安塞低渗油田孔隙结构对渗流特征曲线的影响

渗流曲线的测定是认识油藏流体渗流规律的基础。实验发现安塞油田储集层岩心渗流曲线在低有效净围压下近似表现为两段直线，通过压汞实验和毛管压力曲线数据分析，认为这种特征与储集层孔隙结构有关。在分析渗流特征时应综合考虑孔隙结核特征、流体与孔隙介质的相互作用等因素。     

Synthesis of oleyl oleate as a jojoba oil analog

Synthesis of a wax ester analog of jojoba oil was accomplished from oleic acid and oleyl alcohol with a zeolite as catalyst. A full 2³ factorial design at two levels has been used in the synthesis. The variables selected were temperature, reduced pressure and initial catalyst concentration. The most important variable within the range studied was temperature. Reduced pressure had a negative influence, and initial catalyst concentration showed a positive influence on the process. A response equation has been determined for the yield of ester. The properties of the synthesized product are similar to those of natural jojoba oil.     

Formation of toxic aldehydes in cod liver oil after ultraviolet irradiation

Formaldehyde, acrolein, malonaldehyde (MA), acetaldehyde and propanal produced from cod liver oil upon ultraviolet irradiation (λ_max=300 nm) were derivatized into nitrogenor sulfur-containing compounds and then analyzed by capillary gas chromatography with a nitrogen-phosphorus detector or a flame photometric detector. Acrolein and MA were formed at levels of 10.9±3.06 and 190.2±38.4 nmol/mg of fish oil, respectively. Maximum levels of formaldehyde, acetaldehyde and propanal formed were 7.0±0.90, 49.1±4.5 and 35.8±4.0 nmol/mg of oil, respectively. Formation of propanal in large quantities corresponded to the high content of ɛ-3 fatty acids in cod liver oil.     

东海盆地西南部地质特征与油气分布探讨

本文根据近3×10~4km地震和13口探井及其它地球物理、地质等方面资料,综合分析认为:东海盆地西南部与盆地其它部分在发育演化、构造运动、沉积环境等方面差异甚大。 盆地西南部(杭州湾—冲绳岛断裂以南地区)发育演化经历了断陷—坳陷—隆起—铺盖四个阶段。始新世末期的隆起在研究区演化史上有15～20Ma的沉积间断、剥蚀。这段历程,盆地其它部分未曾经历。其次是区内始新世末期抬升运动,致使始新统及以下老地层受剥蚀,仅始新统最大剥蚀量达1000m,这是盆地内绝无仅有的。第三是第三纪以海相沉积环境为主,特别在始新世,为海侵高潮,海城宽阔达8000km~2,这时盆地东北部正接受陆相沉积。研究区中部(北东向)可能存在超压泥岩及多套生油岩系,应为有利生油气区。研究区可能是盆地最有油气远景地区之一。     

20号合成烃航空润滑油应用的研究

对20号合成烃航空润滑油的使用性能，包括粘温性、氧化安定性、金属腐蚀性、金属磨损性以及高空起泡性等进行了研究，表明20号合成烃航空润滑油具有良好的使用性能，聚α-烯烃生产航空润滑油是合理的工艺路线。     

微波消解-ICP-AES法测定菜油中P、S

采用微波加热,在高温高压下酸消解样品,运用电感耦合等离子体原子发射光谱法(ICP-AES)同时测定菜油中P、S。本法选用紫外区谱线P178.221nm、S180.669nm,避免了基体中存在的Fe、Zn、Al、Cu、Mn、Ca等元素的光谱干扰。实验通过用纯氮吹扫光谱仪光路的方法消减空气中氧对紫外线的吸收,获得了足够的灵敏度。该方法简便、快速,稳定可靠,P、S检出限分别为0.067、0.078μg/ml,RSD为1.35%～5.05%,回收率为89.0%～100.9%。     

Temperature and pressure effects on supercritical CO2 extraction of tomato seed oil

Tomato seed oil was extracted with supercritical carbon dioxide in a semibatch-flow extractor within the temperature range 313–343 K and the pressure range 10.8–24.5MPa. The extraction rates increased with pressure, but decreased with temperature increase because of the variation in solvent density and resultant differences in oil solubility. The fatty acid composition of the extracted oil was similar to that of soybean oil.     

椰油酸单乙醇酰胺磷酸酯的制备及性能研究

以椰油酸甲酯、单乙醇胺，Ｐ２Ｏ５等为原料制备一种新型阴离子表面活性剂－烷醇酰胺磷酸酯盐。初步探讨了工艺条件，测定了其物化性能。     

Influence of two-step process and of different stoichiometric ratios on morphologies generated in castor oil epoxy resins

Phase separation during polymerization was studied in a model system consisting of a diepoxide based on diglycidyl ether of bisphenol A (DGEBA), variable amounts of ethylenediamine (EDA) and the mass of castor oil (CO) necessary to obtain a mass fraction equal to 0-15 in a final system where the stoichiometric ratio of amine to epoxy equivalents, r, was equal to 1. A two-step polymerization process was performed by curing first a system with r = 0-5, during variable times before phase separation, and then carrying the system to r = 1. Thermodynamic analysis of samples with different r values led to a linear relationship between the Flory-Huggins interaction parameter and r. The concentration (P) and average size (D?) of dispersed-phase particles followed opposite trends, i.e. P increased while D? decreased, when either r was increased or the time of curing in the first step of a two-step process was decreased. This was explained by assuming that the competition between nucleation and growth was determined by the viscosity at the cloud point, η_cp. Low values of η_cp favoured growth over nucleation and led to fewer but larger particles.     

环氧油一步合成的反应机理和动力学研究

研究了环氧油一步合成的反应机理和动力学；结合实验结果和理论分析动力学模型，首次提出：在适当的反应条件下，油脂的一步环氧化反应动力学模型可以表示为过氧酸生成反应动力学模型；其实验动力学模型方程为：ｒ０＝ｋ［Ｈ２Ｏ２］（０．９９）［ＨＯＡｃ］（０．９７），其中ｋ与催化剂用量有关。