离子交换铒掺杂磷酸盐玻璃波导特性研究

给出有关离子交换铒掺杂磷酸盐玻璃波导的制备以及发光特性的基本结果。用Ag+ Na+ 离子交换在含有适量氧化钠的铒掺杂磷酸盐玻璃上很容易实现低损耗平面波导 ,并且离子交换过程对这种玻璃的光谱特性没有影响。     

浅论国内大中型磷铵装置技术改造路线的选择

简述国内磷酸二铵的建设情况及不同的生产工艺、原有磷酸二铵装置改造选用的工艺及生产情况 ,重点介绍 Incro工艺在云南红河州磷肥厂年产 12万吨磷铵装置中的改造情况 ,经过比较认为原采用预中和槽流程磷酸二铵装置增产改造时选用 Incro工艺比较合适     

Preparation of Laminin-apatite-polymer Composites Using Metastable Calcium Phosphate Solutions

A synthetic polymer with a laminin-apatite composite layer on its surface would be useful as a percutaneous device. The preparation of such a composite was attempted in the present study using poly（ ethylene terephthalate ） （PET） and polyethylene （PE） as the synthetic polymer. PET and PE plates and those pretreated with an oxygen plasma were alternately dipped in calcium and phosphate ion solutions, and then immersed in a metastable calcium phosphate solution supplemented with laminin （ LCP solution ）. The PET and PE plates pretreated with an oxygen plasma formed a uniform and continuous layer of a laminin-apatite composite on their surfaces. In contrast, the PET and PE plates that had not been pretreated with an oxygen plasma did not form a continuous layer of a laminin-apatite composite on their surfaces. The hydrophilic functional groups on the PET and PE surfaces introduced by the plasma treatment were responsible for the successful laminin-apatite coruposite coating.     

Reconstruction of Mandibular Defect with Porous β-TCP/BMG Artificial Bone

1Introduction Reconstructivesurgeryisoneofthehottestre searchedsubjectsthatdealingwithbonedefects.Thetra ditionalmethodisimplantationoffreshautograftbonebe causeofitsnon immunoreactiveproperty.Butautologousbonewasnotabundantinsomecases.Sowefoundbeta trica…     

Ionothermal synthesis of a three-dimensional zinc phosphate with DFT topology using unstable deep-eutectic solvent as template-delivery agent

A three-dimensional zinc phosphate compound with DFT topology, designated as ZnPO₄-EU1, has been synthesized by an ionothermal approach from the system HF-ZnO–P₂O₅-choline chloride-imidazolidone. Ethylenediamine, derived from decomposition of the imidazolidone component of the deep-eutectic solvent (DES) itself, is delivered to the synthesis and serves as an appropriate template for ZnPO₄-EU1. Experiments in which the synthesis conditions were varied showed that ZnPO₄-EU1 may be prepared over a wide molar ratio of P/Zn = 0.55–13.0. Powder X-ray diffraction patterns have been obtained at intervals to track the crystallization process of this material. The experimental data show that Zn₃(PO₄)₂ · 4H₂O (a dense phase) was first isolated from the DES after reaction for 1 h. Subsequently, the pure phase of ZnPO₄-EU1 was obtained with increasing crystallization time from 12 h to 72 h. The experimental results show that the nucleation and crystallization take place with relatively low levels of solvent degradation, demonstrating that zinc phosphate with a three-dimensional framework can be synthesized by in situ generation of an appropriate template using an unstable DES at high temperatures (150–200 °C).     

PHOSPHORUS AND PHOSPHATE LEVELS IN THE ALEURONE CELLS OF CEREAL GRAINS

The aleurone cells of barley, wheat, rice, rye, oats and triticale contained, comparatively, higher percentages of phosphorus than the aleurone cells of sorghum, maize or millet. The aleurone tissues of barley, wheat and rice had more phosphate than corresponding tissues of sorghum and maize. Phosphate was not detected in the aleurone tissue of maize but was found in trace amounts in the aleurone tissue of sorghum.     

A simple conceptual model for predicting the dissolution of phosphate rock in soils

Laboratory experimental and literature data were integrated to develop a simple, conceptual model to describe and predict the dissolution of a reactive phosphate rock (Gafsa phosphate rock, GPR) in soils. The model showed that initial solution Ca concentration strongly influences the time required for a single application of GPR (at 30 kgP ha^?1) to dissolve. The model predicts that all of the GPR will dissolve within a year of application in an unlimed, acid (pH_w 4.5) loam. However, if the soil has previously been limed to (pH_w 5.8, and contains permanent charge only, the model predicts that only about 50% of the GPR would have dissolved by the end of the second year after application. On the other hand, if a previously limed soil ((pH_w 5.8) contains variable-charge components, the model predicts that virtually all of the GPR would have dissolved in this soil by the end of the second year after application. These results emphasise that, even in the presence of a high proton supply, solution Ca has an overriding influence on the dissolution of GPR. The faster rate of GPR dissolution in the limed soil with variable charge, compared to that in the limed soil with permanent charge only, demonstrates the ability of the variable-charge component of soil to act as a sink for some of the lime-derived Ca. According to the solubility product principle, this allows more GPR to dissolve. Because of the generally stronger buffering of soil for P than for Ca, a relatively large proportion of any P removed by leaching and plant uptake is buffered by the sorbed phase. Consequently, the influence of leaching and plant uptake on GPR dissolution is attributed primarily to the removal of the relatively less-strongly buffered Ca.     

Use of TNSAC in phosphate adsorption studies and relationships. Isotherm relationships and utility in the field

There is a need for developing low cost, easily and abundantly available, yet efficient, adsorbents for the removal of phosphates during the tertiary treatment of wastewaters. The tamarind nut shell activated carbon (TNSAC) prepared on a laboratory scale has been used to evaluate its performance for phosphate adsorption. This paper describes the laboratory production of this adsorbent material in its various forms, and discusses the effects of the TNSAC process variables (the unrinsed and rinsed forms of the TNSAC and the impregnation ratio) on its performance in adsorbing phosphate. The material has been shown to be a good alternative adsorbent. As much as 95% phosphate removal by the unrinsed TNSAC is possible in about 30 min under the test conditions. The phosphate adsorbing capacity is about two times higher for the unrinsed TNSAC in comparison to the rinsed TNSAC. The adsorption rates, however, transit to extremely low rates towards the end when equilibrium conditions could be attained in about 2 h contact time. The phosphate removal mechanics are adsorption and precipitation/ion exchange when unrinsed TNSAC is used, and adsorption alone for the rinsed TNSAC. The maximum phosphate removal is found to take place at an impregnation ratio of 1.0 for both forms of the TNSAC.     

磷酸盐激光玻璃中铂颗粒密度与氧化还原平衡关系的研究

用吸收光谱法研究了Ｒ２Ｏ—ＢａＯ—Ｐ２Ｏ５系统磷酸盐激光玻璃中铂颗粒密度与铭的氧化还原平衡的关系。结果表明，玻璃中铂颗粒密度随平衡向右移动而减小；玻璃中平衡随熔炼气氛中氧分压增大、熔炼温度升高而向右移动，当足够大时，铂颗粒不能形成。     

Internal-corrosion inhibitors for pipelines in heat-supply systems carrying water with a high oxygen content

The reliability of heat-supply systems is determined primarily by internal corrosion of the pipelines. The concentration of oxygen in the water exerts a major influence on the corrosion. In systems with a standard oxygen content, OéDF-Zn is a highly effective corrosion inhibitor. However, there are systems in which the quality of deaeration of the make-up water of the heat-supply system is low (or deaeration is nonexistent), and the concentration of oxygen is considerably above the standard value. Classed among these systems, for example, are the HWS systems, which are incorporated into closed heat-supply systems. The oxygen concentration in these systems is analyzed to assess the situation. __________ Translated from élektricheskie Stantsii, No. 6, June 2007, pp. 35–39.