MS and UV-vis-NIR spectrometry. Their HOMO-LUMO band gaps and possible molecular geometries are discussed according to the absorption spectra in this report. In addition, the cyclic and differential pulse voltammetry of Ca@C76 was conducted in MeCN/C6H5CH3 (1:4 v/v). The voltammograms of Ca@C82 (II, III) and Ca@C84 (II) were also recorded. Their electrochemical behaviors are discussed compared with those of corresponding ytterbium metallofullerenes. The features of the Ca metallofullerenes’ electronic structures are also discussed. 相似文献
95.
96.
Craig A. Dorschel 《Journal of the American Oil Chemists' Society》2002,79(8):749-753
A study of processed peanut oil was undertaken to assess the utility of HPLC combined with tandem MS to obtain data easily
regarding the number of TAG of fats and oils and their FA composition. Mass chromatograms and spectra corresponding to only
TAG of a single M.W. were obtained for the full range of TAG in the sample. Analysis of the mass spectra allowed the identification
of more than 160 TAG in the sample by their FA composition. In addition, it was possible to estimate relative abundances of
the TAG and suggest the position of the FA on glycerol for a limited number of cases. This technique greatly simplifies the
task of assigning FA to coeluting TAG and facilitates identification of TAG present in trace quantities in mixtures, with
possible application in circumstances where such trace TAG could be significant markers. Results are quickly obtained without
extensive sample preparation or prefractionation of the sample. 相似文献
97.
In view of the importance for CoxOy,-MoO3/-Al2O3 hydrodesulphurization (HDS) catalysts, the reactivity of cobalt oxide layers towards cobalt aluminate formation was investigated on both MoO3-covered and bare -Al2O3 substrates. Co3O4/MoO3/-Al2O3 and Co3O4/-Al2O3 systems were prepared by vapour-deposition of MoO3 (12 × 1015 Mo atoms/cm2) and Co (400 × 1015 Co atoms/cm2) layers onto a -Al2O3 substrate, followed by oxidation of the Co layer to Co3O4. After annealing at 800°C for 40 h, the interfacial reaction to cobalt aluminate was assessed using Rutherford backscattering spectrometry. The presence of molybdenum oxide appeared to enhance cobalt aluminate formation. The Mo atoms, which spread out over the entire cobalt-containing layer, presumably caused a high defect density, which explains the observed higher reaction rate. The amount of MoO3 was much too low to stabilize all cobalt atoms by cobalt molybdate formation. 相似文献
98.
V. Spitzer S. A. de L. Bordignon E. P. Schenkel F. Marx 《Journal of the American Oil Chemists' Society》1994,71(12):1343-1348
In addition to some usual fatty acids, the seed oil ofJodina rhombifolia (Santalaceae) contains nine acetylenic fatty acids [9-octadecynoic acid (stearolic acid) (1.1%),trans-10-heptadecen-8-ynoic acid (pyrulic acid) (20.1%), 7-hydroxy-trans-10-heptadecen-8-ynoic acid (2.3%),trans-10,16-heptadecadien-8-ynoic acid (0.7%), 7-hydroxy-trans-10,16-heptadecadien-8-ynoic acid (0.1%),trans-11-octadecen-9-ynoic acid (ximenynic acid) (20.3%), 8-hydroxy-trans-11-octadecen-9-ynoic acid (12.2%),trans-11,17-octadecadien-9-ynoic acid (1.5%), 8-hydroxy-trans-11,17-octadecadien-9-ynoic acid (1.3%), 9-hydroxystearic acid (<0.1%) and 9,10-epoxystearic acid (0.7%)]. The fatty acids
have been analyzed by gas chromatography/mass spectrometry of their methyl ester and 4,4-dimethyloxazoline derivatives. The
hydroxy fatty acid methyl esters have been examined also as trimethyl-silyl ethers. Furthermore, the fatty acid methyl esters
(FAME) have been fractionated according to their polarity (FAME-A: nonhydroxy; FAME-B: hydroxy fatty acids) and to their degree
of unsaturation (FAME-A1/A2; FAME-B1/B2) by preparative thin-layer chromatography and argentation chromatography, respectively.
All of these fractions have been analyzed by ultraviolet and infrared spectroscopy, and the fractions FAME-A and FAME-B have
been analyzed further by nuclear magnetic resonance (1H,13C, 2D H/C, attached proton test) spectroscopy and gas chromatography/mass spectrometry.
This work is dedicated to the 65th birthday of Prof. Dr. K. Pfeilsticker, Institut of Food Science, University Bonn (Germany). 相似文献
99.
Yoshiyuki Sakamoto Tomoyoshi Motohiro Shinichi Matsunaga Kohei Okumura Tomoyuki Kayama Kiyoshi Yamazaki Toshiyuki Tanaka Yoshimi Kizaki Naoki Takahashi Hirofumi Shinjoh 《Catalysis Today》2007,121(3-4):217-225
The release and reduction of NOx in a NOx storage-reduction (NSR) catalyst were studied with a transient reaction analysis in the millisecond range, which was made possible by the combination of pulsed injection of gases and time resolved time-of-flight mass spectrometry. After an O2 pulse and a subsequent NO pulse were injected into a pellet of the Pt/Ba/Al2O3 catalyst, the time profiles of several gas products, NO, N2, NH3 and H2O, were obtained as a result of the release and reduction of NOx caused by H2 injection. Comparing the time profiles in another analysis, which were obtained using a model catalyst consisting of a flat 5 nmPt/Ba(NO3)2/cordierite plate, the release and reduction of NOx on Pt/Ba/Al2O3 catalyst that stored NOx took the following two steps; in the first step NO molecules were released from Ba and in the second step the released NO was reduced into N2 by H2 pulse injection. When this H2 pulse was injected in a large amount, NO was reduced to NH3 instead of N2.
A only small amount of H2O was detected because of the strong affinity for alumina support. We can analyze the NOx regeneration process to separate two steps of the NOx release and reduction by a detailed analysis of the time profiles using a two-step reaction model. From the result of the analysis, it is found that the rate constant for NOx release increased as temperature increase. 相似文献
100.
以多孔玻璃纤维滤膜基钛酸锶钡(BBST)为吸附材料,制备了手控注射式富集器;考察了该富集器对水中Zn2+的吸附富集性能.结果表明:当介质的pH值为3-7时,多孔玻璃纤维滤膜基钛酸锶钡对水中的Zn2+具有很强吸附能力,其静态吸附容量为24.30 mg/g;制备的富集器可实现对Zn2+的动态吸附,被吸附的Zn2+可用2.0%的EDTA溶液动态洗脱回收,其浓集因子可达500.提出了手控注射式钛酸锶钡富集器富集,火焰原子吸收光谱法测定水中痕量Zn2+的新方法.方法检出限为0.09μg/L.应用于一次蒸馏水和纯净水中痕量Zn2+的富集,用火焰原子吸收法测定,回收率为93.0%-102.0%. 相似文献