Adsorption of Cr(III), Ni(II), Zn(II), Co(II) ions onto phenolated wood resin

In this study, phenolated wood resin was used an adsorbent for the removal of Cr(III), Ni(II), Zn(II), Co(II) ions by adsorption from aqueous solution. The adsorption of metal ions from solution was carried at different contact times, concentrations and pHs at room temperature (25°C). For individual metal ion, the amount of metal ions adsorbed per unit weight of phenolated wood resin at equilibrium time increased with increasing concentration and pH. Also, when the amounts of metal ions adsorbed are compared to each other, it was seen that this increase was order of Cr(III) > Ni(II) > Zn(II) > Co(II). This increase was order of Cr(III) > Ni(II) > Co(II) > Zn(II) for commercial phenol–formaldehyde resin. Kinetic studies showed that the adsorption process obeyed the intraparticle diffusion model. It was also determined that adsorption isotherm followed Langmuir and Freundlich models. Adsorption isotherm obtained for commercial phenol–formaldehyde resin was consistent with Freundlich model well. Adsorption capacities from Langmuir isotherm for commercial phenol–formaldehyde resin were higher than those of phenolated wood resin, in the case of individual metal ions. Original adsorption isotherm demonstrated the monolayer coverage of the surface of phenolated wood resin. Adsorption kinetic followed the intraparticle diffusion model. The positive values of ΔG° determined using the equilibrium constants showed that the adsorption was not of spontaneous nature. It was seen that values of distribution coefficient (K_D) decreasing with metal ion concentration in solution at equilibrium (C_e) indicated that the occupation of active surface sites of adsorbent increased with metal ions. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 2838–2846, 2006     

木粉／低密度聚乙烯复合材料的发泡研究

用模压法制备木粉／低密度聚乙烯发泡材料。通过差示量热扫描分析,考察了纯偶氮二甲酰胺(AC)及与 ZnO共混物、纯NaHCO3及与柠檬酸(L)共混物的热分解特性,探讨了发泡剂AC、NaHCO3、柠檬酸、交联剂过氧化二异丙苯等对材料力学性能的影响,并在扫描电镜下观察了材料断面的微观形态。结果表明:采用放热发泡剂和复合发泡剂都能使复合材料密度下降20％左右,发泡后材料的冲击性能为发泡前体系的1．5倍左右;复合发泡剂的发泡效果优于单放热发泡剂的效果。     

Maxwell-Cattaneo方程组的非标准问题的衰减界

主要研究当温度和热量流满足非标准初始条件时的Maxwell-Cattaneo方程组.通过一些微分不等式,在参数的适当的范围上,结合非标准的初始条件,证明了温度和热量流的指数衰减界可由数据项确定.同时我们也推出了一个特例的解的指数衰减界.     

基于PSS/EBKDY模块的短路电流周期分量计算方法分析

介绍了一种基于电网仿真软件PSS／EBKDY模块的短路电流周期分量计算方法,分别用PSS／E和BPA机电暂态仿真软件对计算结果进行了校核．仿真结果显示,基于PSS／EBKDY模块的短路电流算法有较好的精确度,但该算法的缺点是不够保守,这将影响其在工程短路电流计算上的应用．     

太阳能相变储热系统对木材干燥速率的影响

针对木材太阳能干燥间歇性的不足,在原有太阳能干燥装置的基础上,增设了多管道叉排石蜡相变储热系统,并在小型试验台上模拟了木材太阳能干燥过程。试验研究表明:该干燥装置中储热系统供风温度对木材干燥速率的影响最大,干燥速率随着供风温度的升高而增加,最大的差值达到0.29%/h。;其次是循环风速,随着循环风速的提高干燥速率先增大后减小,在风速为1.5 m/s时的干燥速率最高,为1.0%/h;而石蜡管的管排数对干燥速率几乎没有影响,不同管排数下最大的差值为0.05%/h。此装置最优的干燥条件为:石蜡管管排为9排,循环风速为1.5 m/s,供风温度为65℃,此条件下干燥速率可达1.06%/h。上述研究结果可为木材太阳能干燥设备储热系统的研发提供参考。     

电子剪切散斑技术在木材无损检测中的应用

复合板材及木制品等表面或内部的缺陷对材料性能有很大影响,如何快速准确地对其进行无损检测,并判断缺陷的位置大小是很有意义的.针对松木板试件,通过预置表面和内部隐藏缺陷来近似模拟实际缺陷情况,提出一种基于剪切散斑干涉技术的木材无损检测技术新方法,实现了对松木试件的无损检测.在表面缺陷的检测中讨论了剪切量对结果的影响,利用像素标定的方法,得到直径为6、5、3mm的缺陷信息;在内部隐藏缺陷检测中,借助热加载技术同时引入相移技术使剪切散斑检测技术不仅具有非接触、全场实时检测等特点,而且完成对内部隐藏近表面缺陷的定量无损检测.整个检测过程光路简单,实时快速,实验结果与实际情况符合较好.     

CO2 gasification of wood charcoals derived from vacuum and atmospheric pyrolysis

The gasification of biomass derived char obtained via vacuum and atmospheric pyrolysis of Populus tremuloides has been studied in the ranges of 725–960°C and 0.1 to 6 MPa. CO₂ was used as the oxidizing gas. The results show that char reactivity is influenced by the preheating rates and that pressure effects are significant between 850°C and 950°C. A correlation based on the expression: df/dt = k₀{exp(-E/RT)}(1 - f)^af^βP^yCO₂ was used to fit the experimental data. In general, vacuum pyrolysis derived char showed a higher reactivity than atmospheric pyrolysis chars. An explanation based on a higher oxygen content of the vacuum pyrolysis char is suggested.     

Experimental investigations of long stick wood gasification in a bottom lit updraft fixed bed gasifier

Based on the experience of the gasifier users on the efforts and energy for wood chip preparation in a typical gasifier, we have embarked on the development of a gasifier suitable to work with long stick woody biomass as the feed materials. In the context of the impact of gasifiers, as decentralized energy delivery devices such an approach, it is hoped, would be an attractive option in rural areas both in domestic and industrial sectors. In the present paper in the gasifier operation, there is a fixed quantity of char that is combusted to gasify a fixed amount of wood, and the gasifier does not operate in a steady state manner. In this present work, focus is made on the development of a gasifier using long sticks of wood as feed materials. With this concept, a 10 kW thermal output power gasifier is designed and constructed. The gas and airflows can be converted to the air/fuel ratio, the most important aspect of gasifier operation. The air/fuel ratio shows operation in a combustion mode at start up, a gasification mode for the middle part of the run and a charcoal gasification mode at the end of the run. Since the interest here is exploring and validating of this concept, a bottom lit updraft gasifier is designed mainly to look at the gas yield and other favourable factors and to use this gas so obtained for thermal applications. The rate of feed was between 9 and 10 kg/h and continuous operation for 5 h was made in a couple of runs to study the performance. In this paper we report the salient features of our efforts and results, yielding a gasifier efficiency of 73%.     

The use of wood pulp and radiation‐modified starch in wastewater treatment

Radiation‐induced graft copolymerization of maize starch/acrylic acid has been performed. Also, natural byproduct wood pulp was used after chemical treatment for the removal of metal ions from the investigated wastewater. The surface and structure morphology of the wood pulp and starch/acrylic acid were investigated by scanning electron microscopy and infrared spectroscopy. The physical parameters, such as swelling, gel percentage, and grafting efficiency (%) of starch/acrylic acid copolymer, were studied. The factors affecting the abilities of the prepared materials for removing heavy metal ions and dyes from aqueous solutions were studied. It was found that the maximum metal uptake is in the following sequence: Fe³⁺ > Cr³⁺ > Pb²⁺ > Cd²⁺. The adsorption capacity of such investigated metal ions increases with the increase of pH values. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci, 2006     

多孔介质微波加热厚度的确定

简述了微波加热的机理，以湿木材为研究对象，通过理论计算确定了微波在木材中的穿透深度。计算表明：随着木材含水率和微波工作频率的增加，微波在木材中的穿透深度减小；当用频率为915MHz和2450MHz的微波加热或干燥具有高含水率的多孔介质时，多孔介质的最大厚度应分别控制在16cm和6cm以内。