“入世”对PVC糊树脂行业的影响及对策

“入世”后,在5年内我国PVC糊树脂将从现实实施税率16％降到6．5％。这会给国内PVC糊树脂行业带来一些影响,多方面挤压国内PVC糊树脂的生存空间。因此,熟悉、运用世贸组织的有关规则,加快科技进步,调整产品结构,调整产品结构,转变经营观念,努力开拓、占领市场,是国内PVC糊树脂“入世”的重要措施。     

发酵法生产医药用透明质酸

山东临朐华元生物工程有限公司通过对菌株的筛选培育、发酵原料配方和工艺的改进、提纯工艺和设备的优化、制粉工艺和设备的改进、生产环境的改造,利用生物工程技术发酵法研制生产出医药用透明质酸,并形成1.5t/a的生产规模。产品应用于眼科手术、滴眼液、手术防粘连等方面,改变了国内医药用透明质酸依赖进口或动物器官提取法微量生产自用的局面,为国内以透明质酸为基质的制剂产品发展打下了基础。     

多孔催化剂效率因子的多组分扩散模型(Ⅴ) 表面中毒并伴有平衡死区圆柱状催化剂效率因子的有限元求解

针对表面中毒并伴有平衡死区二维圆柱状催化剂的反应-扩散偏微分方程组的特殊性,引入有限元方法求解该类问题,建立了求解步骤。实际计算所得效率因子与实验值对照表明,本法结果准确,过程简单,容易推广应用于各种相类似的体系。     

Dynamic Compressibility of Carbamide at Low Pressures

The shock adiabats of pressed carbamide samples with a density of 1.29 g/cm³ and carbamide samples with a bulk density of 0.78 g/cm³ were studied at pressures of 1–14 GPa using an electromagnetic method. In the coordinates D and U, the shock adiabat of pressed carbamide is linear and the shock adiabat of carbamide of bulk density at a pressure of 2.4 GPa is represented as two linear segments: D = 2U at 0.6 < U <1.3 km/sec and D = 0.6 + 1.55U at 1.3 <U < 2.8 km/sec. The possibility of a phase transition in carbamide under shock compression is discussed.     

FP—640火焰光度计测定氯化铵中氯化钠的含量

介绍了FP—640火焰光度计采用低、高标法钠含量的测定。与标准曲线法钠含量测定相比较,该法具有方便、快速、准确度高的特点。     

Solvent free liquid phase oxidation of benzyl alcohol using Au supported catalysts prepared using a sol immobilization technique

Solvent free oxidation of benzyl alcohol was investigated in the absence of a base using Au catalysts prepared by sol immobilization on titania and carbon supports. Comparison between the Au supported catalysts revealed that activity and distribution of products was dependent on the nature of support and heat treatment. Specifically, heat pre-treatment of the Au catalysts has a beneficial effect in terms of activity, but is detrimental in terms of selectivity to the benzaldehyde. We conclude that sol immobilization is a suitable technique for preparing gold catalysts with small particle size and narrow particle size distributions and very high activity and selectivity for benzyl alcohol oxidation.     

Synthesis and properties of an alkoxysilane dye containing three electronic donor groups for nonlinear optical applications

In order to obtain an efficient hybrid inorganic–organic nonlinear optical (NLO) materials, an azo-dye containing three electronic donor groups 2,5-dimethyl-4-(4′-nitrophenylazo)phenol (DMNPAP) was synthesized and reacted with 3-isocyanatopropyl triethoxysilane (ICTES) to give an alkoxysilane dye (ICTES–DMNPAP). Molecular structural characterizations for DMNPAP and ICTES–DMNPAP were investigated by elemental analysis, ¹H NMR, FTIR, UV–visible spectra and differential scanning calorimetry (DSC). The alkoxysilane dye could be hydrolyzed and polymerized in the presence of water, and then transparent hybrid films could be fabricated by spin coating on the indium–tin-oxide (ITO) glass substrates. Compared with the dye 4-nitro-4′-hydroxy-azobenzene (NHA) containing only one hydroxyl as donor group, DMNPAP exhibited larger β_CTμ_g value measured by solvatochromic method, and second harmonic generation (SHG) measurement of the hybrid films was in agreement with the result.     

Intercalation of methylene blue in n-alkanethiolated self-assembled monolayers: Versatile electrochemical platforms for characterizing surfactant adsorption on hydrophobic surfaces

A versatile electrochemical platform for characterizing the adsorption of neutral and positively charged surfactants on hydrophobic surfaces was established using methylene blue (MB) as the probe. As a rigid, planar and electroactive species, MB can intercalate inside the regular self-assembled monolayers (SAMs) of n-hexanethiol and exhibit well-defined electrochemical responses. The adsorption of surfactants on the hydrophobic SAMs through the intercalation interaction between the hydrophobic tails of surfactants and the SAMs might change the density of the SAMs and influence the electrochemical behaviors of MB, providing a simple but effective approach for characterizing surfactant adsorption on hydrophobic surfaces. As an example, the adsorptive behaviors of cetyltrimethylammonium bromide (CTAB), a positively charged surfactant, and Triton X-100, a neutral surfactant, on hydrophobic surfaces were investigated by cyclic voltammetry and electrochemical impedance spectroscopy. The results showed that these surfactants generally experienced three different adsorptive behaviors: the monomer adsorption at low concentrations, the loose monolayer adsorption at intermediate concentrations and the dense monolayer adsorption at high concentrations. In the case of CTAB, a new additional submonolayer adsorptive behavior between the monomer and the loose monolayer adsorption was observed for the first time, due to its rather long hydrophobic tail.     

Manganese ferrite nanoparticles synthesized through a nanocasting route as a highly active Fenton catalyst

Spinel ferrite MnFe₂O₄ nanoparticles were synthesized by means of a nanocasting technique using a low-cost mesoporous silica gel as a hard template. The magnetic nanoparticles, of <10 nm diameter and with a surface area of around 100 m²/g, were tested as a heterogeneous Fenton catalyst for the decomposition of hydrogen peroxide under neutral and basic conditions. This catalyst shows a much higher activity than previous heterogeneous catalysts reported in the literature, which is mainly ascribed to its small particle size. Furthermore, the magnetic catalyst can be easily separated from the reaction medium by means of an external magnetic field. The effects of residual silica and the purity of the catalyst (hematite formation) on catalytic activity have been studied and correlated. The results obtained show this catalyst to be a suitable candidate for the removal of pollutants in wastewaters by means of the Fenton heterogeneous reaction.     

Preparation of Mesoporous Ni–alumina Catalyst by One-step Sol–gel Method: Control of Textural Properties and Catalytic Application to the Hydrodechlorination of o-dichlorobenzene

Mesoporous Ni–alumina catalysts (Ni–alumina-pre and Ni–alumina-post) were synthesized by one-step sol–gel method using micelle complex comprising lauric acid and nickel ion as a template with metal source and using aluminum sec-butoxide as an aluminum source. The Ni–alumina catalysts showed relatively high surface areas (303 m²/g for Ni–alumina-pre and 331 m²/g for Ni–alumina-post) and narrow pore size distributions centered at ca. 4 nm. Highly dispersed Ni particles were observed in the Ni–alumina catalysts (ca. 5.2 nm for Ni–alumina-pre and ca. 6.8 nm for Ni–alumina-post) after reduction at 550 °C, while a catalyst prepared without a template (NiAl-comp) exhibited inferior porosity with large metal particles (ca. 12.3 nm). Mesoporous Ni–alumina catalysts with different porosity were obtained by employing different hydrolysis step of aluminum source. When aluminum source was hydrolyzed under the presence of micelle complex, a supported Ni catalyst with highly developed framework mesoporosity was obtained (Ni–alumina-post). On the other hand, when aluminum source was pre-hydrolyzed followed by mixing with micelle solution, the resulting catalyst (Ni–alumina-pre) retained high portion of textural porosity. It was revealed that the hydrolysis method employed in this research affected not only textural properties but also metal-support interaction in the Ni–alumina catalysts. It was also found that the Ni–alumina-pre catalyst exhibited weaker interaction between nickel and alumina than the Ni–alumina-post, leading to higher degree of reduction in the Ni–alumina-pre catalyst. In the hydrodechlorination of o-dichlorobenzene, the Ni–alumina catalysts exhibited better catalytic performance than the NiAl-comp catalyst, which was attributed to higher metal dispersion in the Ni–alumina catalysts. In particular, the Ni–alumina-pre catalyst showing 1.5 times higher degree of reduction and larger amounts of o-dichlorobenzene adsorption exhibited better catalytic performance than the Ni–alumina-post catalyst.