CdCl2后处理的Mn掺杂钙钛矿纳米晶光学性能及其白光LED

Mn²⁺离子掺杂全无机钙钛矿(Mn²⁺∶CsPbX₃,X=Cl, Br)纳米晶(NCs)具有宽发射带、长斯托克斯位移和高量子产率等优势,在固态照明、光电探测和成像等领域有广阔应用前景。然而,目前Mn²⁺掺杂的钙钛矿晶体量子产率很难超过70%,如何改善发光效率,同时调控Mn离子发射中心成为构建高质量白光LED的关键。文章通过CdCl₂后处理技术,进行室温下阳离子交换,获得了高效发光的Cd²⁺和Mn²⁺共掺杂的CsPbCl₃纳米晶。Mn的发射波长可以从604 nm连续调控到624 nm,实现稳定的红光发射。Cd离子掺杂改善了Mn-Cl八面体的晶体场环境,使Mn衰减寿命提高到1.32 ms。此外,通过绿色CsPbBr₃纳米晶和蓝-橙双色Mn∶CsPb(ClBr)₃纳米晶构建了高显色指数的暖白光发光二极管(WLED),其流明效率达60 lm/W,显色指数超过85。     

Riemann-Liouville型分数阶导数的非线性估计（英文）

本文主要研究任意有界连续信号的Riemann-Liouville分数阶导数估计问题.当分数阶α属于0到1时,首先利用滑模技术提出一种有界连续信号分数阶导数的非线性估计方法;然后将其结果推广至分数阶α∈R⁺的情况,并给出相应的非线性估计方案.借助Riemann-Liouville分数阶微积分频率分布模型,本文详细分析讨论了所给分数阶导数非线性估计的收敛性问题,并得到相应闭环系统是渐近稳定的结论.文中所提方法的主要优点是在事先未知给定信号分数阶导数上界的情况下,不仅能自适应地估计其Riemann-Liouville分数阶导数,而且当信号中含有随机噪声和不确定扰动时依然能正常工作.数值仿真实例验证了本文所给估计方法的可行性和有效性.     

White‐Emissive Self‐Assembled Organic Microcrystals

Organic semiconductor micro‐/nanocrystals with regular shapes have been demonstrated for many applications, such as organic field‐effect transistors, organic waveguide devices, organic solid‐state lasers, and therefore are inherently ideal building blocks for the key circuits in the next generation of miniaturized optoelectronics. In the study, blue‐emissive organic molecules of 1,4‐bis(2‐methylstyryl)benzene (o‐MSB) can assemble into rectangular microcrystals at a large scale via the room‐temperature solution‐exchange method. Because of the Förster resonance energy transfer, the energy of the absorbed photons by the host matrix organic molecules of o‐MSB can directly transfer to the dopant organic molecules of tetracene or 1,2:8,9‐dibenzopentacene (DBP), which then emit visible photons in different colors from blue to green, and to yellow. More impressively, by modulating the doping molar ratios of DBP to o‐MSB, bright white‐emissive organic microcrystals with well‐preserved rectangular morphology can be successfully achieved with a low doping ratio of 1.5%. These self‐assembled organic semiconductor microcrystals with multicolor emissions can be the white‐light sources for the integrated optical circuits at micro‐/nanoscale.     

Path integral solution for nonlinear systems under parametric Poissonian white noise input

In this paper the problem of the response evaluation in terms of probability density function of nonlinear systems under parametric Poisson white noise is addressed. Specifically, extension of the Path Integral method to this kind of systems is introduced. Such systems exhibit a jump at each impulse occurrence, whose value is obtained in closed form considering two general classes of nonlinear multiplicative functions. Relying on the obtained closed form relation liking the impulses amplitude distribution and the corresponding jump response of the system, the Path Integral method is extended to deal with systems driven by parametric Poissonian white noise. Several numerical applications are performed to show the accuracy of the results and comparison with pertinent Monte Carlo simulation data assesses the reliability of the proposed procedure.     

频闪白光干涉技术

频闪白光干涉技术（SWLI）能够对被测系统进行动态模式的重建和表征,在微机电系统（MEMS）或微光机电系统（MOEMS）等振动样品测量中具有很高的实用性。传统频闪方法不能预先检测或分析具有单个振动激励源的微结构,而频闪白光干涉技术则解决了这一问题。为了全面了解这一新开发的技术,本文介绍了理论、技术方法和该技术各种应用的实验结果及分析。该技术为MEMS、MOEMS甚至微纳尺度生物体动态行为的重建和分析提供了一种有效的方法。实验结果和分析表明所开发的技术在实际应用中具有良好的可行性和准确性。     

神经元膜电位噪声取值范围的评估

大脑神经元的活动是在复杂的生理学环境下工作的，而生理学环境中的噪声来源于多个方面．如何定量地正确评估神经系统中的噪声环境是神经信息处理的基本问题．本文通过神经能量的计算给出了噪声对神经元膜电位及对应的能量波形产生显著影响的临界值的估计范围，从而定义了神经元赖以活动的生理学意义上的噪声环境．     

Dynamical responses for a vertical vibration model of a four-roller cold rolling mill under combined stochastic and harmonic excitations

Considering that random fluctuations can affect the rolling process of cold rolling mills, leading to abnormal cold mill performance and defects in the rolled product. Therefore, it is crucial to study the influence of random fluctuations on the system of cold rolling mills. In this paper, taking a model of the vertical vibration of a four-roller cold rolling mill under harmonic excitation as a prototype class for a real system, the effects of random fluctuations on the system response are analyzed. Firstly, based on the deterministic vertical vibration model of a four-roller cold rolling mill under harmonic excitation, a stochastic vertical vibration model of a four-roller cold rolling mill with random fluctuation as Gaussian white noise is introduced. Subsequently, the vertical vibration model of a four-roller rolling mill is theoretically analyzed by the averaging method and the stochastic averaging method, respectively. The effectiveness of the proposed theoretical method is verified by numerical simulation results, and the influences of harmonic excitation and random excitation on the system response are also investigated in detail. Finally, the results show that the noise induces the occurrence of stochastic transitions and bifurcations, and the steady-state probability density function and time history diagrams are given to further explain the existence of these dynamic phenomena. The related research can provide theoretical guidance for the realization of vibration control and reliability design in the four-roller cold rolling mill system.     

江南传统民居建筑色彩的成因

民居建筑是在特定文化空间与特定地理环境内产生的独特文化现象。是民族智慧与审美的结晶。民居建筑的规模、结构、装饰的形成演变,是其民族文化发展历程的缩影。建筑与民族文化之间是互为因果的关系。"黑瓦白墙"作为江南传统民居中具有代表性的古典建筑风格,尤具有独特的文化内涵。本文以此为立足点,透过文化属性与地理环境等因素来探析江南传统民居建筑色彩的成因。     

PIN OLEDs — Improved structures and materials to enhance device lifetime

Abstract— Currently, three issues are identified that decide upon the commercial success of organic light‐emitting diodes (OLEDs), both in display and lighting applications: power efficiency, lifetime, and price competitiveness. PIN OLEDs are widely seen as the preferred way to maximize power efficiency. Here, it is reported that this concept also delivers the world longest lifetimes. For a highly efficient deep‐red PIN OLED, a half‐lifetime of 25,000 hours for a starting brightness of 10,000 cd/m² and a minimal voltage increase over lifetime is reported. This value corresponds to more than 1 × 10⁶ hours at 1000 cd/m² using an exponent of n = 1.7, which was measured by driving the OLEDs at different starting luminances. Because there is no initial luminance drop, these PIN OLEDs also exhibit a very high 80% lifetime (>300,000 hours at 1000 cd/m²). New record lifetime values for blue and green will be reported as well. Additionally, further topics that have impact on the production yield and cost such as the newly developed air‐stable organic n‐doping material NDN‐26 and top‐emitting structures will be discussed.     

6063铝合金型材氧化过程中出现"白斑"的原因分析及解决

分析了6063型铝型金在硫酸阳极氧化过程中出现“白斑”的原因并提出了解决措施。