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81.
This paper reports off-lattice Monte Carlo simulations of highly-branched comb homopolymers weakly adsorbed on a flat, featureless surface showing only covolume and dispersion interactions with the adsorbate. A minimal coarse-grained model, described by hard spheres connected by harmonic springs, was employed. The interaction energy of the adsorbed combs and linear chains is first discussed as a function of the molecular mass and of the number of beads in contact with the surface. The molecular size is then investigated as a function of backbone length and branching density at a fixed arm size. The apparent swelling exponents of the adsorbed combs are larger than those of the corresponding linear chains, and much larger than that of the free molecules. This result indicates a surface-induced stiffening of the comb backbone, further studied through the persistence length lpers. It is found that lpers increases upon adsorption over the free-molecule value, more so the larger is the branching density. Finally, the thickness of the adsorbed layer, the surface-induced molecular anisotropy and the molecular aspect ratio are investigated as a function of branching density and molecular mass. 相似文献
82.
Haruo Mimura Ryusei Sato Yu Sasaki Yuichi Furuyama Akira Taniike Kazutoshi Yoshida Akira Kitamura 《International journal of molecular sciences》2008,9(10):1989-2002
Tributyltin (TBT) released into seawater from ship hulls is a stable marine pollutant and obviously remains in marine environments. We isolated a TBT resistant marine Pseudoalteromonas sp. TBT1 from sediment of a ship’s ballast water. The isolate (109.3 ± 0.2 colony-forming units mL−1) adsorbed TBT in proportion to the concentrations of TBTCl externally added up to 3 mM, where the number of TBT adsorbed by a single cell was estimated to be 108.2. The value was reduced to about one-fifth when the lysozyme-treated cells were used. The surface of ethanol treated cells became rough, but the capacity of TBT adsorption was the same as that for native cells. These results indicate that the function of the cell surface, rather than that structure, plays an important role to the adsorption of TBT. The adsorption state of TBT seems to be multi-layer when the number of more than 106.8 TBT molecules is adsorbed by a single cell. 相似文献
83.
Pt NaY and Pt In NaY adsorption properties have been compared by using probes like H2, C4H10, 2-C4H8 and microcalorimetry. It appears that the addition of In to Pt does not change the initial heat of H2 chemisorption but decreases the initial heat of butane and butene chemisorption. 相似文献
84.
An improved set of parameters for vanadium in the semiempirical quantum chemical SCF MO method SINDO1 is presented. It is shown that both the geometries and heats of formation of a number of vanadium-containing compounds calculated by this method are in good agreement with available experimental data. Model clusters of increasing size are used for the study of geometric and energetic properties of vanadium pentoxide. Both hydrogen atom and proton adsorption on the (010) surface of vanadium pentoxide and a subsequent formation of different oxygen vacancies have been investigated. Based on these computational results the reactivities of V2O5-surface oxygen atoms for adsorption are discussed. 相似文献
85.
几种吸附式致冷新工质对的性能预测 总被引:3,自引:1,他引:2
应用吸附平衡基本理论对几种可能的吸附式致冷新工质对的性能进行了预测。结果表明,烷烃系列的低混点工质与沸石的配对体系是不可取的,而沸石-氨、活性炭-丙酮、活性炭-氨及活性炭-乙醇则是沸石-水、活性炭-甲醇体系的适宜的替代物。 相似文献
86.
FT-IR spectroscopy has been applied in a study of methanol adsorption on MINaY zeolites (M=Li, K, Rb, Cs). Coordinatively and/or hydrogen bonded methanol was registered in the temperature range 300–473 K. Dehydration of methanol to dimethyl ether occurred at 573 and 623 K. It was found that the activity of the catalyst for methanol dehydration strongly depends on the kind of alkali metal cation, and well correlates the IR data relative to methanol adsorption. 相似文献
87.
Hiromasa Higasa Ryoichi Takahata Hiroshi Imaizumi Kenzo Miya 《Electrical Engineering in Japan》1996,116(3):96-106
A high-temperature superconductor YBa2Cu3O7-x with strong pinning force has allowed stable magnetic suspension with no control to be developed. Two types of superconducting magnetic bearings (SMB) using YBCO and permanent magnet were assembled. The two types are radial and axial. The dynamic stiffness of each SMB as it was cooled down under a magnetic field by liquid nitrogen was measured both radially and axially. As a result, it was found that the spring constants of these SMBs were almost as large as a practically desirable value; however, their damping coefficients were lower than the practical level. These findings are useful as one of the data bases for development of an optimum SMB design to support the weight of rotors in an axial direction. 相似文献
88.
重金属污染物动态吸附试验及数学模拟 总被引:3,自引:0,他引:3
本文采用泥沙动力学中Rouse等人用来研究泥沙浓度沿垂线分布的装置。对泥沙吸附重金属污染物进行了动态模拟。试验分有底泥和无底泥两种情况。研究中发现在Rouse装置的水力、泥沙条件下泥沙吸附重金属污染物达到平衡状态需要6小时以上,由极坐标下的重金属迁移转化数学模型方程,在本文具体试验条件下进行数值求解,计算结果和试验结果合良好,说明数学模型是正确合理的试验是可靠的。计算时依据室内静态试验结果,对动态 相似文献
89.
吸附法脱除乙烯中少量氧气的吸附剂研究 总被引:7,自引:1,他引:6
采用重量法在电子天平上研究了C2H4和O2单组份在5A、13X、丝光沸石和碳分子筛等不同吸附剂上的吸附平衡性质和扩散动力学性质。结果表明,在沸石类吸附剂上,C2H4的平衡吸附量远大于O2的平衡吸附量,C2H4的吸附扩散速率也大于O2的扩散速率;在碳分子筛吸附剂上C2H4的平衡吸附量大于O2的平衡吸附量,但O2的吸附扩散速率远大于C2H4的扩散速率,其扩散系数是C2H4的239倍。单柱评价结果表明,C2H4-O2混合组份通过该碳分子筛吸附剂时,O2的破点时间长,C2H4的纯度可达100%。加压有利于选择吸附O2,而且加压吸附、常压脱附再生性能好。该碳分子筛是脱除高浓度乙烯中少量氧气的理想吸附剂。 相似文献
90.
在复兴大桥超高吨位灌注桩的静载试验,预应力混凝土反力装置替代了传统的钢梁反力系统。这套装置主要包括预应力锚桩、预应力承台与预应力反力梁。试验结果表明,直接获得超高吨位大直径嵌岩桩的极限承载力相当不易,而对这类问题预应力混凝土反力装置是值得考虑的。 相似文献