Measurement of the Metal Surface Acidity/Electronegativity of Pt(110)

In previous work, it has been found that a hydrogen-covered Pt(110) surface is acidic, but quantification of the acidity has not yet been done. In this paper a spectroscopic method is developed to measure the acidity of a metal surface for the first time. The technique involves measuring the intensity of the N–H stretch from the C₅H₄XNH⁺ that forms when hydrogen coadsorbs with pyridine, 2-fluoropyridine and 3-fluoropyridine. The Bethe approximation is then used to estimate the metal surface acidity/electronegativity (MSAEL). The proton affinity/MSAEL of Pt(110) has been determined to be 907 ± 4 kJ/mol at high coverage. This is the first time the MSAEL has been measured on a metal surface. Implications for fuel cell catalysis are discussed.     

飞行时间二次离子质谱--强有力的表面、界面和薄膜分析手段

二次离子质谱（Secondary ion mass spectrometry，简称SIMS）是一种对表面灵敏的质谱技术，建立在表面各种类型带正、负电荷原子或分子发射的基础上。用飞行时间（Time of flight，简称TOF）仪器对这些二次离子进行质量分析，能确保并行质量登录、高质量范围、高流通率下的高分辨和精确质量测定这些优异性能。配合细聚焦扫描一次离子束，可在优于1nm的高深度分辨和优于50nm的横向分辨本领下，实现对表面优于单层ppm(百万分之一）量级的极高检测灵敏度。当今TOF－SIMS已发展为一种成熟且完善的表面分析技术。极高的灵敏度，再加上即使对大分子及不易挥发性分子都独具的敏感性，使它成为很多高技术领域不可缺少的分析手段，这些领域包括微电子学、化学和材料科学以至纳米技术和生命科学等。本文简述了TOF－SIMS的原理、仪器及其多方面的应用和展望。     

ZnS掺杂技术研究及应用现状

对现阶段国内外在ZnS及ZnS基材料掺杂改性方面的研究成果作一概述性介绍，综述了纳米级ZnS发光材料掺杂改性的基本机理，主要的掺杂技术、方法，并对多种掺杂元素的效果进行了分析比较。     

网格曲面中孔洞的光滑填充算法研究

三角网格模型是几何描述的一种重要形式，有着广泛的应用。但三角网络模型常常会存在孔洞缺陷。这些孔洞的存在一方面影响视觉效果，另一方面会影响许多后续的操作，如快速原型制造、有限元分析等，因此有必要对这些孔洞进行修补。目前绝大多数孔洞填充算法是将网格模型中的孔洞提取成空间多边形，并对孔洞多边形进行三角化。这种处理方法的主要缺陷是没有考虑网格曲面在孔洞附近的几何形态，因而填充部分不能与整个曲面光滑地融为一体。笔者提出了一种三角网格曲面中孔洞的光滑填充算法。该算法根据孔洞周围网格曲面的几何信息来增加孔洞内部的采样点，然后再对增加的采样点进行三角化，较好地解决了填充部分与整体曲面光滑连接的问题。     

映秀湾水力发电总厂计算机监控系统改造设想

映秀湾水力发电总厂计算机监控系统建设较早，因受当时计算机应用技术限制，使得目前运行的计算机监控系统存在很多不足之处，为此，提出对该系统进行改造的设想，旨在能进一步满足映电总厂“无人值班”（少人值守）和安全经济运行的需要。     

Effect of Cu concentration on the reactions between Sn-Ag-Cu solders and Ni

The reaction between the Sn-Ag-Cu solders and Ni at 250°C for 10 min and 25 h was studied. Nine different Sn-Ag-Cu solders, with the Ag concentration fixed at 3.9 wt.% and Cu concentrations varied between 0.0–3.0 wt.%, were used. When the reaction time was 10 min, the reactions strongly depended on the Cu concentration. At low-Cu concentrations (≦0.2 wt.%), only a continuous (Ni_1−xCu_x)₃Sn₄ layer formed at the interface. When the Cu concentration increased to 0.4 wt.%, a continuous (Ni_1−xCu_x)₃Sn₄ layer and a small amount of discontinuous (Cu_1−yNi_y)₆Sn₅ particles formed at the interface. When the Cu concentration increased to 0.5 wt.%, the amount of (Cu_1−yNi_y)₆Sn₅ increased and (Cu_1−yNi₆)₆Sn₅ became a continuous layer. Beneath this (Cu_1−yNi_y)₆Sn₅ layer was a very thin but continuous layer of (Ni_1−xCu_x)₃Sn₄. At higher Cu concentrations (0.6–3.0 wt.%), (Ni_1−xCu_x)₃Sn₄ disappeared, and only (Cu_1−yNi_y)₆Sn₅ was present. The reactions at 25 h also depended strongly on the Cu concentration, proving that the strong concentration dependence was not a transient phenomenon limited to a short reaction time. The findings of this study were rationalized using the Cu-Ni-Sn isotherm. This study shows that precise control over the Cu concentration in solders is needed to produce consistent results.     

提高曲面近似展开精度的方法与实现

通过对不可展曲面近似展开精度的研究，提出了根据曲面曲率的大小对曲面自动进行网格划分，通过对综合展开误差数据场进行数据拟合来选取最优展开基点，基于空间曲面与其展开图间近似的等距变换关系进行展开样形的误差矫正等3种方法，这几种方法的实现在不同程度上有效地减小了曲面的近似展开误差，提高了曲面的近似展开精度。     

从实例看花岗岩地基勘察的几个特点

以花岗岩类的硬质岩作为建筑物基础持力层,具有承载力高、稳定性好,抗震性强的特点,被许多重要建筑物所采用,尤其是沿海地区的高层建筑物。但往往此类基岩的层面不够“平整”,基岩层面的变化对基础的设计、施工,尤其是桩基础影响很大。本文通过对某高层建筑进行地基勘察的实例,总结了花岗岩地区风化岩层的几个特征及其在工程勘察中需注意的一些问题。     

胜利701气枪震源船改造设计

阐述胜利701气枪震源船震源系统的改造设计。改造设计使胜利701船达到了Ⅱ类航区海船的规范要求，满足了海上三维勘探和高分辨勘探的发展需要，为以后类似船舶的改造提供了经验。