钛掺杂硅胶块体吸附剂

以陶瓷纤维纸片为基材,顺次经水玻璃、酸性钛盐溶液浸渍共沉淀制得新型陶瓷基钛掺杂硅胶块体吸附剂.多孔介质表面分析显示:掺杂硅胶孔径在0.5～6 nm范围,以中孔为主.Fourier变换红外谱在波数954 cm 1处的特征吸收峰表明吸附剂中形成了Si-O-Ti键.根据掺杂前后固体魔角核磁共振硅谱中硅原子化学位移的变化(向高场方向移动)及X射线光电子能谱中各原子结合能的变化(Ti2p3/2的结合能随钛含量的增加而增加,而Si2p,O1s的结合能则呈相反趋势)进一步表明:钛原子替代硅原子进入硅胶网络.热重分析及烧结实验结果显示:钛掺杂吸附剂具有更好的热稳定性.新型吸附剂优异的吸附性能除了与其高的比表面积相关外,还与Ti-O键对水分子的亲合力紧密相关,其耐热性能增强与形成高热稳定性Ti-O Si键及材料表面导热性能提高有关.     

Varnish layer hardness of oriental beech (fagus orientalist L.) wood as affected by impregnation and bleaching

The impacts of impregnation and bleaching on the varnish layer hardness of Oriental beech (Fagus orientalist L.) wood were investigated. A number of bleaching combinations {[NaOH−H₂O₂], [NaOH−Ca(OH)₂−H₂O₂], [NaOH−MgSO₄−H₂O₂] [NaHSO₃−H₂C₂O₄], [NaSiO₃−H₂O₂], [KMnO₄+NaHSO₃+H₂O₃]} were applied at 18% concentration for bleaching to both impregnated and unimpregnated specimens of Oriental beech wood. Subsequently, water-based (WB) varnish was coated over the samples and the varnish layer hardness values were determined in accordance with ASTM D 4366-95. All of the chemicals used for bleaching reduced the surface hardness. However, after varnish coating, the hardness of most samples was similar to that of the varnish-coated natural (control) samples.     

中国涂料现状及今后发展热点(一)

综述了目前中国涂料业的发展概况,并介绍了今后发展趋势和研究热点──防腐蚀涂料、卷材涂料、功能涂料、绿色木器涂料和粉末涂料等5种涂料。     

改性木粉/PVC复合材料的研究进展

概述了PVC木塑复合材料的发展和背景与性能。简述了木质材料的性质和木粉改性的方法,如物理方法和化学方法。介绍了木塑复合材料的生产流程、成型方法(模压成型、挤出成型、注射成型及其成型设备,讨论了对工艺参数的一些要求。指出目前国内PVC木塑复合材料发展存在的一些问题,并指明了PVC木塑复合材料的应用前景。     

浸渍增重率和反渗率研究

对浸溃过程中浸渍剂沥青的浸入率和反渗率进行了分析与探讨。提出了理想增重率、理论增重率与实际增重率的概念和计算方法。并比较了实际增重率与操作增重率的差别。同时分析了抽真空的绝对压力与施压的绝对压力对各项增重率和反渗率的影响。     

几种云南木材液体浸渍行为的研究

研究了几种云南木材在水和有机液体中的浸渍行为 ,探讨了浸渍液体的溶解度参数、木材种类和密度、助浸剂、浸渍时间和压力以及电子束辐射 (EBI)等因素对木材的液体浸渍行为的影响     

木质素胶粘剂的开发和应用

木质素作为植物中蕴藏量仅次于纤维素的高聚物,是一种廉价易得,储量丰富,环境友好的可再生天然资源。文章主要就木质素的结构和性能以及在各类用途胶粘剂中的应用作了详细的概述。     

Impregnation of X Zeolite with Alkaline Hydroxide During the Synthesis

Enhancement of the basic properties of the X zeolite with FAU framework has been carried out during synthesis, without further treatment such as ion-exchange or impregnation. Control of the washing stage enables retention of the optimum amount of alkaline hydroxides, which increases the basic catalytic activity of X zeolite in the alkylation of toluene. This alkaline hydroxides neither affect the FAU framework nor the silicon/aluminium molar ratio of the X zeolite. The optimum (Na + K)/Al molar ratio of the improved catalyst was 1.06 corresponding to a washing volume of 200 mL. This X zeolite presented better catalytic activity than a cesium-zeolite prepared by ion-exchange. The presence of hydroxysodalite impurity in the X zeolite increased the amount of impregnated alkaline hydroxides but not the catalytic activity. The present study shows that it is possible to increase the basic properties of the X zeolite directly in the synthesis process.     

Lignin‐based polycondensation resins for wood adhesives

Lignin‐based wood adhesives are obtained that satisfy the requirements of relevant international standards for the manufacture of exterior‐grade wood particleboard. Formulations based on low molecular mass lignin and presenting an increase in the relative proportion of reactive points yield better results than the higher molecular mass lignin used in the past. These lignins allow a higher proportion of hydroxymethylation during preparation of methylolated lignins. These lignin‐based adhesives also yield acceptable results at particleboard pressing times that are sufficiently low to be of industrial significance. Lignin‐based wood adhesives, in which a nonvolatile nontoxic aldehyde (glyoxal) is substituted for formaldehyde in their preparation, are prepared and tested for application to wood panels such as particleboard. The adhesives yield good internal bond strength results for the panels, which are good enough to comfortably pass relevant international standard specifications for exterior‐grade panels. The adhesives also show sufficient reactivity to yield panels in press times comparable to that of formaldehyde‐based commercial adhesives. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 1690–1699, 2007     

二合一石墨合成炉的应用

对石墨合成炉运行中出现的故障进行分析和探讨，并提出一些建议和改进措施，以实现石墨合成炉的稳定运行。