In Situ FTIR Study of the Formation of an Organosilane Layer at the Silica/Solution Interface

An FTIR experiment especially designed to study the growth of an organosilane layer at the interface between a solution and a flat silica surface is presented. High sensitivity is achieved by using the attenuated total reflection (ATR) technique in a liquid flow cell. The ATR crystal, either silicon or germanium, is covered with a very thin silica layer. Chemical reactions of a mono-and a di-hydrolyzable silane with the silica substrate have been investigated. The grafting of a submonolayer of the first reagent has been monitored by following the C-H and SiO-H vibrations. The density of grafted molecules has been estimated and information on the nature of the chemical bonding has been achieved. Evidence for the chain-polymerization of the dihydrolyzable silane at the substrate/solution interface has been inferred from the appearance of a Si-O-Si absorption band.     

基于正则总体最小二乘准则的OFDM系统信道估计算法

基于导频的最小二乘(LS)估计方法的优点是结构简单,容易实现,但对噪声和干扰敏感。通过对OFDM系统中由于信道的时变性产生的载波间干扰进行了分析,在此基础上提出正则总体最小二乘(TLS)信道估计算法。根据Tikhonov正则化原理,导出了总体最小二乘正则化解法的计算公式。与一般的LS信道估计相比,TLS方法同时考虑了信道噪声和信道时变特性,所以该算法不仅在一般的信道条件下具有良好的性能而且也适合快变信道条件下的OFDM系统。仿真结果表明,该算法具有很好的均方误差和误比特率性能。     

关于饱和软土地基堤坝边坡稳定分析总应力法的讨论

在饱和的软土地基上修筑堤坝,由于孔隙水压力不易准确测定,需采用“φ=0”的总应力法进行稳定分析。这一做法在国外已明确纳入设计规范,在国内工程界较少受到重视,导致过高地估计了安全系数。本文首先系统地回顾了临界状态土力学中的伏斯列夫强度理论,在理论上阐述了饱和软土地基快速填筑时采用总应力法的原因,同时引用了Bishop和Bjerrum、美国联邦公路局、美国陆军工程师团与我国水电水利工程边坡设计规范的相关条文,确认在饱和软土地基采用总应力法进行稳定分析的合理性。以花敖泡土石坝和拉哇水电站围堰为工程实例,分别采用对土的固结不排水剪的两种做法开展稳定性分析,结果表明,直接将土的固结不排水剪强度指标ccu与φcu作为填筑后的强度参数,将严重高估其安全系数。因此建议正在修订的碾压式土石坝与边坡设计规范增加相应条文,并期望引起工程界对这一问题的重视。     

矩形明渠消力池水跃的水头损失研究

为了研究沿程水头损失与局部水头损失的变化规律,根据沿程水头损失的基本定义,推求矩形明渠消力池水跃区沿程水头损失与床面阻力系数、水跃共轭水深比、跃前断面宽高比及跃前断面水深的理论关系,提出了矩形明渠水跃区沿程水头损失及其系数和局部水头损失系数的理论公式,给出了沿程水头损失系数、局部水头损失系数和总水头损失系数的简单拟合公式。研究表明:沿程水头损失随着跃前断面水深和床面阻力系数的增大而增大,随着水跃共轭水深比和跃前断面宽高比的增大而减小;局部水头损失系数随着跃前断面弗劳德数的增大而增大;水跃区局部水头损失占比随着弗劳德数的增加而增加,弗劳德数为3时的局部水头损失占比达到90%,弗劳德数为6时的局部水头损失占比已达到95%以上。研究成果可进一步完善并丰富水跃理论体系。     

电机智能制造发展现状及推进策略

随着电机制造要求逐步提高、自动化逐渐普及,智能制造将成为未来主流的生产制造模式。基于对传统电机制造现状和发展趋势的分析,厘清智能制造优势及智能制造推进误区,概括智能制造推进内容及策略。以江苏大中电机股份有限公司相关项目为例,介绍智能制造的侧重内容、实施步骤、原则及实施成果。结果表明：总体生产效率提高了35.75%,生产运营成本降低了26.21%,产品不良率降低了75.84%。在此基础上概括电机行业智能制造推进参考战略,为中小型电机行业发展提供支持。     

Pro-Inflammatory Effect of Gliadins and Glutenins Extracted from Different Wheat Cultivars on an In Vitro 3D Intestinal Epithelium Model

There is a need to assess the relationship between improved rheological properties and the immunogenic potential of wheat proteins. The present study aimed to investigate the in vitro effects of total protein extracts from three modern and two landrace Triticum aestivum commercial flour mixes, with significant differences in gluten strength (GS), on cell lines. Cytotoxicity and innate immune responses induced by wheat proteins were investigated using Caco-2 monocultures, two dimensional (2D) Caco-2/U937 co-cultures, and three dimensional (3D) co-cultures simulating the intestinal mucosa with Caco-2 epithelial cells situated above an extra-cellular matrix containing U937 monocytes and L929 fibroblasts. Modern wheat proteins, with increased GS, significantly reduced Caco-2 cell proliferation and vitality in monoculture and 2D co-cultures than landrace proteins. Modern wheat proteins also augmented Caco-2 monolayer disruption and tight junction protein, occludin, redistribution in 3D co-cultures. Release of interleukin-8 into the cell medium and increased U937 monocyte migration in both 2D and 3D co-cultures were similarly apparent. Immuno-activation of migrating U937 cells was evidenced from cluster of differentiation 14 (CD14) staining and CD11b-related differentiation into macrophages. The modern wheat proteins, with gluten polymorphism relatedness and increased GS, were shown to be more cytotoxic and immunogenic than the landrace wheat proteins.     

再生砖混骨料混凝土柱的小偏心受压性能

通过小偏心受压性能试验对比研究3根的天然骨料混凝土柱和3根同强度全再生砖混骨料混凝土柱,强度分别为C25、C30和C35. 对6根柱进行加载试验,分析再生砖混骨料混凝土柱相比于同强度天然骨料混凝土柱在受力过程、破坏特征、变形能力与承载力等方面的差异. 试验发现,再生砖混骨料混凝土柱在小偏心加载至破坏的过程中,具有与天然骨料混凝土柱相似的3个受力阶段,且符合平截面假定. 与同强度的天然骨料混凝土柱相比,变形较大,但再生砖混骨料混凝土柱的极限承载力略高,原因可能在于两者轴心抗压强度的差异.     

铜冶炼企业产品质量控制的探索与实践

为了保持阴极铜化学成分和质量长期稳定,某铜冶炼企业对阴极铜化学成分进行监控,对铜冶炼生产系统中电解工序物料、产出后又重回本系统物料、贵金属系统中产出物料、外购原料中物料的杂质总量进行分析,提出了减少杂质对阴极铜质量影响的措施,为阴极铜质量的稳定创造了良好的生产条件,并提升了企业适应复杂原料市场的能力。     

普碳钢超大总压下量可逆冷轧工艺技术及生产实践

针对目前我国部分钢企由于现有工艺装备投产较早、技术落后、机组能力不足，只能采取中间退火+二轧程工艺生产0.12～0.15 mm薄规格冷轧产品，生产成本增加、周转周期长，不能灵活应对复杂多变的冷轧市场需求的状况，开发了普碳钢单轧程可以实现95%以上超大总压下量的单机架六辊可逆冷轧机组。结合国内新投产的某1 150 mm单机架六辊可逆冷轧机组的稳定规模化生产实践，阐述了机组工艺设备选型、主要工艺技术参数配置和生产需解决的核心关键技术难点，同时列举了几种市场需求量大、附加值高的薄规格冷轧产品的现场实际生产工艺参数，以说明该机组的实际应用效果。     

氧化还原反应式配平中可能差错的几种情况

本文通过许多实例，指出了氧化还原反应式配平中可能出现的得失电子数不等或电荷数未配平、得失电子关系不对及反应式中酸碱性介质有错误等几种差错，并归纳了在酸碱性水溶液中平衡介质的方法。