水轮发电机推力轴承甩油的处理

针对小山电站2号机组推力漏油问题,通过加大稳油板尺寸、加装挡油圈内挡油板、改变油位等方法进行了综合性的处理,弥补了推力轴承甩油导致碳刷打火这一重大缺陷,保证了机组的安全稳定运行.     

浅析人民币升值对广州市加工贸易出口的影响及对策

从人民币升值的大背景入手,对广州2005至2008年市加工贸易出口特点进行分析,以人民币汇率升值对广州市对外贸易的正反影响为例,从政府干预及政策支持和加工贸易出口企业的角度,提出广州加工贸易出口对应人民币升值的对策.     

济南市部分农作物产品虚拟水含量的研究

基于虚拟水的理论,利用标准彭曼公式和Cropwat软件,对济南市2008年的部分农作物产品虚拟水含量进行了计算分析。结果表明:小麦的虚拟水净进口量为-77477.9×103m3,属于虚拟水出口型作物,稻谷、棉花、豆类和花生果的虚拟水净进口量都是正值,属于虚拟水进口型作物。但总的来说,虚拟水的出口大于进口,这直接危及到济南市的水资源安全。针对这一现状,提出了通过虚拟水贸易和调整农作物种植结构的途径来实现济南市水资源的安全和可持续利用发展。     

高架桥声屏障高度对高速列车气动特性的影响

针对现代高速铁路建设中大量采用高架桥的现况,为保证列车安全、舒适、环保运行,给高速铁路建设工程提供参考数据,研究行驶在高架桥上的高速列车气动特性.利用FLUENT模拟单线高架桥声屏障高度对高速列车气动特性的影响.将声屏障分为6种不同高度,不考虑横向风且列车运行速度为200 km/h.地面和高架桥均设为移动壁面边界条件,...     

Thin‐film barriers using transparent conducting oxides for organic light‐emitting diodes

Abstract— This study covers thin‐film barriers using inorganic barriers of transparent conducting oxides (TCOs) such as zinc oxide (ZnO) and indium tin oxide (ITO). The TCOs were fabricated using a sputtering method with a process gas of pure argon at room temperature. ITO showed better properties as a barrier than the ZnO and exhibited the electronic performance necessary to perform additional functions. The ITO has superior barrier performance because it has a lower crack density due to its partial amorphous phase. For organic/inorganic multilayer barriers, the organic underlayer decreased the water‐vapor transmission rate (WVTR) more than the organic upper layer, indicating that the planarization effect was important in reducing the WVTRs. The results of this organic/ITO multilayer barrier study are expected to be useful in finding a practical solution to OLED encapsulation.     

微通道板BeO防离子反馈膜粒子阻透率的模拟研究

带有防离子反馈膜的微通道板是第三代微光像增强器件中的核心部件。文章阐述了防离子反馈膜的电子透过、离子阻止特性,利用Monte-Carlo模拟方法计算了氧化铍和三氧化二铝防离子反馈膜电子透过率和离子阻止率在不同条件下的变化曲线。模拟结果表明,氧化铍薄膜比三氧化二铝薄膜的电子透过特性好,而三氧化二铝薄膜比氧化铍薄膜的离子阻止本领好,证实了氧化铍作为防离子反馈膜的可行性。     

Drug self-assembly: A phenomenon at the nanometer scale with major impact in the structure–biological properties relationship and the treatment of disease

Under water-rich conditions, small amphiphilic and hydrophobic drug molecules self-assemble into supramolecular nanostructures. Thus, substantial modifications in their interaction with cellular structures and the ability to reach intracellular targets could happen. Additionally, drug aggregates could be more toxic than the non-aggregated counterparts, or vice versa. Moreover, since self-aggregation reduces the number of effective “monomeric” molecules that interact with the target, the drug potency could be underestimated. In other cases, the activity could be ascribed to the non-aggregated molecule while it stems from its aggregates. Thus, drug self-assembly could mislead from drug throughput screening assays to advanced preclinical and clinical trials. Finally, aggregates could serve as crystallization nuclei. The impact that this phenomenon has on the biological performance of active compounds, the inconsistent and often controversial nature of the published data and the need for recommendations/guidelines as preamble of more harmonized research protocols to characterize drug self-aggregation were main motivations for this review. First, the key molecular and environmental parameters governing drug self-aggregation, the main drug families for which this phenomenon and the methods used for its characterization are described. Then, promising nanotechnology platforms investigated to prevent/control it towards a more efficient drug development process are briefly discussed.     

EVA-g-GMA的制备及其对PLA/PHBV共混物性能的影响

通过熔融聚合法先制备了乙烯-醋酸乙烯酯接枝甲基丙烯酸缩水甘油酯(EVA-gGMA),采用红外光谱仪和核磁共振对EVA-g-GMA的结构进行了表征。然后将不同质量分数的EVA-g-GMA加入到聚乳酸/聚(3-羟基丁酸酯-co-3-羟基戊酸酯)(PLA/PHBV)共混物中,对共混物的性能进行研究。结果表明:GMA成功接枝到EVA上,随着EVA-g-GMA加入量的增加,PHBV与PLA的Tg升高,结晶度逐渐下降;分散相在PLA基体中的分散逐渐均匀,粒径减小,相界面渐渐模糊;在EVA-g-GMA加入后,共混物粘度升高,断裂伸长率和冲击强度分别可达290.9%和43.5KJ·m-2,三元共混物的水蒸气阻隔性相对于PLA/PHBV略有下降。综合考虑各种因素,EVA-g-GMA的加入使得PLA/PHBV的整体性能得到极大改善。     

燃气热循环下7YSZ热障涂层的微结构演变与阻抗谱特征

在1250℃燃气热循环条件下,测试热障涂层抗冷热冲击性能,以模拟发动机叶片的启动升温与关闭降温循环过程。采用电化学阻抗谱测试和扫描电镜(SEM)系统研究热循环过程中热生长氧化物(TGO)生长与YSZ陶瓷层微结构演变。结果表明:随着热循环次数增加,热障涂层内TGO不断生长变厚,在中频阶段的阻抗谱响应越来越显著。YSZ陶瓷层内部经历了微裂纹的萌生与扩展两个阶段。经过100次热循环后的YSZ层表现出与喷涂态涂层相似的阻抗特征,表明高温下烧结会使YSZ层产生的微裂纹在短时间内愈合。但经过300次热循环后的YSZ层表现出与喷涂态完全不同的阻抗谱,并随热循环次数增加,YSZ颗粒间隙阻抗值不断增加,表明YSZ内层产生了不可愈合的微裂纹,是导致YSZ层最终失效的主要因素。     

Mechanical and thermal properties of RE4Hf3O12 (RE=Ho,Er, Tm) ceramics with defect fluorite structure

The thermal and environmental barrier coatings (T/EBC) are technologically important for advanced propulsion engine system. In this study, RE₄Hf₃O₁₂ (RE=Ho, Er, Tm) with defect fluorite structure was investigated for potential use as top TBC layer. Dense pellets were fabricated via a hot pressing method and the mechanical and thermal properties were characterized. RE₄Hf₃O₁₂ (RE=Ho, Er, Tm) possessed a high Vickers hardness of 11 GPa. The material retained high elastic modulus at elevated temperatures up to 1773 K, which made it attractive for high temperature application. The coefficient of thermal expansion (CTE) of RE₄Hf₃O₁₂ (RE = Ho, Er, Tm) laid in the range between 7 × 10⁻⁶ K⁻¹ to 10 × 10⁻⁶ K⁻¹ from 473 K to 1673 K. In addition, the rare earth hafnates exhibited lower thermal conductivity which rendered it a good candidate material for thermal barrier applications.