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991.
Graft copolymerization of acrylic acid (AA) onto polyphenylene sulfide (PPS) nonwoven initiated by low temperature plasma was studied. The effects of various conditions on graft reaction and the grafting rate were investigated. SEM images showed that PPS nonwoven was grafted, and the graft copolymerization only occurred on the surface of PPS. It may be due to the chain transference going with the graft copolymerization. It was found that with the increasing of plasma power, treatment time, space between electrodes, monomer concentration, and temperature of graft polymerization, the grafting rate increased at first, went to the top, and then decreased. The PPS nonwoven surface graft reaction could be optimized by the following processing conditions: 120 s of plasma treatment time, 50 W of plasma power, 1.5 cm of space between electrodes, 30% (w/w) of monomer concentration, and 50°C of temperature of graft polymerization. Measurement of XPS showed that the peak of C1s of graft polyacrylic acid was existed, and the peak area increased with the increase of the grafting rate. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 5884–5889, 2006 相似文献
992.
993.
994.
热压氮化硅在1200℃的高温疲劳损伤 总被引:1,自引:3,他引:1
研究了热压氮化硅陶瓷的室温和高温力学性能及在1200℃的高温疲劳损伤行为,发现材料的弹性模量、抗变强度与断裂韧性均随温度升高而下降,但在1000℃以上降低最为显著。在1200℃高温疲劳寿命与应力之间符合单对数线性关系经分析发现这种现象与失效的热激活过程有关。通过对实验数据,XRD相结构、变形动力学过程和断口的微观分析证明,陶瓷高温疲劳失效机理为“杂质空穴复合作用机制”。对热压氮化硅来说,失效机理主 相似文献
995.
Shiang-Hua Wang Ford-Son Hwang Tseung-Yuen Tseng 《Journal of the American Ceramic Society》1990,73(9):2767-2770
High-Curie-point semiconducting barium-lead titanate positive temperature coefficient of resistivity (PTCR) ceramics of composition Ba0.897 Pb0.1 La0.003 TiO3 and Ba0.5 Pb0.5 La0.003 TiO3 were prepared. The starting powders were synthesized by reacting commercial BaTiO3 , PbO, and TiO2 . To avoid the nonstoichiometry due to the volatilization of Pb during the sintering process, a lead atmosphere sintering approach with PbTiO3 as packing powder was used. The samples being fabricated by this method show a PTCR effect of 3 to 4.5 orders of magnitude above the Curie point. The curie points were about 180°C for Ba0.897 Pb0.1 La0.003 TiO3 and about 360°C for Ba0.497 Pb0.5 La0.003 TiO3 . 相似文献
996.
为研究不同煅烧温度下,含氟硫熟料中不同性能、形貌特征的A矿与水泥水化形成钙矾石的关系以及A矿对水泥水化性能的影响,采用工业原料并尽量模拟立窑内煅烧状况,对经1350℃和1425℃温度下煅烧的熟料进行了A矿形貌、A矿水化率及A矿与钙矾石形成关系等系列试验。试验结果表明,在传统的煅烧温度下(1400~l425℃)烧成的熟料.其A矿的固溶程度及A矿含量均比低温(1350℃)烧成的高;掺氟硫复合矿化剂烧制的熟料的A矿具有较高的水化速度,熟料强度较高.其制成的水泥在水化时,液相成分受高固溶程度A矿的水化所控制,所形成的钙矾石较低温煅烧的稳定.且A矿水化产物的形成与钙矾石(AFt)的形成较协调,水泥石机械强度更高。 相似文献
997.
998.
在有助剂和催化剂的作用下,采取低温、低压加氢技术。使氢化工艺能达到低温、低压、短氢化时间、氢化过程更加完善的目的。 相似文献
999.
Organic/inorganic composite membranes with different inorganic heteropolyacid (HPA) additives maintain sufficient proton conductivities for atmospheric pressure elevated temperature (>100 °C) polymer electrolyte fuel cell (PEFC) operation. However, membrane and membrane electrode assembly (MEA) processing is severely curtailed because of the solubility of the HPA additives in aqueous media. Composite membranes with the HPA (phosphotungstic acid; PTA) additive rendered insoluble by ion exchanging protons with larger cations such as Cs+, NH4+, Rb+ and Tl+ were fabricated. The additive loss in aqueous media was lowered from nearly 100% (unmodified HPA) to about 5% (modified HPA). The membranes were robust, and demonstrated low H2 crossover currents of around 2 mA/cm2 for a 28 μm thick membrane. All membranes were evaluated at high temperatures and low relative humidities in an operating fuel cell. The conductivities of the composite membranes at 120 °C and 35% relative humidity were on the order of 1.6 × 10−2 S/cm. 相似文献
1000.
Ji Hye Yoon Sang Beom Choi You Jin Oh Min Jeong Seo Young Ho Jhon Tae-Bum Lee Daejin Kim Seung Hoon Choi Jaheon Kim 《Catalysis Today》2007,120(3-4):324-329
A new mixed-valent iron MOF, formulated as Fe3O(F4BDC)3(H2O)3·(DMF)3.5 (1), has been synthesized by using a perfluorinated linear dicarboxylate to link trigonal prismatic Fe3(μ3-O)(O2C–)6 clusters. The structure refinement based on single crystal X-ray diffraction data collected from 1 reveals the material exhibits the acs topology with large channels along the crystallographic c-axis. Due to the presence of fluorine atoms the organic link, 2,3,5,6-tetrafluorobenzene-1,4-dicarboxylate (F4BDC), has a 63° torsion angle between the carboxylate and aromatic planes, resulting in larger channels compared to those in the isoreticular material MOF-235. While few iron-based MOFs have demonstrated porosity, nitrogen and hydrogen sorption experiments carried out at 77 K proved the porosity of outgassed 1, which has a Langmuir surface are of 635 m2/g and a gravimetric capacity of 0.9 wt% of hydrogen at 1 bar. 相似文献