槽液稳定性好的高硬度丙烯酸阳极电泳涂料的研制

在混合溶剂中加入甲基丙烯酸、各种甲基丙烯酸酯单体以及引发剂AIBN和链转移剂DDM,在85℃下反应合成了丙烯酸树脂。分别研究了不同酸值和羟值的丙烯酸单体、不同Tg的丙烯酸树脂以及各种助溶剂和中和剂对漆膜性能的影响。获得了丙烯酸阳极电泳涂料的最佳配方:丙烯酸共聚树脂的酸值为65 mg KOH/g、羟值为69 mg KOH/g、Tg为20℃,溶剂是体积比为1∶1的丙二醇单甲醚和异丙醇的混合物,中和剂是二乙醇胺。该电泳涂料具有良好的槽液稳定性和起泡消泡性。制得的涂膜外观平整、丰满、光亮,厚度为18~20μm,硬度为5 H,冲击强度为500 N/cm2,附着力为1级,柔韧性为1 mm,耐烟雾实验超过400 h。     

基于全散度的C-V模型阈值法

为了提高传统C-V模型的收敛速度并降低其对噪声的敏感性,提出基于全散度的C-V模型及其快速阈值分割算法。将Bregman散度与全散度统一获得新的全散度,并将其引入C-V模型的拟合偏差项,提高图像灰度值与分割区域平均灰度偏差值计算的鲁棒性。同时,采用变分水平集理论获得基于直方图的快速阈值计算方法。实验结果表明,该方法分割效果及收敛速度得到提高,且具有较好的鲁棒性和抗噪性。     

基于全概率公式直接推求管运洪水

本文为保证防洪安全的前提下充分发挥水库的综合效益,提出了基于全概率公式推求管运洪水的方法,并详细阐述了其基本原理;提出了在资料较短或前、后汛期洪水特性大致相同的情况下运用全概率公式推求管运洪水的实际方法;以马边站的洪水资料进行实例研究,其结果表明基于全概率公式推算出来的管运洪水既能使水库工程达到防洪标准,又能充分发挥水库的综合效益。     

负离子分解室内有机化合物的测试

低浓度、高毒性的挥发性有机化合物(VOC)污染大气,造成“病态建筑综合症(SBS)”,严重威胁着人们的身体健康。空气中的负离子除有利于人体生理健康以外,还能有效分解空气中的VOC。将一种负离子添加剂添加到墙体涂料中,可以得到一种能有效释放负离子的涂料。本文测试了涂刷负离子添加剂涂料的测试小室中负离子分解总挥发性有机化合物(TVOC)及甲醛的性能,结果证明:涂料释放的负离子能有效分解VOC,使室内VOC的浓度在较短时间内满足GB/T—18883—2002的要求。     

Self-emulsifiable soybean oil phosphate ester polyols for low-VOC corrosion resistant coatings

A series of soybean oil phosphate ester polyols (SOPEP) was prepared by reaction of fully epoxidized soybean oil with phosphoric acid and simultanoeous hydrolysis in the presence of a polar solvent. The polyols were characterized by determination of acid value, oxirane number, hydroxyl value, molecular weight (GPC), and FTIR spectra. These polyols with varying amounts of acid phosphate groups could be self-emulsified to form aqueous dispersions after neutralization with organic base. These aqueous dispersion showed varying degrees of stability and their appearance ranged from opaque dispersions to translucent to clear solutions. Waterborne coating compositions were prepared using these aqueous dispersions as principal components and their thermally cured film properties were studied. it was found that by careful selection and formulation, SOPEPs can be successfully used for low-VOC waterborne coating formulations. SOPEPs with 3.5% phosphate ester content showed visibly superior corrosion resistance properties.     

降低全低变工艺阻力的措施

将变换流程改为全低变工艺后,吨氨蒸汽消耗明显下降,但触媒床层阻力迅速上升.通过采取增设焦炭过滤器、更换触媒、改进蒸汽分布器等一系列措施,不仅保证了正常的生产指标,而且还使变换炉的阻力有了明显下降,取得了满意的效果.     

城市径流总量控制指标分解及实现路径探索与实践

针对海绵城市径流总量控制目标,提出一种在城市规划体系中控制性详细规划和修建性详细规划阶段分解落实年径流总量控制率的方法。在控制性详细规划阶段分解径流总量控制指标时,分步骤先后确定各项低影响开发措施的面积率和下沉深度;在修建性详细规划阶段,配合径流总量控制指标分解结果,给出适宜的各项低影响开发措施的技术实施导则,以保证各单项指标的正确实施,并以某项目为例介绍了技术实施导则的构建方法。     

含双丙酮丙烯酰胺(DAAM)的水性乳液的制备与性能研究

通过预乳化乳液聚合工艺,合成了含官能团单体双丙酮丙烯酰胺(DAAM)、丙烯酰胺、N-甲基丙烯酰胺(NMA)的自交联丙烯酸酯乳液。实验结果表明,DAAM用量的增加对乳液涂膜的硬度有影响,而涂膜的耐水性随NMA用量增加有显著提高,在DAAM用量为单体含量的2％,NMA用量为单体含量的4％时,涂膜的铅笔划痕硬度达2H,耐水性达96h以上。     

Hardness and Fracture Toughness of SiC-Particle-Reinforced MoSi2 Composites

The indentation technique has been used to evaluate the hardness and fracture toughness of SiC-reinforced MoSi₂ composites made by hot-pressing. It is seen that the toughness increases with increasing indentation crack length (under increasing load) and a probable mechanism responsible for this behavior is described. It is also observed that there is an optimum volume fraction of SiC particles for which the maximum fracture toughness of the composite can be achieved.     

Microhardness studies of PMMA/natural rubber blends

The microhardness, H, of PMMA/natural rubber blends, prepared following the solution method has been investigated by means of the microindentation technique. Hardness changes are correlated with the variation of the glass transition temperature. The influence of temperature and degree of deformation on H were additionally examined. The inclusion of rubber particles in the PMMA matrix is shown to soften the blends. The variation of the micromechanical property at the phase boundary of polymer/rubber particle has been studied. Results reveal that H drastically drops at the interphase. In the case of the drawn materials, the indentation anisotropy (ΔH) is shown to gradually increase with the draw ratio, where ΔH is found to be higher for the PMMA/rubber blend than for the original PMMA. This result is explained by the higher orientation of the PMMA molecules near the periphery of stretched rubber particles. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 205–210, 2004