辐照改性聚丙烯拉伸流变行为及其挤出发泡的研究

通过在线形聚丙烯中加入双官能团丙烯酸酯类单体,经小剂量γ射线高能辐照,制备了高熔体强度聚丙烯,研究了其拉伸流变行为及其在挤出发泡方面的应用。Rheotens拉伸流变测试表明,辐照改性后由于形成了长支化分子结构,聚丙烯的熔体强度、拉伸黏度显著提高,具有明显的应变硬化特征。实验表明,ZnO可明显降低AC发泡剂分解温度,缓和分解放热;在辐照改性制备的高熔体强度聚丙烯中加入AC／ZnO复合发泡剂,可挤出发泡得到泡孔尺寸较为均一、分布均匀、具有闭孔结构的发泡材料。     

Effect of molecular weight and branch content on the creep behavior of oriented polyethylene

Creep studies were carried out on a range of homopolymers and copolymers of polyethylene with well‐defined molecular weight and branch content. The creep data were analyzed in terms of two thermally activated processes acting in parallel and the effects of molecular weight and branch content are discussed. It is shown that increasing either the number‐average molecular weight or the weight‐average molecular weight gives improved creep behavior at all stress levels. The introduction of butyl branches leads to lower creep at low‐stress levels but can give rise to higher creep at high stress. Plots of the equilibrium log₁₀(strain rate) versus stress at fixed draw ratio (strain) can be used to define sections through a unique true stress/true strain/strain rate surface for each material. These creep results have an additional value in terms of the link between slow crack propagation (SCG) in polyethylene and fibril creep, confirming the proposal made elsewhere that SCG can be quantified in terms of creep to failure across the true stress/true strain/strain rate surface. © 2003 Wiley Periodicals, J Appl Polym Sci 89: 1663–1670, 2003     

Internal fracture of notched epoxy resins

The brittle fracture of round-notched epoxy resin bars subjected to plane strain bending has been studied at varying strain rates. Observations of fracture processes and surface morphologies revealed that the internal crack was nucleated at the plastic-elastic boundary when the plastic deformation zone at the notch root reached a certain size. A slip-line field theory allows calculation of the stress components at the plastic-elastic boundary from a knowledge of the location of the internal crack. An analysis of the data concluded that the triaxial stress level ahead of the plastic zone was raised by plastic constraints to an ideal fracture stress which is considerably larger than that of glassy thermoplastics.     

Preparation and thermomechanical characterization of poly(vinyl chloride) blends compatible with terpolymer‐containing maleic anhydride

In this study, I aimed to change the thermomechanical characteristics of poly(vinyl chloride) (PVC), which is widely used in commercial areas. Copolymers containing maleic anhydride (MA) units are commonly used to obtain compatible polymer blends. In our study, PVC blends were also prepared with the terpolymers with and without anhydride units. I assumed that the impact of the terpolymer on the thermomechanical characteristics of the PVC material could be more effectively controlled. For this purpose, two sets of six different blends of PVC with or without MA were synthesized, among which one was pure PVC, but the other five blends contained 2, 4, 6, 8, and 10% terpolymer. In conclusion, I observed that the terpolymer with the MA unit more regularly changed the thermomechanical characteristics of PVC. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 1586–1589, 2004     

球窝型动态混合器结构和机理的研究

介绍研制的题示混合器结构及其混合机理。在分析球窝流场各节点速度分布的基础上,用加权平均总应变和分流混合度作为评定指标,对球窝型混合器的混合行为进行分析。通过对比实验证明球窝型混合器对于高粘流体具有良好的混合功效。     

响应面法优化甘油歧化产1,3-丙二醇菌培养基的研究

以甘油为原料,在单因素试验的基础上,利用响应面法研究了(NH4)2HPO4、K2HPO4/KH2PO4、pH值对1,3-丙二醇产量的影响,得到二次多项式回归模型.结果表明:回归模型能很好地反映各因素水平与响应值之间的关系,同时得出这3因素的最佳用量为(NH4)2HPO42.76 g/L、K2HPO4/KH2PO4(质量比1∶1)3.98 g/L、pH值7.58,此时1,3-丙二醇理论产量为28.702 g/L,实际产量为27.597 g/L,比优化前提高了19.02%.     

有粘结预应力外包角钢混凝土梁施工阶段弹性受力分析

外包钢混凝土结构构造简单、联接方便、承载力高、延性好。但作为受弯构件,其抗裂性能及抗弯刚度等优势不是很明显。对其施加预应力,形成有粘结预应力外包角钢混凝土结构,可以进一步提高构件的承载能力、抗弯刚度、抗裂性能、耐久性。文章对有粘结预应力外包角钢混凝土梁进行施工阶段弹性受力分析,并给出其相应应力、应变计算公式。     

模具沉积层应变的模拟

为分析沉积层应变的变化情况,并找出温度与形变的变化规律,采用有限元分析软件ANSYS计算并绘制不同时刻以及不同位置沉积层内的温度及应力应变曲线,在建立传热模型过程中考虑了金属液滴向沉积层的传热以及沉积层向系统外的热量散失等问题．采用在厚度方向以微小层逐层叠加来模拟涂层的增厚,并以此为基础构造沉积层有限元计算模型,应用单元生与死逐层激活层单元参与计算过程．实现移动边界以充分模拟真实的喷涂沉积过程．通过分析不同时刻以及不同位置沉积层内的应力应变曲线,获得了沉积层应力应变变化规律．结果表明,沉积层内存在残余塑性应变,且沉积层与母模接触部位等效应力最大,是最易翘曲的地方,验证了沉积层失稳的一般形式．     

弹性介质中框架结构的有限元计算分析(英文)

文章提出了一种考虑剪切变形,由经典弯杆理论发展形成的在弹性介质中框架结构的有限元计算方法.