电子束蒸发制备CuAlO2透明导电膜及光学性质

利用烧结的CuAlO2靶材运用电子束蒸发法沉积了p型CuAlO2薄膜样品.在空气中1000℃退火之后,薄膜样品出现了(006)定向结晶,且铜铝原子比满足化学计量.CuAlO2薄膜呈现了很好的透明性,500nm厚的薄膜样品在可见光范围透射率超过了80%.利用光谱分析,CuAlO2薄膜的光学禁带约为3.80eV,其平均折射率约为1.54,同其它方法制备的该薄膜的性能相近.薄膜样品室温电导率约为0.08S/cm.     

硫酸铵盐制备氧化铝粉体及透明氧化铝陶瓷的微观结构

通过X射线衍射及扫描电镜,对在生产线上硫酸铵盐制得的类球形高纯氧化铝粉体进行了表征,并探讨了粉体表观特征对透明氧化铝陶瓷微观结构的影响.结果表明:在温度超过1 200 ℃时,获得的氧化铝粉体为三方α-Al2O3类球形晶粒,粉体中未发现γ-Al2O3.粉体的比表面积对陶瓷的烧成收缩有重要影响.采用干压成型时,具有适当低的比表面积的粉体制备透明氧化铝陶瓷时,有利于稳定其晶相结构,晶粒尺寸与粉体的比表面积有一定的关系.     

膨胀型脲醛树脂防火涂料的制备

以改性脲醛树脂为基料,磷酸和淀粉为阻燃剂制得膨胀型透明防火涂料.介绍该涂料的配方和生产方法,初步研究脲醛树脂改性机理.加入以造纸废液为主自制的稳定分散剂,涂料的稳定性大大提高,尤其是涂料不易凝胶,储存期延长.该涂料价格低廉,具有良好的阻燃防火性能和较好的透明性.     

红外探测器用滤光片的技术现状及应用

近红外滤光片和中红外带通滤光片在航天、气象和遥感等领域都有重要的应用。红外滤光片是让红外光透过而使其他波长光截止的滤光片,它的主要指标是峰值透过率。带通滤光片的重要指标是峰值透过率和通带半宽度。光学薄膜的膜系结构和具体设计对这些指标起决定性作用。本文主要介绍这两种滤光片的几例实际运用。     

环保型透明双组分改性聚氨酯胶黏剂的研究

报道了一种无溶剂、双组分、透明环氧改性聚氨酯胶黏剂,利用红外光谱法跟踪探讨了合成机理,分析了各基团之间的化学反应及其产物随时间的变化。结果表明:改性后聚氨酯的许多性能得到改进;在最佳原料配比及适宜的实验条件下,产品黏度适中,流动性好,性能稳定,储存期长;在m(合成环氧改性聚氨酯)∶m(固化剂)=5∶3的条件下,室温表干时间约45 min,剪切强度大于19 MPa,产品为韧性,耐溶剂、耐温性优良,固化过程中不起泡,用于粘接及灌封时美观。     

高强、高透明、紫外屏蔽细菌纤维素复合膜的制备与性能

本研究以细菌纤维素（BC）为主要原料,通过折射率匹配原理制备具有高透明度的聚乙烯醇（PVA）/BC复合膜,并进一步与环氧树脂（EP）复合,减小复合膜表面的粗糙度,从而降低其雾度,制备了高强、高透明且疏水的PVA/BC/EP复合膜。结果表明,PVA/BC/EP复合膜比纯BC膜具有更光滑的表面和更致密的结构,雾度低,光透过率达90%;由于PVA、BC和EP之间存在相互作用,复合膜的拉伸强度高达177.1 MPa,表面疏水性也得到明显提高。引入碳量子点可赋予复合膜良好的紫外光屏蔽性能,为高强度、高透明度及紫外屏蔽多功能膜材料的应用提供了新思路。     

丙烯酸透明粉末涂料在汽车车身罩光方面的应用

分析了丙烯酸粉末涂料用于汽车车身罩光时需要解决的若干问题,如降低固化温度、提高涂层抗冲击性能、提高涂层表面光滑平整度、提高涂层耐候性能、提高与底漆的配套性能等。针对不同问题,给出了相应的解决工艺。     

Synthesis and luminescence characterization of Pr3+, Gd3+ co-doped SrF2 transparent ceramics

Pr³⁺, Gd³⁺ co-doped SrF₂ transparent ceramic, as the potential material for visible luminescent applications, was prepared by hot-pressing of precursor nanopowders. The microstructure, phase compositions, and in-line transmittance, as well as the photoluminescence properties were investigated systematically. Highly optical quality Pr,Gd:SrF₂ transparent ceramic with nearly pore-free microstructure was obtained at 800°C for 1.5 hours. The average in-line transmittance of the x at.% Pr, 6 at.% Gd:SrF₂ (x = 0.2, 0.5, 1.0, 2.0) transparent ceramics reached to 87.3 % in the infrared region. The photoluminescence spectra presented intense visible light emissions under the excitation of 444 nm, the main intrinsic emission bands located at 483 and 605 nm, which were attributed to the transitions of Pr³⁺: ³P₀ → ³H₄ and ¹D₂ → ³H₄, respectively. With the co-doping of Gd³⁺ ions, the emission intensity of the Pr:SrF₂ transparent ceramic was greatly enhanced. All the emission bands of x at.% Pr, 6 at.% Gd:SrF₂ transparent ceramics exhibited the highest luminescence intensity with the 1.0 at.% Pr³⁺ doping concentrations, whereas the lifetimes decreased dramatically with the Pr³⁺ doping contents increasing from 0.2 to 2.0 at.% due to its intense concentration quenching effect. The 1 at.% Pr, 6 at.% Gd:SrF₂ transparent ceramic is a promising material for visible luminescent device applications.     

Er3+-doped CaF2 polycrystalline ceramic with perfect transparency for mid-infrared laser

Er³⁺-doped CaF₂ transparent ceramics are promising mid-infrared gain materials because of their utra-low phonon energy as well as excellent physical, chemical, and optical properties. However, existing hot-pressed and hot-formed CaF₂ ceramics are very difficult to be used in practical applications due to residual pores and weak polycrystallization, respectively. Here, we developed the high quality Er³⁺-doped CaF₂ transparent polycrystalline ceramic by single crystal ceramization. The sample exhibits obvious polycrystalline structure, good mechanical properties, perfectly transmittance, and excellent mid-infrared performance, which provides significant and wide-ranging opportunities for advanced mid-infrared gain materials.     

Processing of CaLa2S4 infrared transparent ceramics: A comparative study of HP and FAST/SPS techniques

The densification of CaLa₂S₄ (CLS) powders prepared by combustion method was investigated by the use of Field-Assisted Sintering Technique (FAST) and Hot Pressing (HP). CLS powders were sintered using FAST at 1000°C at different pressures and heating rates and sintered by HP under 120 MPa from 800°C to 1100°C for 6 hours with a heating rate of 10°C/min. Comparison of both techniques was further realized by use of the same conditions of pressure, dwell time, and heating rate. Complementary techniques (XRD, SEM-EDS, density measurements, FTIR spectroscopy) were employed to correlate the sintering processes/parameters to the microstructural/compositional developments and optical transmission of the ceramics. Both sintering techniques produce ceramics with submicrometer grain size and relative density of about 99%. Nevertheless, HP is more suitable to densify CLS ceramics without fragmentation and also reach higher transmission than FAST. Transmission of 40%–45% was measured out of a possible maximum of 69% based on the Fresnel losses in the 8-14 μm window when HP is applied at 1000°C for 6 hours under 120 MPa. In both techniques, ceramics undergo reduction issues that originate from graphitic sintering atmosphere.